The studies have been carried out in laboratory on the effect of dyeing,electroplating, pesticide effluents and their intermixture on embryos of lefteye flounder (Paralichthys olivaceus ). The main toxic substances in...The studies have been carried out in laboratory on the effect of dyeing,electroplating, pesticide effluents and their intermixture on embryos of lefteye flounder (Paralichthys olivaceus ). The main toxic substances in dying effluent are aniline ( 20 mg/L ) andphenol ( 24 mg/L ). The main toxic substances in electroplating effluent are Zn ( 1 970 mg/L ). Cu (9 mg/L ) and Pb ( 7.5 mg/L ). The main toxic substances in pesticide effluent are monocrotophos andphosphite. The test results indicate that the lowest concentrations of dyeing, electroplating,pesticide effluents and their intermixture, having significant effect on the hatch rate anddevelopment of P. olivaceus embryos, are 0.5 %, 0.15 %, 0.25 % and 0.25 %, respectively; and theincipient LC_(50) of dyeing, electroplating, pesticide effluents and their intermixture are 3.38 % (2.29 %～3.87 % ), 0.81 % ( 0.71 % ～0. 92 % ). 1.57 % ( 1.37 %～1.82 % ) and 1.48 % ( 1.24 %～1.76% ). Based on the incipient LG_(50) values, the toxicity sequence of the three industrial effluentsis in the order of electroplating effluent > pesticide effluent > dyeing effluent.展开更多
Ultrasound (US)-induced cavitation is an effective way in oxidizing organic contaminants in wastewater either as the independent operation unit or in combination with other oxidation methods. In this paper, black liqu...Ultrasound (US)-induced cavitation is an effective way in oxidizing organic contaminants in wastewater either as the independent operation unit or in combination with other oxidation methods. In this paper, black liquor and filtrate after acidifying and settling were sonicated. The effect of working parameters on ultrasonic degradation of black liquor, such as different combination methods, frequency, power supply, initial concentration, pH, duration time, ionic strength and catalyst were studied. The results were as follows: (1) At the conditions of 40kHz, 100W, 4h, pH at 6 and temperature 30?℃, utilizing US/US-H2O2/US-Fenton, weak-orange filtrate turned to colloid with the increase of time and little sediment produced after settling. Especially filtrate came to be milk white collides and upper water approached to nearly achromatic by US-Fenton. Compared with the US, US-H2O2/US-Fenton COD (Chemical oxidation demand) removal ratio can increase 15%, 30% respectively. Because of more hydroxyl radicals produced in the reaction process; (2) At the condition of 100W and 4h, the degradation efficiency of black liquor was better at 40kHz over at 20kHz. Moreover black liquor can be biodegraded easily. Those based on that the big molecule of contaminants in aqueous solution can be changed into the little molecule with ultrasound (3) At the condition of 40kHz and 4h, the COD removal ratio of black liquor was more higher at 60W than at 80W, while the removal ratio of COD at 60W was nearly close to the ratio at 100W; (4) The initial concentration of black liquor influenced the effect of sonochemical degradation; (5) The variation of pH had no effect on degradation; (6) The longer the duration time, the greater the removal ratio of COD. But this ratio increased slowly after 4h; (7) Adding 0.2g/L NaCl to change the ionic strength of the black liquor, the COD removal ratio can increase 10%; (8) The degradation rates increased by the coexistent catalysts of TiO2, Co2+ and Ag+.展开更多
The adsorption ofEscherichia coli and Staphylococcus aureus on chaff and WMDP （waste of molasses dates production） has been studied. FTIR spectra were employed to investigate the adsorption ofEscherichia coli and St...The adsorption ofEscherichia coli and Staphylococcus aureus on chaff and WMDP （waste of molasses dates production） has been studied. FTIR spectra were employed to investigate the adsorption ofEscherichia coli and Staphylococcus aureus on surfaces. Adsorption of bacteria resulted in obvious shifts of some infrared bands of adsorbents. The adsorption isotherms ofEscherichia coli on two surfaces and Staphylococcus aureus on WMDP, are of L-curve type according to Giles classification. However, type H isotherm was observed in the adsorption of S. aureus on chaff. The adsorption isotherms of bacteria on the examined adsorbents conformed to the Langmuir and Temkin equations. The adsorption of bacteria was studied at different temperatures （10, 25 and 40 ℃）, the thermodynamic parameters （AH, AS and AG） have also been calculated and it has been found that the adsorption process of bacteria was exothermic in nature. The number of bacteria adsorbed on surfaces was decreased with the increase of sodium chloride concentration. The amount of bacteria cells adsorbed was increased in the presence of different cations and followed the sequence： FeCl3 〉 CaCl2 〉 KCl 〉 NaCl. The pseudo-first order and pseudo-second order models for describing the kinetic data were applied and it was found that the process was well described by pseudo-second order model. The desorption studies indicated that the bacteria were strongly retained by two adsorbents.展开更多
In order to analyze the characteristics of surface water resource quality for the reconstruction of old water treatment plant,multivariate statistical techniques such as cluster analysis and factor analysis were appli...In order to analyze the characteristics of surface water resource quality for the reconstruction of old water treatment plant,multivariate statistical techniques such as cluster analysis and factor analysis were applied to the data of Yuqiao Reservoir-surface water resource of the Luan River,China.The results of cluster analysis demonstrate that the months of one year were divided into 3 groups and the characteristic of clusters was agreed with the seasonal characteristics in North China.Three factors were derived from the complicated set using factor analysis.Factor 1 included turbidity and chlorophyll,which seemed to be related to the anthropogenic activities;factor 2 included alkaline and hardness,which were related to the natural characteristic of surface water;and factor 3 included Cl and NO2-N affected by mineral and agricultural activities.The sinusoidal shape of the score plots of the three factors shows that the temporal variations caused by natural and human factors are linked to seasonality.展开更多
文摘The studies have been carried out in laboratory on the effect of dyeing,electroplating, pesticide effluents and their intermixture on embryos of lefteye flounder (Paralichthys olivaceus ). The main toxic substances in dying effluent are aniline ( 20 mg/L ) andphenol ( 24 mg/L ). The main toxic substances in electroplating effluent are Zn ( 1 970 mg/L ). Cu (9 mg/L ) and Pb ( 7.5 mg/L ). The main toxic substances in pesticide effluent are monocrotophos andphosphite. The test results indicate that the lowest concentrations of dyeing, electroplating,pesticide effluents and their intermixture, having significant effect on the hatch rate anddevelopment of P. olivaceus embryos, are 0.5 %, 0.15 %, 0.25 % and 0.25 %, respectively; and theincipient LC_(50) of dyeing, electroplating, pesticide effluents and their intermixture are 3.38 % (2.29 %～3.87 % ), 0.81 % ( 0.71 % ～0. 92 % ). 1.57 % ( 1.37 %～1.82 % ) and 1.48 % ( 1.24 %～1.76% ). Based on the incipient LG_(50) values, the toxicity sequence of the three industrial effluentsis in the order of electroplating effluent > pesticide effluent > dyeing effluent.
文摘Ultrasound (US)-induced cavitation is an effective way in oxidizing organic contaminants in wastewater either as the independent operation unit or in combination with other oxidation methods. In this paper, black liquor and filtrate after acidifying and settling were sonicated. The effect of working parameters on ultrasonic degradation of black liquor, such as different combination methods, frequency, power supply, initial concentration, pH, duration time, ionic strength and catalyst were studied. The results were as follows: (1) At the conditions of 40kHz, 100W, 4h, pH at 6 and temperature 30?℃, utilizing US/US-H2O2/US-Fenton, weak-orange filtrate turned to colloid with the increase of time and little sediment produced after settling. Especially filtrate came to be milk white collides and upper water approached to nearly achromatic by US-Fenton. Compared with the US, US-H2O2/US-Fenton COD (Chemical oxidation demand) removal ratio can increase 15%, 30% respectively. Because of more hydroxyl radicals produced in the reaction process; (2) At the condition of 100W and 4h, the degradation efficiency of black liquor was better at 40kHz over at 20kHz. Moreover black liquor can be biodegraded easily. Those based on that the big molecule of contaminants in aqueous solution can be changed into the little molecule with ultrasound (3) At the condition of 40kHz and 4h, the COD removal ratio of black liquor was more higher at 60W than at 80W, while the removal ratio of COD at 60W was nearly close to the ratio at 100W; (4) The initial concentration of black liquor influenced the effect of sonochemical degradation; (5) The variation of pH had no effect on degradation; (6) The longer the duration time, the greater the removal ratio of COD. But this ratio increased slowly after 4h; (7) Adding 0.2g/L NaCl to change the ionic strength of the black liquor, the COD removal ratio can increase 10%; (8) The degradation rates increased by the coexistent catalysts of TiO2, Co2+ and Ag+.
文摘The adsorption ofEscherichia coli and Staphylococcus aureus on chaff and WMDP （waste of molasses dates production） has been studied. FTIR spectra were employed to investigate the adsorption ofEscherichia coli and Staphylococcus aureus on surfaces. Adsorption of bacteria resulted in obvious shifts of some infrared bands of adsorbents. The adsorption isotherms ofEscherichia coli on two surfaces and Staphylococcus aureus on WMDP, are of L-curve type according to Giles classification. However, type H isotherm was observed in the adsorption of S. aureus on chaff. The adsorption isotherms of bacteria on the examined adsorbents conformed to the Langmuir and Temkin equations. The adsorption of bacteria was studied at different temperatures （10, 25 and 40 ℃）, the thermodynamic parameters （AH, AS and AG） have also been calculated and it has been found that the adsorption process of bacteria was exothermic in nature. The number of bacteria adsorbed on surfaces was decreased with the increase of sodium chloride concentration. The amount of bacteria cells adsorbed was increased in the presence of different cations and followed the sequence： FeCl3 〉 CaCl2 〉 KCl 〉 NaCl. The pseudo-first order and pseudo-second order models for describing the kinetic data were applied and it was found that the process was well described by pseudo-second order model. The desorption studies indicated that the bacteria were strongly retained by two adsorbents.
基金Project supported by the Hi-Tech Research and Development(863)Program of China(No.2006AA06Z311)Development Program for Outstanding Young Teachers in Harbin Institute of Technology(No.HITQNJS.2008.044),China
文摘In order to analyze the characteristics of surface water resource quality for the reconstruction of old water treatment plant,multivariate statistical techniques such as cluster analysis and factor analysis were applied to the data of Yuqiao Reservoir-surface water resource of the Luan River,China.The results of cluster analysis demonstrate that the months of one year were divided into 3 groups and the characteristic of clusters was agreed with the seasonal characteristics in North China.Three factors were derived from the complicated set using factor analysis.Factor 1 included turbidity and chlorophyll,which seemed to be related to the anthropogenic activities;factor 2 included alkaline and hardness,which were related to the natural characteristic of surface water;and factor 3 included Cl and NO2-N affected by mineral and agricultural activities.The sinusoidal shape of the score plots of the three factors shows that the temporal variations caused by natural and human factors are linked to seasonality.
