A complex [Cu2Br2(L)2]n(1)(L=bis(2-pyrimidinylthio)methane)has been synthesized and structurally characterized.Complex 1 contains dinuclear Cu2Br2 units,which are linked by ditopic L to form a 2D layer structure with ...A complex [Cu2Br2(L)2]n(1)(L=bis(2-pyrimidinylthio)methane)has been synthesized and structurally characterized.Complex 1 contains dinuclear Cu2Br2 units,which are linked by ditopic L to form a 2D layer structure with a 36-membered macrometallocycle.The adjacent layers are further connected through interpyrimidyl rings C-H … N and π-π interactions to give rise to a three-dimensional supramolecular structure.Complex 1 also displays strong green solid-state photoluminescence,due to metal-to-ligand charge-transfer(MLCT)at room temperature.CCDC:711434.展开更多
文摘A complex [Cu2Br2(L)2]n(1)(L=bis(2-pyrimidinylthio)methane)has been synthesized and structurally characterized.Complex 1 contains dinuclear Cu2Br2 units,which are linked by ditopic L to form a 2D layer structure with a 36-membered macrometallocycle.The adjacent layers are further connected through interpyrimidyl rings C-H … N and π-π interactions to give rise to a three-dimensional supramolecular structure.Complex 1 also displays strong green solid-state photoluminescence,due to metal-to-ligand charge-transfer(MLCT)at room temperature.CCDC:711434.
