The easy oxidation and surface roughness of Cu nanowire （NW） films are the main bottlenecks for their usage in transparent conductive electrodes （TCEs）. Herein, we have developed a facile and scaled-up solution ro...The easy oxidation and surface roughness of Cu nanowire （NW） films are the main bottlenecks for their usage in transparent conductive electrodes （TCEs）. Herein, we have developed a facile and scaled-up solution route to prepare Cu NW-based TCEs by embedding Cu NWs into pre-coated smooth poly（3,4-ethylenedioxythiophene）：poly（styrenesulfonate） （PEDOT：PSS） films on poly（ethylene terephthalate） （PET） substrates. The so obtained Cu NW- PEDOT：PSS/PET films have low surface roughness （-70 nm in height）, high stability toward oxidation and good flexibility. The optimal TCEs show a typical sheet resistance of 15Ω·sq-1 at high transparency （76% at A = 550 nm） and have been used successfully to make polymer （poly（3-hexylthiophene）：phenyl-C61- butyric acid methyl ester） solar cells, giving an efficiency of 1.4%. The overall properties of Cu NW-PEDOT：PSS/PET films demonstrate their potential application as a replacement for indium tin oxide in flexible solar cells.展开更多
The effect of grid shape on the properties of transparent conductive films(TCFs) is theoretically analyzed and experimentally verified. The light transmittance by three types of grid shapes: triangle, square and hexag...The effect of grid shape on the properties of transparent conductive films(TCFs) is theoretically analyzed and experimentally verified. The light transmittance by three types of grid shapes: triangle, square and hexagon have been theoretically calculated and simulated. It was found that hexagonal grid unit has the highest light transmittance limit under the practical lattice parameters and its decrease in light transmittance caused by the increase of line width in printing process is the least. The grid of three different shapes with same theoretical transmittance is fabricated through flexographic printing. The result shows that the actual light transmittance of the printed TCFs is lower than its theoretical value because of the inevitable width increase of printed grid lines, with slight difference between the three shapes. However, it is greatly different in terms of conductivity, leading to variation in the quality factor Q(defined as the ratio of light transmittance to total resistance) which represents the performance of TCFs. The Q of hexagonal grid(6.04) is the highest, which is 21% higher than that of the square grid.展开更多
文摘The easy oxidation and surface roughness of Cu nanowire （NW） films are the main bottlenecks for their usage in transparent conductive electrodes （TCEs）. Herein, we have developed a facile and scaled-up solution route to prepare Cu NW-based TCEs by embedding Cu NWs into pre-coated smooth poly（3,4-ethylenedioxythiophene）：poly（styrenesulfonate） （PEDOT：PSS） films on poly（ethylene terephthalate） （PET） substrates. The so obtained Cu NW- PEDOT：PSS/PET films have low surface roughness （-70 nm in height）, high stability toward oxidation and good flexibility. The optimal TCEs show a typical sheet resistance of 15Ω·sq-1 at high transparency （76% at A = 550 nm） and have been used successfully to make polymer （poly（3-hexylthiophene）：phenyl-C61- butyric acid methyl ester） solar cells, giving an efficiency of 1.4%. The overall properties of Cu NW-PEDOT：PSS/PET films demonstrate their potential application as a replacement for indium tin oxide in flexible solar cells.
基金supported by the Beijing Municipal Commission of Education Foundation for School Innovation Ability Promotion Plan(Grant No.TJSHG201310015016)the Key Project of Beijing Institute of Graphic Communication(Grant No.Ea201501)the Creative Groups of Materials and Technology of Printed Electronics(Grant No.23190113100)
文摘The effect of grid shape on the properties of transparent conductive films(TCFs) is theoretically analyzed and experimentally verified. The light transmittance by three types of grid shapes: triangle, square and hexagon have been theoretically calculated and simulated. It was found that hexagonal grid unit has the highest light transmittance limit under the practical lattice parameters and its decrease in light transmittance caused by the increase of line width in printing process is the least. The grid of three different shapes with same theoretical transmittance is fabricated through flexographic printing. The result shows that the actual light transmittance of the printed TCFs is lower than its theoretical value because of the inevitable width increase of printed grid lines, with slight difference between the three shapes. However, it is greatly different in terms of conductivity, leading to variation in the quality factor Q(defined as the ratio of light transmittance to total resistance) which represents the performance of TCFs. The Q of hexagonal grid(6.04) is the highest, which is 21% higher than that of the square grid.
