Nanoscale layered K2Ti4O9 was prepared by solid-state method using nanosca le TiO2 with average particle size of 20 nm as the raw material. The obtained na noscale K2Ti4O9 was further used as the host material for the...Nanoscale layered K2Ti4O9 was prepared by solid-state method using nanosca le TiO2 with average particle size of 20 nm as the raw material. The obtained na noscale K2Ti4O9 was further used as the host material for the preparation of Al2 O3 pillared K2Ti4O9 and the K2Ti4O9 was undergone H+-exchange, alkylamine-pre-ex pansion, Keggin-pillaring and heat-treatment. The products were characterized by XRD, TEM and BET methods. The interlayer distance of K2Ti4O9 was expanded step by step during the pillaring procedure and the Al2O3 pillared H2Ti4O9 with narro w pore-size distribution and high surface area (212.8 m2·g-1) was obtained.展开更多
The mechanism of stress generation and propagation by detonation loading in five separate independent advance of ore breaking patterns is discussed in the paper. An elastic numerical model was developed using AN- SYS/...The mechanism of stress generation and propagation by detonation loading in five separate independent advance of ore breaking patterns is discussed in the paper. An elastic numerical model was developed using AN- SYS/LS-DYNA 3D Nonlinear Dynamic Finite Element Software. In this package ANSYS is the preprocessor and LS-DYNA is the postprocessor. Numerical models in the paper to actual were l：10 and the element mesh was dissected in scanning mode utilizing the symmetry characteristics of the numerical model. Five different advance rates were studied. Parameters, such as the time required to maximum stress, the action time of the available stress, the maximum velocity of the nodes, the stress penetration time, the magnitude of the stress peak and the time duration for high stress were numerically simulated. The 2.2 m advance appeared optimum from an analysis of the simulation results. The results from numerical simulation have been validated by tests with physical models.展开更多
In the present work, a novel heterogeneous photo-Fenton catalyst was prepared by iron and cerium pillared bentonite. The catalyst Fe-Ce/bentonite was characterized by X-ray diffraction （XRD）, X-ray fluorescence （XR...In the present work, a novel heterogeneous photo-Fenton catalyst was prepared by iron and cerium pillared bentonite. The catalyst Fe-Ce/bentonite was characterized by X-ray diffraction （XRD）, X-ray fluorescence （XRF）, Brunauer-Emmett-Teller （BET） and scanning electron microscopy （SEM） methods. It is found that Fe and Ce intercalate into the silicate layers of bentonite successfully. Tetracycline was removed by heterogeneous photo-Fenton reaction using the catalyst in this work. The effects of different reaction systems, hydrogen peroxide concentration, initial pH, catalyst dosage, UV power and introduction of different anions on degradation were investigated in details. The stability of catalyst was investigated through recycling experiment. The results show that removal rate of tetracycline is 98.13% under the conditions of 15 mmol/L H202, 0.50 g/L catalyst dosage, initial pH 3.0, 11 W UV lamp power and 60 min reaction time. However, the removal rate decreases after adding some anions. The hydroxyl radical plays an important role in heterogeneous photo-assisted Fenton degradation of tetracycline. The catalyst is very stable and can be recycled many times.展开更多
文摘Nanoscale layered K2Ti4O9 was prepared by solid-state method using nanosca le TiO2 with average particle size of 20 nm as the raw material. The obtained na noscale K2Ti4O9 was further used as the host material for the preparation of Al2 O3 pillared K2Ti4O9 and the K2Ti4O9 was undergone H+-exchange, alkylamine-pre-ex pansion, Keggin-pillaring and heat-treatment. The products were characterized by XRD, TEM and BET methods. The interlayer distance of K2Ti4O9 was expanded step by step during the pillaring procedure and the Al2O3 pillared H2Ti4O9 with narro w pore-size distribution and high surface area (212.8 m2·g-1) was obtained.
文摘The mechanism of stress generation and propagation by detonation loading in five separate independent advance of ore breaking patterns is discussed in the paper. An elastic numerical model was developed using AN- SYS/LS-DYNA 3D Nonlinear Dynamic Finite Element Software. In this package ANSYS is the preprocessor and LS-DYNA is the postprocessor. Numerical models in the paper to actual were l：10 and the element mesh was dissected in scanning mode utilizing the symmetry characteristics of the numerical model. Five different advance rates were studied. Parameters, such as the time required to maximum stress, the action time of the available stress, the maximum velocity of the nodes, the stress penetration time, the magnitude of the stress peak and the time duration for high stress were numerically simulated. The 2.2 m advance appeared optimum from an analysis of the simulation results. The results from numerical simulation have been validated by tests with physical models.
基金Project(51004053)supported by National Natural Science Foundation of ChinaProject(2009J01033)supported by Natural Science Foundation of Fujian Province,China+2 种基金Project(3502Z20116008)supported by the Science and Technology Research Project of Xiamen City,ChinaProject(JA11146)supported by Program for Fostering Distinguished Young Scholars in University of Fujian Province,ChinaProject(2011B003)supported by the Foundation for Young Professors of Jimei University,China
文摘In the present work, a novel heterogeneous photo-Fenton catalyst was prepared by iron and cerium pillared bentonite. The catalyst Fe-Ce/bentonite was characterized by X-ray diffraction （XRD）, X-ray fluorescence （XRF）, Brunauer-Emmett-Teller （BET） and scanning electron microscopy （SEM） methods. It is found that Fe and Ce intercalate into the silicate layers of bentonite successfully. Tetracycline was removed by heterogeneous photo-Fenton reaction using the catalyst in this work. The effects of different reaction systems, hydrogen peroxide concentration, initial pH, catalyst dosage, UV power and introduction of different anions on degradation were investigated in details. The stability of catalyst was investigated through recycling experiment. The results show that removal rate of tetracycline is 98.13% under the conditions of 15 mmol/L H202, 0.50 g/L catalyst dosage, initial pH 3.0, 11 W UV lamp power and 60 min reaction time. However, the removal rate decreases after adding some anions. The hydroxyl radical plays an important role in heterogeneous photo-assisted Fenton degradation of tetracycline. The catalyst is very stable and can be recycled many times.
