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脱线柱预富集ICP-MS法测定南极水样中的痕量元素 被引量:16
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作者 陈树榆 孙梅 余明华 《分析试验室》 CAS CSCD 北大核心 2002年第1期16-20,共5页
采用脱线螯合阳离子树脂 (D40 1 )将待分析元素预富集并与基体元素分离 ,采用电感耦合等离子体质谱法 (ICP MS)测定了南极拉斯曼丘陵地区环境水样中的难于或不能直接检测的超痕量元素Mn ,Co ,Ni,Cu ,Cd ,Ba和Pb ;建立了一种准确、简便... 采用脱线螯合阳离子树脂 (D40 1 )将待分析元素预富集并与基体元素分离 ,采用电感耦合等离子体质谱法 (ICP MS)测定了南极拉斯曼丘陵地区环境水样中的难于或不能直接检测的超痕量元素Mn ,Co ,Ni,Cu ,Cd ,Ba和Pb ;建立了一种准确、简便、快速的在线加内标校准方法。被分析元素的测定灵敏度均提高了30倍左右 ;对于 1 0 0mL水样检测限为 1 42 5ng/L~ 2 4 展开更多
关键词 电感耦合等离子体质谱法 柱预富集 ICP-MS 南极水样 水污染 痕量元素 测定
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毛细管区带电泳的离子交换在柱预富集技术研究
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作者 张召香 何友昭 《分析化学》 SCIE EI CAS CSCD 北大核心 2005年第8期1132-1134,共3页
提出了离子交换固相萃取的毛细管区带电泳在柱预富集技术。预富集毛细管和分离毛细管的端面靠紧,二者通过一段带侧孔的聚四氟乙烯(PTFE)套管固定。预富集毛细管内壁键合羧基阳离子交换基团,进样时分析离子被保留在预富集管的固定相上,用... 提出了离子交换固相萃取的毛细管区带电泳在柱预富集技术。预富集毛细管和分离毛细管的端面靠紧,二者通过一段带侧孔的聚四氟乙烯(PTFE)套管固定。预富集毛细管内壁键合羧基阳离子交换基团,进样时分析离子被保留在预富集管的固定相上,用2mol/L的氯化铵溶液洗脱,再进行毛细管区带电泳分离。方法成功富集和分离了两种低浓度的药物阳离子,普萘洛尔和美托洛尔的灵敏度比常规电动进样分别提高4200和3400倍,其浓度检出限分别为0.02μg/L和0.14μg/L。 展开更多
关键词 毛细管区带电泳 离子交换 柱预富集技术 药物分析 普萘洛尔 美托洛尔 分离
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Application of reflux classifier with closely spaced inclined channels in pre-concentrate process of fine antimony oxide particles 被引量:2
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作者 LIU Zhen-qiang LU Dong-fang +3 位作者 WANG Yu-hua CHU Hao-ran ZHENG Xia-yu CHEN Fu-lin 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第11期3290-3301,共12页
In this work,the reflux classifier with closely spaced inclined channels is used as the pre-concentration facility to improve the separation efficiency before the shaking table separation.Three operating parameters of... In this work,the reflux classifier with closely spaced inclined channels is used as the pre-concentration facility to improve the separation efficiency before the shaking table separation.Three operating parameters of reflux classifier(RC)to pre-concentrate fine(0.023−0.15 mm)tailings of antimony oxide were optimized by response surface methodology(RSM)using a three-level Box-Behnken design(BBD).The parameters studied for the optimization were feeding speed,underflow,and ascending water speed.Second-order response functions were produced for the Sb grade and recovery rate of the concentrate.Taking advantage of the quadratic programming,when the factors of feeding,underflow and ascending water are respectively 225,30 and 133 cm^3/min,a better result can be achieved for the concentrate grade of 2.31% and recovery rate of 83.17%.At the same time,70.48% of the tailings with the grade of 0.20% were discarded out of the feeding.The results indicated that the reflux classifier has a good performance in dealing with fine tailings of antimony oxide.Moreover,second-order polynomial equations,ANOVA,and three-dimensional surface plots were developed to evaluate the effects of each parameter on Sb grade and recovery rate of the concentrate. 展开更多
关键词 reflux classifier antimony oxide PRE-CONCENTRATION inclined channels
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