In this paper, a method was established to determine the boiling point distribution of hydrocarbon types in diesel. The diesel sample was separated into the saturate and aromatic fractions by means of solid-phase extr...In this paper, a method was established to determine the boiling point distribution of hydrocarbon types in diesel. The diesel sample was separated into the saturate and aromatic fractions by means of solid-phase extraction （SPE）, and each fraction was analyzed by GC/FID-EIMS. According to the relationship between boiling point and retention time of n-paraffins in the chromatogram, the percentages of saturates and aromatics at each temperature interval were calculated. According to the average mass spectra of the saturate and aromatic fractions at each temperature interval, the hydrocarbon types of the sample were identified through summation of characteristic mass fragments. Using this method, the changes in composition of diesel during hydrotreating process were studied. The results showed that hydrogenation of aromatics is the main reaction during the hydrotreating process. The more rings the aromatics have, the easier the hydrogenation reactions would take place. The aromatics were converted into cycloparaffins via the hydrogenation and saturation process, leading to an increase in low boiling point fractions in the hydrotreated oil.展开更多
Thermal upgrading of vacuum residue mixed with waste plastics was studied in a laboratory scale delayed coking unit.The model of feed thermal decomposition was set up and the first order reaction kinetics was used to ...Thermal upgrading of vacuum residue mixed with waste plastics was studied in a laboratory scale delayed coking unit.The model of feed thermal decomposition was set up and the first order reaction kinetics was used to predict products distribution during the coking process.The distillate yield was higher(70%) for the vacuum residue/polystyrene(VR/PS) feed system and the vacuum residue/low density polyethylene(VR/LDPE) feed system.The resulted distillate yield was separated into fractions according to their boiling points,with gasoline and diesel being our fractions of concern.The activation energy was higher for gasoline production(around 60 kcal/mol) varying with the type of feed system,while it was 33 kcal/mol for diesel fraction.The regression coefficient R was 0.990.展开更多
The European Union Framework Programme 71 Enerfish project aims to demonstrate a new poly-generation application with renewable energy sources for the fishery industry in Vietnam. The fish processing plant under consi...The European Union Framework Programme 71 Enerfish project aims to demonstrate a new poly-generation application with renewable energy sources for the fishery industry in Vietnam. The fish processing plant under consideration can be made by energy self-sufficient when all fish waste oil is processed into biodiesel and further converted to electricity and heat （for cooling） in a CHP （combined heat and power） unit. The purpose of the present paper is to discuss the profitability of such plants in southeast Asia. The economic model shows that electricity production is, due to the low electricity tariff, uneconomical （except during electricity blackout）, even if cogeneration heat can be utilized. This prompt a design of the plant whereby the necessary heat for the biodiesel process is taken from the waste heat produced by the compressors of a CO2 cooling system. According to the calculations and assumptions of the present study, the profitability of biodiesel production from fish cleaning wastes in Vietnam depends strongly on the market prices for fish waste and fish oil. Different business case scenarios are described.展开更多
基金the National Key Basic Research Science Foundation(Grant No.2006CB202501)
文摘In this paper, a method was established to determine the boiling point distribution of hydrocarbon types in diesel. The diesel sample was separated into the saturate and aromatic fractions by means of solid-phase extraction （SPE）, and each fraction was analyzed by GC/FID-EIMS. According to the relationship between boiling point and retention time of n-paraffins in the chromatogram, the percentages of saturates and aromatics at each temperature interval were calculated. According to the average mass spectra of the saturate and aromatic fractions at each temperature interval, the hydrocarbon types of the sample were identified through summation of characteristic mass fragments. Using this method, the changes in composition of diesel during hydrotreating process were studied. The results showed that hydrogenation of aromatics is the main reaction during the hydrotreating process. The more rings the aromatics have, the easier the hydrogenation reactions would take place. The aromatics were converted into cycloparaffins via the hydrogenation and saturation process, leading to an increase in low boiling point fractions in the hydrotreated oil.
文摘Thermal upgrading of vacuum residue mixed with waste plastics was studied in a laboratory scale delayed coking unit.The model of feed thermal decomposition was set up and the first order reaction kinetics was used to predict products distribution during the coking process.The distillate yield was higher(70%) for the vacuum residue/polystyrene(VR/PS) feed system and the vacuum residue/low density polyethylene(VR/LDPE) feed system.The resulted distillate yield was separated into fractions according to their boiling points,with gasoline and diesel being our fractions of concern.The activation energy was higher for gasoline production(around 60 kcal/mol) varying with the type of feed system,while it was 33 kcal/mol for diesel fraction.The regression coefficient R was 0.990.
文摘The European Union Framework Programme 71 Enerfish project aims to demonstrate a new poly-generation application with renewable energy sources for the fishery industry in Vietnam. The fish processing plant under consideration can be made by energy self-sufficient when all fish waste oil is processed into biodiesel and further converted to electricity and heat （for cooling） in a CHP （combined heat and power） unit. The purpose of the present paper is to discuss the profitability of such plants in southeast Asia. The economic model shows that electricity production is, due to the low electricity tariff, uneconomical （except during electricity blackout）, even if cogeneration heat can be utilized. This prompt a design of the plant whereby the necessary heat for the biodiesel process is taken from the waste heat produced by the compressors of a CO2 cooling system. According to the calculations and assumptions of the present study, the profitability of biodiesel production from fish cleaning wastes in Vietnam depends strongly on the market prices for fish waste and fish oil. Different business case scenarios are described.
