Calcium sulfoaluminate,3CaO·3Al2O3·CaSO4,has been widely recognized in the realms of high-temperature combustion and cement chemistry.However,the lack of relevant thermodynamic data limits the progress of it...Calcium sulfoaluminate,3CaO·3Al2O3·CaSO4,has been widely recognized in the realms of high-temperature combustion and cement chemistry.However,the lack of relevant thermodynamic data limits the progress of its research and development.Through comparative calculations using several different approaches,we obtain the thermochemical properties of 3CaO·3Al2O3·CaSO4 in this work,such as its standard formation enthalpy,Gibbs free en- ergy of formation,entropy,and molar heat capacity.With these fundamental data,thermodynamic calculations become possible for reactions involving this mineral.It is found that some reactions proposed in literature to generate this mineral may not proceed thermodynamically.展开更多
Based on the Chinese National Standards involving heat pump water heater and space heating system, performances of the R744/R290 subcritical heat pump system have been discussed and compared with those of the R22 syst...Based on the Chinese National Standards involving heat pump water heater and space heating system, performances of the R744/R290 subcritical heat pump system have been discussed and compared with those of the R22 system, which is widely used in heat pump systems in China nowadays. It can be indicated that R744/R290 mixture can work efficiently as a refrigerant for heat pumps with a large heat-sink temperature rise. When mass fraction of R290 is increased, discharge pressure is reduced. Under the nominal working condition, there is an optimum mixture mass fraction of 20/80 for R744/R290 under conventional condensation pressure. Both the heating COPhs （coefficient of performance） and volumetric heating capacity are increased by about 12.62% and 34.24% respectively compared with those of R22 based system. But for the heat sink with a small temperature rise, R744/R290 system has poorer performances than R22 system. When heat transfer pinch point in evaporator and condensation processes is considered, the degree of superheat has a negative influence upon system performances under the given conditions.展开更多
We complete the derivation of the Cornwall-Jackiw-Tomboulis effective potentiM for quark propagator at finite temperature and finite quark chemical potential in the real-time formalism of thermal field theory and in L...We complete the derivation of the Cornwall-Jackiw-Tomboulis effective potentiM for quark propagator at finite temperature and finite quark chemical potential in the real-time formalism of thermal field theory and in Landau gauge. In the approximation that the function A（p^2） in inverse quark propagator is replaced by unity, by means of the running gauge coupling and the quark mass function invariant under the renormalization group in zero temperature Quantum Chromadynamics （QCD）, we obtain a calculable expression for the thermal effective potential, which will be a useful means to research chiral phase transition in QCD in the real-time formalism.展开更多
The molar heat capacities(C_p) of guaiacol(CAS 90-50-1) and acetyl guaiacol ester(AGE, CAS 613-70-7) were determinated from 290 K to 350 K by differential scanning calorimetry(DSC), and expressed as a function of temp...The molar heat capacities(C_p) of guaiacol(CAS 90-50-1) and acetyl guaiacol ester(AGE, CAS 613-70-7) were determinated from 290 K to 350 K by differential scanning calorimetry(DSC), and expressed as a function of temperature. Two kinds of group contribution models were used to estimate the molar heat capacities of both guaiacol and AGE, the average relative deviation is less than 10%. The standard molar enthalpies of combustion of guaiacol and AGE were- 3590.0 k J·mol^(-1)and- 4522.1 k J·mol^(-1) by a precise thermal isolation Oxygen Bomb Calorimeter. The standard molar enthalpies of formation of guaiacol and AGE in a liquid state at298.15 K were calculated to be- 307.95 k J·mol^(-1) and- 448.72 k J·mol^(-1), respectively, based on the standard molar enthalpies of combustion. The thermodynamic properties are useful for exploiting the new synthesis method, engineering design and industry production of AGE using guaiacol as a raw material.展开更多
The Hadley circulation is one of the most important atmospheric circulations.Widening of the Hadley circulation has drawn extensive studies in the past decade.The key concern is that widening of the Hadley circulation...The Hadley circulation is one of the most important atmospheric circulations.Widening of the Hadley circulation has drawn extensive studies in the past decade.The key concern is that widening of the Hadley circulation would cause poleward shift of the subtropical dry zone.Various metrics have been applied to measure the widening of the tropics.What are responsible for the observed widening trends of the Hadley circulation? How anthropogenic and natural forcings caused the widening? How the widening results in regional climatic effects? These are the major questions in studing the widening of the Hadley circulation.While both observations and simulations all show widening of the Hadley circulation in the past few decades,there are no general agreements of changes in the strength of the Hadley circulation.Although some reanalysis datasets show strengthening of the Hadley circulation,it was shown that the strengthening trend could be artificial,and simulations show weakening of the Hadley circulation for global greenhouse warming.In the present paper,we shall briefly review the major progresses of studies in trends in width and strength of the Hadley circulation.We address answers to these questions,clarify inconsistent results,and propose ideas for future studies.展开更多
基金Supported by the National Natural Science Foundation of China(50906046)the National High-Tech Research and Development Program of China(2009AA05Z303)the Program for New Century Excellent Talents in University(NCET-10-0529)
文摘Calcium sulfoaluminate,3CaO·3Al2O3·CaSO4,has been widely recognized in the realms of high-temperature combustion and cement chemistry.However,the lack of relevant thermodynamic data limits the progress of its research and development.Through comparative calculations using several different approaches,we obtain the thermochemical properties of 3CaO·3Al2O3·CaSO4 in this work,such as its standard formation enthalpy,Gibbs free en- ergy of formation,entropy,and molar heat capacity.With these fundamental data,thermodynamic calculations become possible for reactions involving this mineral.It is found that some reactions proposed in literature to generate this mineral may not proceed thermodynamically.
文摘Based on the Chinese National Standards involving heat pump water heater and space heating system, performances of the R744/R290 subcritical heat pump system have been discussed and compared with those of the R22 system, which is widely used in heat pump systems in China nowadays. It can be indicated that R744/R290 mixture can work efficiently as a refrigerant for heat pumps with a large heat-sink temperature rise. When mass fraction of R290 is increased, discharge pressure is reduced. Under the nominal working condition, there is an optimum mixture mass fraction of 20/80 for R744/R290 under conventional condensation pressure. Both the heating COPhs （coefficient of performance） and volumetric heating capacity are increased by about 12.62% and 34.24% respectively compared with those of R22 based system. But for the heat sink with a small temperature rise, R744/R290 system has poorer performances than R22 system. When heat transfer pinch point in evaporator and condensation processes is considered, the degree of superheat has a negative influence upon system performances under the given conditions.
文摘We complete the derivation of the Cornwall-Jackiw-Tomboulis effective potentiM for quark propagator at finite temperature and finite quark chemical potential in the real-time formalism of thermal field theory and in Landau gauge. In the approximation that the function A（p^2） in inverse quark propagator is replaced by unity, by means of the running gauge coupling and the quark mass function invariant under the renormalization group in zero temperature Quantum Chromadynamics （QCD）, we obtain a calculable expression for the thermal effective potential, which will be a useful means to research chiral phase transition in QCD in the real-time formalism.
文摘The molar heat capacities(C_p) of guaiacol(CAS 90-50-1) and acetyl guaiacol ester(AGE, CAS 613-70-7) were determinated from 290 K to 350 K by differential scanning calorimetry(DSC), and expressed as a function of temperature. Two kinds of group contribution models were used to estimate the molar heat capacities of both guaiacol and AGE, the average relative deviation is less than 10%. The standard molar enthalpies of combustion of guaiacol and AGE were- 3590.0 k J·mol^(-1)and- 4522.1 k J·mol^(-1) by a precise thermal isolation Oxygen Bomb Calorimeter. The standard molar enthalpies of formation of guaiacol and AGE in a liquid state at298.15 K were calculated to be- 307.95 k J·mol^(-1) and- 448.72 k J·mol^(-1), respectively, based on the standard molar enthalpies of combustion. The thermodynamic properties are useful for exploiting the new synthesis method, engineering design and industry production of AGE using guaiacol as a raw material.
基金supported by the National Natural Science Foundation of China(41530423,and 41761144072)
文摘The Hadley circulation is one of the most important atmospheric circulations.Widening of the Hadley circulation has drawn extensive studies in the past decade.The key concern is that widening of the Hadley circulation would cause poleward shift of the subtropical dry zone.Various metrics have been applied to measure the widening of the tropics.What are responsible for the observed widening trends of the Hadley circulation? How anthropogenic and natural forcings caused the widening? How the widening results in regional climatic effects? These are the major questions in studing the widening of the Hadley circulation.While both observations and simulations all show widening of the Hadley circulation in the past few decades,there are no general agreements of changes in the strength of the Hadley circulation.Although some reanalysis datasets show strengthening of the Hadley circulation,it was shown that the strengthening trend could be artificial,and simulations show weakening of the Hadley circulation for global greenhouse warming.In the present paper,we shall briefly review the major progresses of studies in trends in width and strength of the Hadley circulation.We address answers to these questions,clarify inconsistent results,and propose ideas for future studies.
