Isooctane is a promising gasoline additive that could be produced by dimerization of isobutene(IB) with subsequent hydrogenation.In this work,the dimerization of IB has been carried out in a batch reactor over a tempe...Isooctane is a promising gasoline additive that could be produced by dimerization of isobutene(IB) with subsequent hydrogenation.In this work,the dimerization of IB has been carried out in a batch reactor over a temperature range of 338-383 K in the presence of laboratory prepared Ni/Al_2O_3 as a catalyst and n-pentane as solvent.The influence of various parameters such as temperature,catalyst loading and initial concentration of IB was examined.A Langmuir-Hinshelwood kinetic model of IB dimerization was established and the parameters were estimated on the basis of the measured data.The feasibility of oligomerization of IB based on the reactive distillation was simulated in ASPEN PLUS using the kinetics developed.The simulation results showed that the catalyst of Ni/Al_2O_3 had higher selectivity to diisobutene(DIB) and slightly lower conversion of IB than ion exchange resin in the absence of polar substances.展开更多
Shrimp aquaculture is an important source of revenue for the state of Sarawak, Malaysia. However, there were concerns on the impact of shrimp farming on the mangrove ecosystem due to the discharge of shrimp pond water...Shrimp aquaculture is an important source of revenue for the state of Sarawak, Malaysia. However, there were concerns on the impact of shrimp farming on the mangrove ecosystem due to the discharge of shrimp pond water to the surrounding environment and potential self-pollution through the intake of surrounding water for the shrimp ponds. Therefore, the objectives of this study were to determine the water quality of the harvesting pond water and quantify the pollutants loadings. Samplings were conducted in three ponds and three channels near the pond outflow in a commercial shrimp farm during complete draining of water at harvest. Results indicated that TSS and Chl-a were high in both the ponds and channels. Total ammonia-nitrogen was the predominant form of the inorganic nitrogen and the mean values in both the ponds and channels were more than 1 mg/L which exceeded the maximum recommended for fish. Therefore, the water quality of the ponds and channel indicate that pond effluent should not be discharged directly into the surrounding environment but treated and nutrients recovered. Loads of total suspended solids, BODs, inorganic nitrogen, ammonia nitrogen, soluble reactive phosphorus and Chl-a of the effluent were quantified.展开更多
Physiological and ecological mechanisms that define treelines are still debated. It has been suggested that the absence of trees above the treeline is caused by low temperatures that limit growth. Thus, we hypothesize...Physiological and ecological mechanisms that define treelines are still debated. It has been suggested that the absence of trees above the treeline is caused by low temperatures that limit growth. Thus, we hypothesized that there is a critical minimum temperature （CTmin） preventing xylogenesis at treeline. We tested this hypothesis by examining weekly xylogenesis across three and four growing seasons in two natural Smith fir （Abies georgei var. srnithii） treeline sites on the southeastern Tibetan Plateau. Despite differences in the timing of cell differentiation among years, minimum air temperature was the dominant climatic variable associated with xylem growth; the critical minimum temperature （CTmin） for the onset and end of xylogenesis occurred at 0.7 ±0.4 ℃. A process-based modelling chronology of tree-ring formation using this CTmin was consistent with actual tree-ring data. This extremely low CTmin permits Smith fir growing at treeline to complete annual xylem production and maturation and provides both support and a mechanism for treeline formation.展开更多
We present a study to show the possibility of using two well-known space partitioning and indexing techniques, kd trees and quad trees, in declustering applications to increase input/output （I/O） paraUelization and ...We present a study to show the possibility of using two well-known space partitioning and indexing techniques, kd trees and quad trees, in declustering applications to increase input/output （I/O） paraUelization and reduce spatial data processing times. This parallelization enables time-consuming computational geometry algorithms to be applied efficiently to big spatial data rendering and querying. The key challenge is how to balance the spatial processing load across a large number of worker nodes, given significant performance heterogeneity in nodes and processing skews in the workload.展开更多
Electromagnetic levitation technique was used to undercool bulk samples of Co-20% Cu and Co-60% Cu alloys and high undercoolings up to 303 and 110 K were achieved,respectively.The dendritic growth velocities were meas...Electromagnetic levitation technique was used to undercool bulk samples of Co-20% Cu and Co-60% Cu alloys and high undercoolings up to 303 and 110 K were achieved,respectively.The dendritic growth velocities were measured as a function of undercooling.The dendrite growth velocity of the Co-20% Cu alloy was much higher than that of the Co-60% Cu alloy.The experimental data were analyzed on the basis of the LKT/BCT dendritic growth model by taking into account non-equilibrium interface kinetics.It has been revealed that a transition from solute diffusion controlled dendritic growth to thermal diffusion controlled dendritic growth occurs at an undercooling of about 66 K for the Co-20% Cu alloy,whereas the dendrite growth in Co-60% Cu alloy proceeds in a solute diffusion controlled mode within a large solidification temperature range,and the solutal undercooling plays a dominant role.It is thus deduced that certain distinct solidification temperature ranges may be responsible for the different solidification modes for the two alloys.展开更多
基金Supported by the State key Development Program for Basic Research of China(2012CB720502)the National High Technology Research and Development(2012AA040306)+1 种基金the National Natural Science Foundation of China(21076074)the Shanghai Pujiang Talents Program(10PJ1402400)
文摘Isooctane is a promising gasoline additive that could be produced by dimerization of isobutene(IB) with subsequent hydrogenation.In this work,the dimerization of IB has been carried out in a batch reactor over a temperature range of 338-383 K in the presence of laboratory prepared Ni/Al_2O_3 as a catalyst and n-pentane as solvent.The influence of various parameters such as temperature,catalyst loading and initial concentration of IB was examined.A Langmuir-Hinshelwood kinetic model of IB dimerization was established and the parameters were estimated on the basis of the measured data.The feasibility of oligomerization of IB based on the reactive distillation was simulated in ASPEN PLUS using the kinetics developed.The simulation results showed that the catalyst of Ni/Al_2O_3 had higher selectivity to diisobutene(DIB) and slightly lower conversion of IB than ion exchange resin in the absence of polar substances.
文摘Shrimp aquaculture is an important source of revenue for the state of Sarawak, Malaysia. However, there were concerns on the impact of shrimp farming on the mangrove ecosystem due to the discharge of shrimp pond water to the surrounding environment and potential self-pollution through the intake of surrounding water for the shrimp ponds. Therefore, the objectives of this study were to determine the water quality of the harvesting pond water and quantify the pollutants loadings. Samplings were conducted in three ponds and three channels near the pond outflow in a commercial shrimp farm during complete draining of water at harvest. Results indicated that TSS and Chl-a were high in both the ponds and channels. Total ammonia-nitrogen was the predominant form of the inorganic nitrogen and the mean values in both the ponds and channels were more than 1 mg/L which exceeded the maximum recommended for fish. Therefore, the water quality of the ponds and channel indicate that pond effluent should not be discharged directly into the surrounding environment but treated and nutrients recovered. Loads of total suspended solids, BODs, inorganic nitrogen, ammonia nitrogen, soluble reactive phosphorus and Chl-a of the effluent were quantified.
基金supported by the National Natural Science Foundations of China(41525001,41661144040,41601204)supported by the Bilateral Project between China and Slovenia(BI-CN/09–11-012)+1 种基金COST Action(FP1106,STRe ESS)supported by the Chinese Academy of Sciences President International Fellowship Initiative for Visiting Scientists(2016VBA074)
文摘Physiological and ecological mechanisms that define treelines are still debated. It has been suggested that the absence of trees above the treeline is caused by low temperatures that limit growth. Thus, we hypothesized that there is a critical minimum temperature （CTmin） preventing xylogenesis at treeline. We tested this hypothesis by examining weekly xylogenesis across three and four growing seasons in two natural Smith fir （Abies georgei var. srnithii） treeline sites on the southeastern Tibetan Plateau. Despite differences in the timing of cell differentiation among years, minimum air temperature was the dominant climatic variable associated with xylem growth; the critical minimum temperature （CTmin） for the onset and end of xylogenesis occurred at 0.7 ±0.4 ℃. A process-based modelling chronology of tree-ring formation using this CTmin was consistent with actual tree-ring data. This extremely low CTmin permits Smith fir growing at treeline to complete annual xylem production and maturation and provides both support and a mechanism for treeline formation.
文摘We present a study to show the possibility of using two well-known space partitioning and indexing techniques, kd trees and quad trees, in declustering applications to increase input/output （I/O） paraUelization and reduce spatial data processing times. This parallelization enables time-consuming computational geometry algorithms to be applied efficiently to big spatial data rendering and querying. The key challenge is how to balance the spatial processing load across a large number of worker nodes, given significant performance heterogeneity in nodes and processing skews in the workload.
基金supported by the National Natural Science Foundation of China (Grant No.50871088)NPU-FFR and the Foundation of Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials,Ministry of Education,Shandong University,China
文摘Electromagnetic levitation technique was used to undercool bulk samples of Co-20% Cu and Co-60% Cu alloys and high undercoolings up to 303 and 110 K were achieved,respectively.The dendritic growth velocities were measured as a function of undercooling.The dendrite growth velocity of the Co-20% Cu alloy was much higher than that of the Co-60% Cu alloy.The experimental data were analyzed on the basis of the LKT/BCT dendritic growth model by taking into account non-equilibrium interface kinetics.It has been revealed that a transition from solute diffusion controlled dendritic growth to thermal diffusion controlled dendritic growth occurs at an undercooling of about 66 K for the Co-20% Cu alloy,whereas the dendrite growth in Co-60% Cu alloy proceeds in a solute diffusion controlled mode within a large solidification temperature range,and the solutal undercooling plays a dominant role.It is thus deduced that certain distinct solidification temperature ranges may be responsible for the different solidification modes for the two alloys.
