The complexation between poly(amidoamine) (PAMAM) dendrimers and silver ion was studied in this paper. The results showed that generations and surface groups of dendrimers, reaction time, pH value, mole ratio of Ag+ /...The complexation between poly(amidoamine) (PAMAM) dendrimers and silver ion was studied in this paper. The results showed that generations and surface groups of dendrimers, reaction time, pH value, mole ratio of Ag+ /PAMAM dendrimers, as well as reaction temperature strongly influence complexation between Ag+ and PAMAM dendrimers. The maximum complexing number of Ag+ that amino , hydroxyl and carboxylate terminated PAMAM dendrimers could bind has been obtained. It has been found that the measured value of amino and hydroxyl terminated PAMAM is almost similar to the theory value, but to carboxylate terminated PAMAM, there is a discrepancy between the measured value and theory value because of the electrostatic interaction between the silver ion and carboxyl group.展开更多
文摘The complexation between poly(amidoamine) (PAMAM) dendrimers and silver ion was studied in this paper. The results showed that generations and surface groups of dendrimers, reaction time, pH value, mole ratio of Ag+ /PAMAM dendrimers, as well as reaction temperature strongly influence complexation between Ag+ and PAMAM dendrimers. The maximum complexing number of Ag+ that amino , hydroxyl and carboxylate terminated PAMAM dendrimers could bind has been obtained. It has been found that the measured value of amino and hydroxyl terminated PAMAM is almost similar to the theory value, but to carboxylate terminated PAMAM, there is a discrepancy between the measured value and theory value because of the electrostatic interaction between the silver ion and carboxyl group.
基金supported by the National Natural Science Foundation of China (21725402)the Science and Technology Commission of Shanghai Municipality (17XD1401600)+1 种基金Guangdong Innovative and Entrepreneurial Research Team Program (2016ZT06C322)supports from the Flow Cytometry Core Facility and the Confocal Microscopy Facility at ECNU
