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电沉积法制备树枝状纳米银及其电催化性能研究
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作者 苗智颖 秦霞 +1 位作者 邵学广 陈强 《纳米技术》 2016年第3期43-51,共9页
采用电沉积法室温条件下在浸入AgNO3溶液的金箔表面制备了树枝状纳米银材料,施加电压为?0.3 V、电沉积时间为60 s、电解液含KNO3 (0.1 M)和AgNO3 (20 mM),所制备的纳米材料利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射分析... 采用电沉积法室温条件下在浸入AgNO3溶液的金箔表面制备了树枝状纳米银材料,施加电压为?0.3 V、电沉积时间为60 s、电解液含KNO3 (0.1 M)和AgNO3 (20 mM),所制备的纳米材料利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射分析(XRD)、能量色散X射线光谱(EDX)等方法进行表征,根据表征结果分析了树枝状纳米银的晶体结构和形成机制;与未作任何修饰的裸Au电极相比,修饰了银纳米材料的Au电极对H2O2有明显的响应,在?0.35 V处出现明显的还原峰,证明树枝状纳米银对H2O2的还原有良好催化作用。 展开更多
关键词 电沉积法 树枝状纳米银 过氧化氢
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Controllable Electrochemical Synthesis of Silver Dendritic Nanostructures and Their SERS Properties 被引量:1
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作者 洪勋 王冠中 +2 位作者 王颖 祝巍 沈小双 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第5期596-602,622,共8页
Ag dendritic nanostructures were synthesized on fluorine-doped tin oxide covered glass sub- strates by the electrodeposition method. Results demonstrate that the size, diameter, crys- tallinity, and branch density of ... Ag dendritic nanostructures were synthesized on fluorine-doped tin oxide covered glass sub- strates by the electrodeposition method. Results demonstrate that the size, diameter, crys- tallinity, and branch density of the Ag dendrites can be controlled by the applied potential, the surfactants and the concentration of AgNO3. Three kinds of typical silver dendrites were applied as substrates of the surface enhanced Raman scattering (SERS) and one of them was able to clearly detect rhodamine 6G concentrations up to 0.1 nmol/L. The differences of the SERS spectra at these Ag dendrites confirmed that the shapes and interparticle spacings have great effect on Raman enhancement, especially the interparticle spacings. 展开更多
关键词 SILVER Dendritic nanostructure ELECTRODEPOSITION Surface enhanced Raman scattering
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