Pyrolysis of phenol formaldehyde resin has been investigated by Pyrolysis Gas Chromatography-Mass Spectroscopy at the different temperatures from 500℃ to 750℃. Its composition of pyrclysates has been analyzed. Sever...Pyrolysis of phenol formaldehyde resin has been investigated by Pyrolysis Gas Chromatography-Mass Spectroscopy at the different temperatures from 500℃ to 750℃. Its composition of pyrclysates has been analyzed. Several compounds, especially benzene, toluene, p-xylene could only be formed above 500-550℃. Howerver, peak intensities for some pbend derivatives were decreased at the higher temperature. During pyrolysis, for thermo-setting phenol formaldehyde resins, polymeric chain scissions take place as a successive removal of the monomer units from the polymeric chain. The chain scissions are followed by secondary reactions, which leads to a variety of compounds. Addition reactions can also take place among the double-bond compounds during pyrolysis.展开更多
Pyrolytic resin carbon anode for lithoum ion batteries was prepared from thermosetting phenolic resin. Pyrolysis of the primary phenolic resin and the dewatered one was studied by thermal gravimetric analysis. Structu...Pyrolytic resin carbon anode for lithoum ion batteries was prepared from thermosetting phenolic resin. Pyrolysis of the primary phenolic resin and the dewatered one was studied by thermal gravimetric analysis. Structures and characteristics of the carbon materials were determined by X-ray diffraction, Brunauer-Emmer-Teller surface area analysis and electrochemical measurements. With the increase of pyrolyzing temperature and soaking time, the resin carbon material has larger crystallite sizes of L_c and L_a, lower specific surface area, smaller irreversible capacity and higher initial coulombic efficiency. The pyrolyzing temperature and soaking time are optimized to be 1050℃ and 2h. The resin carbon anode obtained under the optimum conditions shows good electrochemical performances with reversible capacity of 387mA·h/g and initial coulombic efficiency of 69.1%.展开更多
GLARE （glass fibre/epoxy reinforced aluminum laminate） is a member of the fiber metal laminate （FML） family, and is built up of alternating metal and fiber layers. About 500 m2 GLARE is employed in each Airbus A38...GLARE （glass fibre/epoxy reinforced aluminum laminate） is a member of the fiber metal laminate （FML） family, and is built up of alternating metal and fiber layers. About 500 m2 GLARE is employed in each Airbus A380 because of the superior mechanical properties over the monolithic Muminum alloys, such as weight reduction, improved damage tolerance and higher ultimate tensile strength. Many tons of new GLARE scraps have been accumulated during the Airbus A380 manufacturing. Moreover, with the increasing plane orders of Airbus A380, more and more end-of-life （EOL） GLARE scrap will be generated after retire of planes within forty years. Thermal processing is a potential method for the material recycling and re-use from GLARE with the aim of environmental protection and economic benefits. The current study indicatdes that thermal delamination is a crucial pre-treatment step for the GLARE recycling. The decomposition behavior of the epoxy resins at elevated temperatures was investigated by using the simultaneous thermal analysis, thermogravimetry analysis （TGA） and differential scanning calorimetry （DSC）. Based on the thermal analysis results, GLARE thermal delamination experiments at refined temperatures were carried out to optimize the treatment temperature and holding time.展开更多
文摘Pyrolysis of phenol formaldehyde resin has been investigated by Pyrolysis Gas Chromatography-Mass Spectroscopy at the different temperatures from 500℃ to 750℃. Its composition of pyrclysates has been analyzed. Several compounds, especially benzene, toluene, p-xylene could only be formed above 500-550℃. Howerver, peak intensities for some pbend derivatives were decreased at the higher temperature. During pyrolysis, for thermo-setting phenol formaldehyde resins, polymeric chain scissions take place as a successive removal of the monomer units from the polymeric chain. The chain scissions are followed by secondary reactions, which leads to a variety of compounds. Addition reactions can also take place among the double-bond compounds during pyrolysis.
文摘Pyrolytic resin carbon anode for lithoum ion batteries was prepared from thermosetting phenolic resin. Pyrolysis of the primary phenolic resin and the dewatered one was studied by thermal gravimetric analysis. Structures and characteristics of the carbon materials were determined by X-ray diffraction, Brunauer-Emmer-Teller surface area analysis and electrochemical measurements. With the increase of pyrolyzing temperature and soaking time, the resin carbon material has larger crystallite sizes of L_c and L_a, lower specific surface area, smaller irreversible capacity and higher initial coulombic efficiency. The pyrolyzing temperature and soaking time are optimized to be 1050℃ and 2h. The resin carbon anode obtained under the optimum conditions shows good electrochemical performances with reversible capacity of 387mA·h/g and initial coulombic efficiency of 69.1%.
基金the Royal Netherlands Academy of Science and Arts(KNAW)(No.10CDP026)the National Outstanding Young Scientist Foundation of China (No.50825401)the National Natural Science Foundation of China(No.50821003)
文摘GLARE （glass fibre/epoxy reinforced aluminum laminate） is a member of the fiber metal laminate （FML） family, and is built up of alternating metal and fiber layers. About 500 m2 GLARE is employed in each Airbus A380 because of the superior mechanical properties over the monolithic Muminum alloys, such as weight reduction, improved damage tolerance and higher ultimate tensile strength. Many tons of new GLARE scraps have been accumulated during the Airbus A380 manufacturing. Moreover, with the increasing plane orders of Airbus A380, more and more end-of-life （EOL） GLARE scrap will be generated after retire of planes within forty years. Thermal processing is a potential method for the material recycling and re-use from GLARE with the aim of environmental protection and economic benefits. The current study indicatdes that thermal delamination is a crucial pre-treatment step for the GLARE recycling. The decomposition behavior of the epoxy resins at elevated temperatures was investigated by using the simultaneous thermal analysis, thermogravimetry analysis （TGA） and differential scanning calorimetry （DSC）. Based on the thermal analysis results, GLARE thermal delamination experiments at refined temperatures were carried out to optimize the treatment temperature and holding time.
