According to the mathematical model which describes the curing process of composites constructed from continuous fiber-reinforced, thermosetting resin matrix prepreg materials, and the consolidation of the composite, ...According to the mathematical model which describes the curing process of composites constructed from continuous fiber-reinforced, thermosetting resin matrix prepreg materials, and the consolidation of the composite, the computer code calculates the data of the process variables of the flat-plate composites cured by a specified cure cycle, provides the variation of temperature distribution, the cure degree process, the resin variation and fibers stress inside the composite, the void variation and the residual stress distribution. The mechanism of curing process is illustrated and the cure cycle of composite material is optimized.展开更多
Maintaining both the safety and serviceability of deteriorating highway bridge networks necessitates suitable BMS （bridge maintenance system） tools that can maximize cost effectiveness. Numerous experiments have bee...Maintaining both the safety and serviceability of deteriorating highway bridge networks necessitates suitable BMS （bridge maintenance system） tools that can maximize cost effectiveness. Numerous experiments have been conducted to detect the long-term mechanical properties of the epoxy resin materials used in FRP （fiber reinforced polymers） strengthening and maintenance technique. Experiments were used to develop a short-term test and construct a model that can reliably predict the long-term behavior of epoxy resin. Furthermore, FEA （finite element analysis） models were developed, using the ANSYS software, to simulate three unstrengthened and FRP strengthened prestressed concrete girder bridges of different configurations. Models simulate the original and aged properties of construction and retrofitting materials under the application of AASHTO （American Association of State Highway and Transportation Officials） fatigue truck and a site-specific fatigue truck in different scenarios. These models were used to develop the bridge performance chart for the capacity of the bridge, with and without strengthening interventions, as a BMS tool. The results show an immediate significant improvement in the concrete tensile stress with the intervention of FRP strengthening.展开更多
The photopolymerization kinetics of cycloaliphatic epoxide and oxetane with accelerators were investigated with Real-time Fourier transform infrared spectroscopy(RT-FTIR).The consumption rates of epoxy group and oxeta...The photopolymerization kinetics of cycloaliphatic epoxide and oxetane with accelerators were investigated with Real-time Fourier transform infrared spectroscopy(RT-FTIR).The consumption rates of epoxy group and oxetane group as a function of time were obtained by monitoring of the absorption peaks in the 789 cm-1 and 981 cm-1.The effect of accelerators type and the accelerating mechanism were discussed.In general,benzyl alcohol and its analogues with electron-donating substituents are useful accelerators for the cationic polymerization of cycloaliphatic epoxide and oxetane.Activated monomer mechanism and free-radical chain-induced decomposition of onium salt cationic photoinitiator account for the observed accelerating effect on the polymerization rate.展开更多
文摘According to the mathematical model which describes the curing process of composites constructed from continuous fiber-reinforced, thermosetting resin matrix prepreg materials, and the consolidation of the composite, the computer code calculates the data of the process variables of the flat-plate composites cured by a specified cure cycle, provides the variation of temperature distribution, the cure degree process, the resin variation and fibers stress inside the composite, the void variation and the residual stress distribution. The mechanism of curing process is illustrated and the cure cycle of composite material is optimized.
文摘Maintaining both the safety and serviceability of deteriorating highway bridge networks necessitates suitable BMS （bridge maintenance system） tools that can maximize cost effectiveness. Numerous experiments have been conducted to detect the long-term mechanical properties of the epoxy resin materials used in FRP （fiber reinforced polymers） strengthening and maintenance technique. Experiments were used to develop a short-term test and construct a model that can reliably predict the long-term behavior of epoxy resin. Furthermore, FEA （finite element analysis） models were developed, using the ANSYS software, to simulate three unstrengthened and FRP strengthened prestressed concrete girder bridges of different configurations. Models simulate the original and aged properties of construction and retrofitting materials under the application of AASHTO （American Association of State Highway and Transportation Officials） fatigue truck and a site-specific fatigue truck in different scenarios. These models were used to develop the bridge performance chart for the capacity of the bridge, with and without strengthening interventions, as a BMS tool. The results show an immediate significant improvement in the concrete tensile stress with the intervention of FRP strengthening.
基金Natural Science Foundation of Hubei Province of China(No.2005ABA181)National Innovation Fund for Small Technology-based Firms(No.05C26214201059)
文摘The photopolymerization kinetics of cycloaliphatic epoxide and oxetane with accelerators were investigated with Real-time Fourier transform infrared spectroscopy(RT-FTIR).The consumption rates of epoxy group and oxetane group as a function of time were obtained by monitoring of the absorption peaks in the 789 cm-1 and 981 cm-1.The effect of accelerators type and the accelerating mechanism were discussed.In general,benzyl alcohol and its analogues with electron-donating substituents are useful accelerators for the cationic polymerization of cycloaliphatic epoxide and oxetane.Activated monomer mechanism and free-radical chain-induced decomposition of onium salt cationic photoinitiator account for the observed accelerating effect on the polymerization rate.
