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抚顺镜煤和树脂煤CS_2可溶物的族组成和萃取 被引量:27
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作者 张玉贵 王宝俊 +2 位作者 田亚峻 谢克昌 魏贤勇 《中国矿业大学学报》 EI CAS CSCD 北大核心 2003年第3期267-269,273,共4页
用 CS2 对抚顺镜煤和树脂煤进行了索氏萃取 ,并用柱层析法对萃取物进行了族组分分离 ,研究了萃取物的族组成和萃取动力学特征。实验结果表明 :树脂煤的萃取率远高于镜煤 ,萃取物中烷烃和芳烃含量较高 ,而镜煤萃取物主要为非烃 ;其萃取... 用 CS2 对抚顺镜煤和树脂煤进行了索氏萃取 ,并用柱层析法对萃取物进行了族组分分离 ,研究了萃取物的族组成和萃取动力学特征。实验结果表明 :树脂煤的萃取率远高于镜煤 ,萃取物中烷烃和芳烃含量较高 ,而镜煤萃取物主要为非烃 ;其萃取过程可分为两个阶段 ,第一阶段速率比第二阶段速率大一个数量级 ;煤中低分子化合物有游离态、吸附态和共溶态三种赋存形式。 展开更多
关键词 抚顺镜 树脂煤 索氏萃取 柱层析法 族组成 萃取动力学 赋存形式 溶剂萃取
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格陵兰东北地区的富树脂煤:一种从未认识的高富油侏罗系源岩 被引量:2
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作者 J.A.Bojesen-koefoed F.G.Christiansen +1 位作者 H.I.Petersen 姜峰 《天然气地球科学》 EI CAS CSCD 1999年第1期69-75,共7页
格陵兰东北霍克斯特郎半岛地区的富树脂、高硫煤是优质的油源岩。I_H可能超过了700,其总生烃潜力估计为27×10~6bbl/km^2。这种低阶煤还没有完成生烃潜力,其整体上以壳质组显微组分为主,其中树脂为最主要的组份,占煤的70%。抽提饱... 格陵兰东北霍克斯特郎半岛地区的富树脂、高硫煤是优质的油源岩。I_H可能超过了700,其总生烃潜力估计为27×10~6bbl/km^2。这种低阶煤还没有完成生烃潜力,其整体上以壳质组显微组分为主,其中树脂为最主要的组份,占煤的70%。抽提饱和烃组分的生标分布显示出一系列特征,包括高含量的倍半萜和二萜、高Pr/Ph比值、低CPI、烷基和甲基烷基环己烷优势、低含量的三环三萜和藿烷及明显的C_(29)比C_(27)甾烷优势。泥炭沉积于静水近海岸环境,以少量的碎屑物注入和偶尔的海侵为特征,母质植物以未知的裸子植物为主。 展开更多
关键词 烃源岩 树脂煤 热解实验 成油 油矿床
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热重分析法测定煤中树脂体含量 被引量:2
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作者 谢华 姜志伟 李幼竹 《煤炭科学技术》 CAS 北大核心 1996年第8期12-13,共2页
通过对不同煤样品用热重分析方法测定其挥发量,由质量平衡原理计算确定煤中树脂体含量,实验证明该方法具有较为准确和快速的特点。
关键词 热重分析树脂体挥发量
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煤制酚醛树脂的结构特征 被引量:1
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作者 杜淑凤 《洁净煤技术》 CAS 2000年第1期25-27,共3页
采用红外光谱、核磁共振、热重分析、分子量测定等现代分析方法 ,对煤制酚醛树脂进行了全面分析 ,初步探讨了煤制酚醛树脂的结构特征 ,认为煤制酚醛树脂与线性酚醛树脂 (基本芳环骨架上有 -OH、 -CH2 等基团在 1,2 ,4位取代的酚醛树脂 ... 采用红外光谱、核磁共振、热重分析、分子量测定等现代分析方法 ,对煤制酚醛树脂进行了全面分析 ,初步探讨了煤制酚醛树脂的结构特征 ,认为煤制酚醛树脂与线性酚醛树脂 (基本芳环骨架上有 -OH、 -CH2 等基团在 1,2 ,4位取代的酚醛树脂 )有极为相似的红外谱图 ,具有相似的分子结构。煤制酚醛树脂性能好、成本低 (硝化煤可部分代替昂贵的苯酚 ) 。 展开更多
关键词 硝化酚醛树脂 结构特征 酚醛树脂
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触媒型除氧树脂去除水中溶解氧的应用研究 被引量:8
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作者 张瑛洁 张警声 《华北电力技术》 CAS 北大核心 2000年第12期5-8,共4页
介绍了一种新的催化加氢去除水中溶解氧的方法 (催化剂为国产的 CY-0 2触媒型除氧树脂 ) ,并就压力、温度、填料层高度、喷淋密度、流速、接触时间、床层高度、p H、含盐量等因素进行了实验 ,确定了应用参数。
关键词 锅炉 水处理 溶解氧 型除氧树脂
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Structural Characteristics of Mesophase Spheres Prepared from Coal Tar Pitch Modified by Phenolic Resin 被引量:10
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作者 李同起 刘秀军 +1 位作者 王成扬 王慧 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2006年第5期660-664,共5页
Mesocarbon microbeads (MCMB) were prepared from coal tar pitch modified by phenolic resin and from the same pitch modified by phenolic resin and hexamethylenetetramine at 440℃ for lh. By investigating the morpholog... Mesocarbon microbeads (MCMB) were prepared from coal tar pitch modified by phenolic resin and from the same pitch modified by phenolic resin and hexamethylenetetramine at 440℃ for lh. By investigating the morphology of mesophase spheres and the structure of the MCMB carbonized at 1000℃ for lh using scanning electron microscope (SEM) and XRD, it was found that phenolic resin accelerated the formation and coalescence of mesophase spheres. Some of the obtained MCMB were hi- or tri-spheres with the distorted microtextural carbon layers. Hexamethylenetetramine in the pitch modified by phenolic resin accelerated the condensation of phenolic resin and consequently expedited the combination of mesophase spheres, which was proved by the formation of some tetra-spheres. Owing to the cross-linkage of the additives, MCMB with complex structure were obtained. 展开更多
关键词 mesocarbon microbeads MESOPHASE phenolic resin scanning electron microscopy
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Geochemical characteristics of different maceral groups in the Huangxian Coal,China
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作者 蔡振宇 王金喜 +2 位作者 金玉洁 张洪建 金瞰昆 《Journal of Coal Science & Engineering(China)》 2004年第2期37-41,共5页
In order to research how lignite is utilized, two coal samples of seams 2 and 4 were taken from the Huangxian Basin, China. The samples were separated into vitrinite, sporinite, and resinite. Geo-chemical and pyrolysi... In order to research how lignite is utilized, two coal samples of seams 2 and 4 were taken from the Huangxian Basin, China. The samples were separated into vitrinite, sporinite, and resinite. Geo-chemical and pyrolysis methods were used to analyse three maceral groups and two seam samples. The results indicate that the resinite and sporinite groups have higher extract yields, S1, S2, HI values, and pyrolysis compounds. These differences may shed light on the usage of the Huangxian lignite. Seam 2 pro- duces more gas and oil than seam 4 does because seam 2 contains more resinite and sporinite macerals. 展开更多
关键词 MACERAL LIGNITE VITRINITE resinite PYROLYSIS Huangxian Basin
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Development and implementation of spin to stall resin at Anglo Americans Australian underground coal operations
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作者 Emery J. Canbulat I. +2 位作者 Craig P. Naylor J. Sykes A. 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2016年第1期161-168,共8页
Longwall mining is by far the most common method of underground coal extraction in Australia. The industry trends and expectations are placing increasing emphasis on the reliability and productivity of these operation... Longwall mining is by far the most common method of underground coal extraction in Australia. The industry trends and expectations are placing increasing emphasis on the reliability and productivity of these operations. The longwalls are becoming wider and longer while retreat rates are continuously increasing due to significant improvements achieved in longwall equipment reliability and automation.This increased longwall productivity is placing significant emphasis on the reliability of longwall panel development. Although there have been significant improvements in the reliability of continuous miners and hydraulic drill rigs,the traditional resin encapsulated bolt installation is still the principal method used in all major coal-producing countries around the world. Anglo American realised an opportunity existed to introduce an alternative roof bolt installation technique called ‘‘spin to stall" in Australia.Spin to stall was first introduced in Anglo American Coal in South Africa where it has been successfully used for over a decade,though implementation of South African spin to stall resin in Australia has proven to be near impossible due to a significant difference in geotechnical conditions,mining method,and,subsequently,roof bolting equipment. Therefore,a new spin to stall development project was initiated between Anglo American Coal and Jennmar Australia(SPIN2STALLò). This paper summarises the journey of this project,the results,and the successful implementation of spin to stall achieved at Grasstree Mine. 展开更多
关键词 Roof boltingRoof bolt installationSpin to stallGeotechnical engineeringStrata control
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