The study was undertaken to assess the extent of mercury contamination in the soil and three types of leaf plants in Campus AL-Mustansaryah University sites within Baghdad, Iraq, as well as to determine the relationsh...The study was undertaken to assess the extent of mercury contamination in the soil and three types of leaf plants in Campus AL-Mustansaryah University sites within Baghdad, Iraq, as well as to determine the relationship between environmental parameters and the distribution of the mercury contamination with carbon in soil samples were collected and analyzed for inorganic mercury. The highest mercury concentrations were recorded at the sites located lowest cover the plant and close to the diesel-electric generators. Mercury concentrations in leaf plant Ziziphusspina-christi higher concentration than the rest type and soil were mostly higher mercury concentration. Also ratio of carbon to coincide with the increase in the concentration of mercury in the soil of the study areas. Mercury is more biologically because of his preference to bind with carbon. This research confirms that Campus University is key areas for formation of bioavailable mercury distribution is tied to organic carbon.展开更多
Soil samples were collected from apple orchards 5,15,20,30,and 45 years old,and one adjacent forest soil was used as reference to investigate the free Cu2+ion activity in soil solution and the soil Cu fractionation in...Soil samples were collected from apple orchards 5,15,20,30,and 45 years old,and one adjacent forest soil was used as reference to investigate the free Cu2+ion activity in soil solution and the soil Cu fractionation in the solid phase following long-term application of copper fungicide,Bordeaux mixture,in apple orchards and to investigate the relationships among soil free Cu2+ions,Cu fractionation and soil microbial parameters.The total Cu concentration in the orchard soils varied from 21.8 to 141 mg kg-1,increasing with the orchard age,and the value for the reference soil was 12.5 mg kg-1.The free Cu2+ion concentrations in the soil solutions extracted by 0.01 mol L-1 KNO3 ranged from 3.13×10-8(reference)to 4.08×10-6 mol L-1(45 years-old orchard).The concentration of Cu complexed in the fulvic fraction increased with orchard age from 5.16 to 52.5 mg kg-1.This was also the case for other soil Cu fractions except the residual one.The residual soil Cu remained practically constant,ranging from 4.28 to 5.66 mg kg-1,suggesting that anthropogenic soil Cu mainly existed in the more labile active fractions.Regression analyses revealed that both the free Cu2+ions in the soil solution and the humic acid-complexed Cu fraction in the solid phase were strongly related with soil microbial parameters.展开更多
文摘The study was undertaken to assess the extent of mercury contamination in the soil and three types of leaf plants in Campus AL-Mustansaryah University sites within Baghdad, Iraq, as well as to determine the relationship between environmental parameters and the distribution of the mercury contamination with carbon in soil samples were collected and analyzed for inorganic mercury. The highest mercury concentrations were recorded at the sites located lowest cover the plant and close to the diesel-electric generators. Mercury concentrations in leaf plant Ziziphusspina-christi higher concentration than the rest type and soil were mostly higher mercury concentration. Also ratio of carbon to coincide with the increase in the concentration of mercury in the soil of the study areas. Mercury is more biologically because of his preference to bind with carbon. This research confirms that Campus University is key areas for formation of bioavailable mercury distribution is tied to organic carbon.
基金Supported by the National Natural Science Foundation of China(Nos.40871115 and 40671095)
文摘Soil samples were collected from apple orchards 5,15,20,30,and 45 years old,and one adjacent forest soil was used as reference to investigate the free Cu2+ion activity in soil solution and the soil Cu fractionation in the solid phase following long-term application of copper fungicide,Bordeaux mixture,in apple orchards and to investigate the relationships among soil free Cu2+ions,Cu fractionation and soil microbial parameters.The total Cu concentration in the orchard soils varied from 21.8 to 141 mg kg-1,increasing with the orchard age,and the value for the reference soil was 12.5 mg kg-1.The free Cu2+ion concentrations in the soil solutions extracted by 0.01 mol L-1 KNO3 ranged from 3.13×10-8(reference)to 4.08×10-6 mol L-1(45 years-old orchard).The concentration of Cu complexed in the fulvic fraction increased with orchard age from 5.16 to 52.5 mg kg-1.This was also the case for other soil Cu fractions except the residual one.The residual soil Cu remained practically constant,ranging from 4.28 to 5.66 mg kg-1,suggesting that anthropogenic soil Cu mainly existed in the more labile active fractions.Regression analyses revealed that both the free Cu2+ions in the soil solution and the humic acid-complexed Cu fraction in the solid phase were strongly related with soil microbial parameters.