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核/壳型含硅苯丙乳液的合成与研究 被引量:5
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作者 张凯 程永清 吕晓燕 《中国胶粘剂》 CAS 2008年第12期9-13,共5页
以甲基丙烯酸甲酯(MMA)和苯乙烯(St)为核单体,丙烯酸丁酯(BA)、丙烯酸(AA)和γ-(2,3-环氧丙氧)丙基三甲氧基硅烷(KH-560)为壳单体,制备出具有核/壳型结构的含硅苯丙乳液。采用激光粒度分析法、差示扫描量热法(DSC)、红外光谱(FT-IR)法... 以甲基丙烯酸甲酯(MMA)和苯乙烯(St)为核单体,丙烯酸丁酯(BA)、丙烯酸(AA)和γ-(2,3-环氧丙氧)丙基三甲氧基硅烷(KH-560)为壳单体,制备出具有核/壳型结构的含硅苯丙乳液。采用激光粒度分析法、差示扫描量热法(DSC)、红外光谱(FT-IR)法和透射电镜(TEM)等测试手段,研究了软硬单体配比、乳化剂、引发剂和交联剂KH-560用量对乳液及其胶膜性能的影响。研究结果表明,当w(引发剂)=0.5%、m(BA)∶m(St)∶m(MMA)=1.5∶0.5∶1.0、w(混合乳化剂)=3.0%和w(KH-560)=16%时,制取的含硅苯丙乳液稳定性好、平均粒径小且分布较窄,适度交联可提高乳胶膜的耐水性和硬度。 展开更多
关键词 苯丙乳液 有机硅树脂 核/壳型结构 耐水性
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反相悬浮聚合法制备“核/壳”型高吸水及耐盐性树脂
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作者 童晓梅 张敏 +1 位作者 袁亮 任庆海 《日用化学品科学》 CAS 2007年第11期15-18,共4页
通过交联剂和复配改性剂的改性作用,用反相悬浮聚合法,制备了"核/壳"结构的聚合物,产物大大提高了吸水性及耐盐性。实验探讨了工艺条件,通过红外光谱分析产物结构及其吸水机理。
关键词 核/结构 反相悬浮聚合法 高吸水性 耐盐性 复配改性剂
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A short revisit to Kuo-Brown effective interactions 被引量:1
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作者 WANG XiaoBao DONG GuoXiang 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2015年第10期18-22,共5页
This paper is a short revisit to Kuo-Brown effective interaction derived from the Hamada-Johnston nucleon-nucleon potential, done by Gerry Brown and Tom Kuo. This effective interaction, derived in year 1966, is the fi... This paper is a short revisit to Kuo-Brown effective interaction derived from the Hamada-Johnston nucleon-nucleon potential, done by Gerry Brown and Tom Kuo. This effective interaction, derived in year 1966, is the first attempt to describe nuclear structure properties from the free nucleon-nucleon potential. Nowadays much progress has been achieved for the effective interactions in shell model. We would compare the effective interactions obtained in the 1966 paper with up-to-date shell-model interactions in sd-shell and pf-shell model space. Recent knowledge of effective interactions on nuclear structure, can also be traced in the KuoBrown effective interaction, i.e., the universal roles of central and tensor forces, which reminds us that such discovery should be noticed much earlier. 展开更多
关键词 shell model effective interactions tensor force
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Structure of high spin state in proton-rich ^(74,76,78)Kr isotopes:A projected shell model description 被引量:1
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作者 LIU YanXin YU ShaoYing SHEN CaiWan 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2015年第1期32-37,共6页
The N≈Z nuclei in the mass A^80 region has been researched because of an abundance of nuclear structure phenomena.The projected shell model(PSM)was adopted to investigate the structure of high spin state in proton-ri... The N≈Z nuclei in the mass A^80 region has been researched because of an abundance of nuclear structure phenomena.The projected shell model(PSM)was adopted to investigate the structure of high spin state in proton-rich 74,76,78Kr isotopes including yrast spectra,moment of inertia,electric quadrupole transitions and the behavior of single particle.The calculated results are in good agreement with available data and the shape coexistence in low-spin is also discussed. 展开更多
关键词 projected shell model high spin state moment of inertia electric quadrupole transition
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Rotational structure of the odd-proton nuclide ^(171)Tm:A projected shell model study
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作者 LIU YanXin CHEN FangQi +1 位作者 YU ShaoYing SUN Yang 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2015年第5期76-81,共6页
Deformed odd-mass nuclei are ideal examples where the interplay between single-particle and collective degrees of freedom can be studied. Inspired by the recent experimental high-spin data in the odd-proton nuclide 17... Deformed odd-mass nuclei are ideal examples where the interplay between single-particle and collective degrees of freedom can be studied. Inspired by the recent experimental high-spin data in the odd-proton nuclide 171 Tm, we perform projected shell model(PSM) calculations to investigate structure of the ground band and other bands based on isomeric states. In addi- tion to the usual quadrupole-quadrupole force in the Hamiltonian, we employ the hexadecapole-hexadecapole(HH) interac- tion, in a self-consistent way with the hexadecapole deformation of the deformed basis. It is found that the known experi- mental data can be well described by the PSM calculation. The effect of the HH force on the quasiparticle isomeric states is discussed. 展开更多
关键词 rotational band isomeric state hexadecapole-hexadecapole interaction projected shell model
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Analytical Derivations of Single-Particle Matrix Elements in Nuclear Shell Model
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作者 Aziz H.Fatah R.A.Radhi Nzar R.Abdullah 《Communications in Theoretical Physics》 SCIE CAS CSCD 2016年第7期104-114,共11页
We present analytical method to calculate single particle matrix elements used in atomic and nuclear physics. We show seven different formulas of matrix elements of the operator f(r)d_r^m where f(r) = r~μ, r~μjJ(qr)... We present analytical method to calculate single particle matrix elements used in atomic and nuclear physics. We show seven different formulas of matrix elements of the operator f(r)d_r^m where f(r) = r~μ, r~μjJ(qr), V(r)corresponding to the Gaussian and the Yukawa potentials used in nuclear shell models and nuclear structure. In addition,we take into account a general integral formula of the matrix element 〈 n′ l′|f(r) d_r^(m) |n l〉 that covers all seven matrix elements obtained analytically. 展开更多
关键词 nuclear structure shell model nuclear matrix elements and nuclear structure
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