Pt monolayer-based core-shell catalysts have garnered significant interest for the application of low temperature fuel cell technology as their use may enable a decreased loading of Pt while still providing sufficient...Pt monolayer-based core-shell catalysts have garnered significant interest for the application of low temperature fuel cell technology as their use may enable a decreased loading of Pt while still providing sufficient current density to meet volumetric requirements. One promising candidate in this class of materials is a Pd@Pt core-shell catalyst, which shows enhanced activity toward oxygen reduction reaction(ORR). One concern with the use of Pd@Pt, however, is the durability of the core-shell structure as Pd atoms are thermodynamically favored to migrate to the surface. The pathway of the migration has not been systematically studied. The current study explores the stability of this structure to thermal annealing and probes the effect of this heat treatment on the catalyst surface structure and its oxygen reduction activity. It was found that surface alloying between Pd and Pt occurs at temperatures as low as 200 °C, and significantly alters the structure and ORR catalytic activity in the range of 200–300 °C. Our results shed lights on the thermal induced interatomic diffusion in all core-shell and thin film structures.展开更多
In a simple hadronie model, the two-photon exchange contributions to the single spin asymmetries for the nucleon and the 3He are estimated. The results show that the elastic contributions of two-photon exchange to the...In a simple hadronie model, the two-photon exchange contributions to the single spin asymmetries for the nucleon and the 3He are estimated. The results show that the elastic contributions of two-photon exchange to the single spin asymmetries for the nucleon are rather small while those for the 3He are relatively large. Besides the strong angular dependence, the two-photon contributions to the single transfer. spin asymmetry for the 3He are very sensitive to the momentum展开更多
We derive the exchange currents of pseudoscalar, vector, and scalar mesons from Feynman diagrams, and use them to calculate the magnetic form factors of nucleon and △(1232). The magnetic moments and electromagnetic r...We derive the exchange currents of pseudoscalar, vector, and scalar mesons from Feynman diagrams, and use them to calculate the magnetic form factors of nucleon and △(1232). The magnetic moments and electromagnetic radii are obtained by using those form factors and the parameters determined from the masses of nucleon and △(1232).We find the magnetic moments and electromagnetic radii of nucleon and △(1232) can be produced very well in the extended Goldstone-Boson-exchange model in which all of pseudoscalar, vector, and scalar meson nonet are included.The magnetic moments of △(1232) are closer to experiment values and results from lattice calculation than the results obtained by the model without other mesons except for pion and sigma.展开更多
The adsorption characteristics of inosine from fermentation solution on anion exchange resin under the condition of different PH, resin type are investigated. Besides 3 the desorption conditions are studied under diff...The adsorption characteristics of inosine from fermentation solution on anion exchange resin under the condition of different PH, resin type are investigated. Besides 3 the desorption conditions are studied under different temperature.The adsorption and desorption mechanism are described to obtain the optimumtechnological condition of inosine extraction.展开更多
As a critical component of alkaline fuel cells, anion exchange membranes determine the energy efficiency, output power density and the long term stability. Recently, the anion exchange membranes with gemini-cation sid...As a critical component of alkaline fuel cells, anion exchange membranes determine the energy efficiency, output power density and the long term stability. Recently, the anion exchange membranes with gemini-cation side chains exhibit superior ion conductivity due to their good nanophase separation. However, the costly and complicated synthesis limits their scaling up and commercialization. To address this problem, a convenient synthetic procedure under mild conditions is well developed. A tertiary amine precursor is introduced onto the polymer by the nucleophilic substitution reaction to avoid the conventional chloro/bromo-methylation. Followed by a simple Menshutkin reaction with 6- bromo-N,N,N-trimethylhexan-1-am inium bromide, the polym er electrolytes are obtained in a high yield. The resulting anion exchange membranes with high conductivity, good fuel cell performance and restricted swelling suggest the potential for the application in fuel cell devices.展开更多
文摘Pt monolayer-based core-shell catalysts have garnered significant interest for the application of low temperature fuel cell technology as their use may enable a decreased loading of Pt while still providing sufficient current density to meet volumetric requirements. One promising candidate in this class of materials is a Pd@Pt core-shell catalyst, which shows enhanced activity toward oxygen reduction reaction(ORR). One concern with the use of Pd@Pt, however, is the durability of the core-shell structure as Pd atoms are thermodynamically favored to migrate to the surface. The pathway of the migration has not been systematically studied. The current study explores the stability of this structure to thermal annealing and probes the effect of this heat treatment on the catalyst surface structure and its oxygen reduction activity. It was found that surface alloying between Pd and Pt occurs at temperatures as low as 200 °C, and significantly alters the structure and ORR catalytic activity in the range of 200–300 °C. Our results shed lights on the thermal induced interatomic diffusion in all core-shell and thin film structures.
文摘In a simple hadronie model, the two-photon exchange contributions to the single spin asymmetries for the nucleon and the 3He are estimated. The results show that the elastic contributions of two-photon exchange to the single spin asymmetries for the nucleon are rather small while those for the 3He are relatively large. Besides the strong angular dependence, the two-photon contributions to the single transfer. spin asymmetry for the 3He are very sensitive to the momentum
文摘We derive the exchange currents of pseudoscalar, vector, and scalar mesons from Feynman diagrams, and use them to calculate the magnetic form factors of nucleon and △(1232). The magnetic moments and electromagnetic radii are obtained by using those form factors and the parameters determined from the masses of nucleon and △(1232).We find the magnetic moments and electromagnetic radii of nucleon and △(1232) can be produced very well in the extended Goldstone-Boson-exchange model in which all of pseudoscalar, vector, and scalar meson nonet are included.The magnetic moments of △(1232) are closer to experiment values and results from lattice calculation than the results obtained by the model without other mesons except for pion and sigma.
文摘The adsorption characteristics of inosine from fermentation solution on anion exchange resin under the condition of different PH, resin type are investigated. Besides 3 the desorption conditions are studied under different temperature.The adsorption and desorption mechanism are described to obtain the optimumtechnological condition of inosine extraction.
基金supported by the National Natural Science Foundation of China (21720102003, 91534203 and 21522607)the Fundamental Research Funds for the Central Universities (WK2060190072 and WK2340000066)
文摘As a critical component of alkaline fuel cells, anion exchange membranes determine the energy efficiency, output power density and the long term stability. Recently, the anion exchange membranes with gemini-cation side chains exhibit superior ion conductivity due to their good nanophase separation. However, the costly and complicated synthesis limits their scaling up and commercialization. To address this problem, a convenient synthetic procedure under mild conditions is well developed. A tertiary amine precursor is introduced onto the polymer by the nucleophilic substitution reaction to avoid the conventional chloro/bromo-methylation. Followed by a simple Menshutkin reaction with 6- bromo-N,N,N-trimethylhexan-1-am inium bromide, the polym er electrolytes are obtained in a high yield. The resulting anion exchange membranes with high conductivity, good fuel cell performance and restricted swelling suggest the potential for the application in fuel cell devices.
