The electrodeposition behaviors of nickel on glassy carbon（GC） and carbon steel（CS） electrodes were investigated in the14.3%-85.7%（mole fraction） betaine.HCl ethylene glycol（EG） ionic liquid using cyclic volta...The electrodeposition behaviors of nickel on glassy carbon（GC） and carbon steel（CS） electrodes were investigated in the14.3%-85.7%（mole fraction） betaine.HCl ethylene glycol（EG） ionic liquid using cyclic voltammetry and chronoamperometry.The results indicated that the reduction of Ni（Ⅱ） on CS electrode via a diffusion-controlled quasi-reversible process was much more facile and easier than that occurred on GC electrode,which followed a diffusion-controlled three-dimensional instantaneous nucleation and growth.Scanning electron microscopy was used to observe that the deposit was dense and contained fine crystallites with average size of（80±4） nm.Energy dispersive spectrometer analysis showed that the obtained deposit was metallic nickel.X-ray diffraction spectroscopy indicated that（111） plane was the most preferred crystal orientation.The nickel deposit was luminous and bright,and had good adhesion with the CS substrate.展开更多
A mathematical model considering free nuclei was developed to reveal the migration behavior of the free nuclei. Numerical simulation results show that most of the nuclei on the top surface of the melt move downwards a...A mathematical model considering free nuclei was developed to reveal the migration behavior of the free nuclei. Numerical simulation results show that most of the nuclei on the top surface of the melt move downwards and distribute randomly inside the Al melt, which induces more nucleation sites resulting in grain refinement. At the same time, the effect of nuclei size on the nuclei distribution and refinement employing electric current pulse （ECP） was also investigated. The smaller nuclei migrate a short distance with the Al melt at lower speed. But for the larger nuclei, the migration downwards with higher speed benefits the refinement of interior grains of the melt. The research results help to better understand the refinement process and provide a more reasonable explanation of the grain refinement mechanism using ECP.展开更多
The countermeasures are the actions that should be taken, after the occurrence of a nuclear accident to protect the public against the associated risks. These actions may be represented by sheltering, evacuation, dist...The countermeasures are the actions that should be taken, after the occurrence of a nuclear accident to protect the public against the associated risks. These actions may be represented by sheltering, evacuation, distribution of stable iodine tablets and/or relocation. This study represents a comprehensive probabilistic study to investigate the role of the adoption of the countermeasures in case of a hypothetical accident of type LOCA for nuclear power plant of PWR （1000 Mw）. The effective doses in different organs, short and long health effects, and the associated risks are calculated with and without countermeasures. In addition, the overall costs of the accident and the costs of countermeasures are estimated which represent our first trials to know how much the proposed accident cost. The results showed that, the area around the site requires early and late countermeasures action after the accident especially in the downwind sectors. For late countermeasures, the duration time of relocation ranged from about two to 10 years. The adoption of the countermeasures increases the costs of emergency plan by 40% but reduces the risk associated the accident.展开更多
The paper expresses the view that China's essential way out for developing nuclear power lies in localization of manu facture, based on her technical level and capability in designing and manufacturing nuclear pow...The paper expresses the view that China's essential way out for developing nuclear power lies in localization of manu facture, based on her technical level and capability in designing and manufacturing nuclear power equipment. Moreover, the paper opines that domestically manufactured nuclear power equipment has a certain competitive potential with respect to quality and price, the crux lying in the neces sity of reforming the management system of nuclear power.展开更多
Nucleation mechanism and technological process for Ni-Fe co-deposition with a relatively high Fe^(2+)concentration surrounded were described,and the effects of Fe^(2+) concentration,solution pH,temperature,and sodium ...Nucleation mechanism and technological process for Ni-Fe co-deposition with a relatively high Fe^(2+)concentration surrounded were described,and the effects of Fe^(2+) concentration,solution pH,temperature,and sodium dodecyl sulfonate concentration were investigated.Electrochemical experiments demonstrate that iron's electrodeposition plays a leading role in the Ni-Fe co-deposition process,and the co-deposition nucleation mechanism accords with a progressive nucleation.Temperature increase does favor in increasing nickel content in the ferronickel(Ni-Fe co-deposition products),while Fe^(2+) concentration increase does not.When solution pH is higher than 3.5,nickel content in the ferronickel decreases with pH because of the hydrolysis of Fe^(2+).With the current density of 180 A/m^2,Na_2SO_4 concentration of 100 g/L and Ni^(2+) concentration of 60 g/L,a smooth ferronickel deposit containing 96.21% Ni can be obtained under the conditions of temperature of 60 °C,Fe^(2+) concentration of 0.3 g/L,solution pH of 3 and sodium dodecyl sulfonate concentration of 40 mg/L.展开更多
Indonesia has been planning to build Nuclear Power Plants （NPPs） since the 1970＇s. Nevertheless, due to some problems the program is immaterialized so far. Recently, in anticipation of domestic energy crisis, nucle...Indonesia has been planning to build Nuclear Power Plants （NPPs） since the 1970＇s. Nevertheless, due to some problems the program is immaterialized so far. Recently, in anticipation of domestic energy crisis, nuclear program is revitalized. In the current situation, nuclear program is facing various challenges, including public perception, political instability, brain drain of skilled people, governmental support, and international confidence. In coping with these challenges, several efforts have been done. For instance, to deals with public perception, BATAN is making continuous effort in convincing the public and the decision makers to be aware of the necessity of nuclear power. In line with such effort, several milestones of the nuclear power programme have also been achieved. One of the most important milestones is the enactment of Act No. 10/1997 on Nuclear Energy. The Act demands the establishment of independent regulatory body separated from promoting body.展开更多
We propose and study a spin-orbit interaction based mechanism to actively cool down the torsional vibrationof a nanomechanical resonator made by semiconductor materials.We show that the spin-orbit interactions of elec...We propose and study a spin-orbit interaction based mechanism to actively cool down the torsional vibrationof a nanomechanical resonator made by semiconductor materials.We show that the spin-orbit interactions of electronscan induce a coherent coupling between the electron spins and the torsional modes of nanomechanical vibration.Thiscoupling leads to an active cooling for the torsional modes through the dynamical thermalization of the resonator by thespin ensemble.展开更多
Palladium（II） and chloride ions tend to form complexes in aqueous solution. Both theoretical and experimental （by UV spec- trum） results indicate that there are four complexes formed in aqueous solution containing...Palladium（II） and chloride ions tend to form complexes in aqueous solution. Both theoretical and experimental （by UV spec- trum） results indicate that there are four complexes formed in aqueous solution containing 3 mol/L hydrochloric acid and 20 mmol/L PdC12. This work evaluates the kinetics of electrochemical deposition of palladium on a Platinum electrode. For this purpose, palladium electrodeposition was investigated by means of cyclic voltammetry （CV）, potentiostatic current-time tran- sients （CTTs） and Tafel curve. By CTTs curves, the regions corresponding to the charge transfer control, mixed control and diffusion control were identified. In the diffusion control region, palladium electrodeposition mechanism was characterized as progressive nucleation with three-dimensional （3D） growth under diffusion control; as for the mixed control region, an adsorp- tion （1Ads）, ion transfer （liT）, and nucleation and growth （ING） model were proposed to analyze the current-time transients quan- titatively, which could separate the IAds, lit and IN~ perfectly.展开更多
基金Projects(51274108,21263007,51204080)supported by the National Natural Science Foundation of ChinaProject(2011FA009)supported by the Applied Research Foundation of Yunnan Province,ChinaProject(14118441)supported by the Talents Cultivation Foundation of Kunming University of Science and Technology,China
文摘The electrodeposition behaviors of nickel on glassy carbon（GC） and carbon steel（CS） electrodes were investigated in the14.3%-85.7%（mole fraction） betaine.HCl ethylene glycol（EG） ionic liquid using cyclic voltammetry and chronoamperometry.The results indicated that the reduction of Ni（Ⅱ） on CS electrode via a diffusion-controlled quasi-reversible process was much more facile and easier than that occurred on GC electrode,which followed a diffusion-controlled three-dimensional instantaneous nucleation and growth.Scanning electron microscopy was used to observe that the deposit was dense and contained fine crystallites with average size of（80±4） nm.Energy dispersive spectrometer analysis showed that the obtained deposit was metallic nickel.X-ray diffraction spectroscopy indicated that（111） plane was the most preferred crystal orientation.The nickel deposit was luminous and bright,and had good adhesion with the CS substrate.
基金Project(SELF-2011-01)supported by the Open Project of Shanghai Key Laboratory of Modern Metallurgy and Materials Processing,ChinaProjects(51204109,51035004)supported by the National Natural Science Foundation of China
文摘A mathematical model considering free nuclei was developed to reveal the migration behavior of the free nuclei. Numerical simulation results show that most of the nuclei on the top surface of the melt move downwards and distribute randomly inside the Al melt, which induces more nucleation sites resulting in grain refinement. At the same time, the effect of nuclei size on the nuclei distribution and refinement employing electric current pulse （ECP） was also investigated. The smaller nuclei migrate a short distance with the Al melt at lower speed. But for the larger nuclei, the migration downwards with higher speed benefits the refinement of interior grains of the melt. The research results help to better understand the refinement process and provide a more reasonable explanation of the grain refinement mechanism using ECP.
文摘The countermeasures are the actions that should be taken, after the occurrence of a nuclear accident to protect the public against the associated risks. These actions may be represented by sheltering, evacuation, distribution of stable iodine tablets and/or relocation. This study represents a comprehensive probabilistic study to investigate the role of the adoption of the countermeasures in case of a hypothetical accident of type LOCA for nuclear power plant of PWR （1000 Mw）. The effective doses in different organs, short and long health effects, and the associated risks are calculated with and without countermeasures. In addition, the overall costs of the accident and the costs of countermeasures are estimated which represent our first trials to know how much the proposed accident cost. The results showed that, the area around the site requires early and late countermeasures action after the accident especially in the downwind sectors. For late countermeasures, the duration time of relocation ranged from about two to 10 years. The adoption of the countermeasures increases the costs of emergency plan by 40% but reduces the risk associated the accident.
文摘The paper expresses the view that China's essential way out for developing nuclear power lies in localization of manu facture, based on her technical level and capability in designing and manufacturing nuclear power equipment. Moreover, the paper opines that domestically manufactured nuclear power equipment has a certain competitive potential with respect to quality and price, the crux lying in the neces sity of reforming the management system of nuclear power.
基金Project(51574135)supported by the National Natural Science Foundation of ChinaProject(KKPT201563022)supported by Collaborative Innovation Center of Kunming University of Science and Technology,China
文摘Nucleation mechanism and technological process for Ni-Fe co-deposition with a relatively high Fe^(2+)concentration surrounded were described,and the effects of Fe^(2+) concentration,solution pH,temperature,and sodium dodecyl sulfonate concentration were investigated.Electrochemical experiments demonstrate that iron's electrodeposition plays a leading role in the Ni-Fe co-deposition process,and the co-deposition nucleation mechanism accords with a progressive nucleation.Temperature increase does favor in increasing nickel content in the ferronickel(Ni-Fe co-deposition products),while Fe^(2+) concentration increase does not.When solution pH is higher than 3.5,nickel content in the ferronickel decreases with pH because of the hydrolysis of Fe^(2+).With the current density of 180 A/m^2,Na_2SO_4 concentration of 100 g/L and Ni^(2+) concentration of 60 g/L,a smooth ferronickel deposit containing 96.21% Ni can be obtained under the conditions of temperature of 60 °C,Fe^(2+) concentration of 0.3 g/L,solution pH of 3 and sodium dodecyl sulfonate concentration of 40 mg/L.
文摘Indonesia has been planning to build Nuclear Power Plants （NPPs） since the 1970＇s. Nevertheless, due to some problems the program is immaterialized so far. Recently, in anticipation of domestic energy crisis, nuclear program is revitalized. In the current situation, nuclear program is facing various challenges, including public perception, political instability, brain drain of skilled people, governmental support, and international confidence. In coping with these challenges, several efforts have been done. For instance, to deals with public perception, BATAN is making continuous effort in convincing the public and the decision makers to be aware of the necessity of nuclear power. In line with such effort, several milestones of the nuclear power programme have also been achieved. One of the most important milestones is the enactment of Act No. 10/1997 on Nuclear Energy. The Act demands the establishment of independent regulatory body separated from promoting body.
基金NSFC under Grant Nos.90203018,10474104,10574077,and 60433050NFRPC under Grant Nos.2006CB921206,2006CBOL0601,2006AA06Z104,and 2005CB724508
文摘We propose and study a spin-orbit interaction based mechanism to actively cool down the torsional vibrationof a nanomechanical resonator made by semiconductor materials.We show that the spin-orbit interactions of electronscan induce a coherent coupling between the electron spins and the torsional modes of nanomechanical vibration.Thiscoupling leads to an active cooling for the torsional modes through the dynamical thermalization of the resonator by thespin ensemble.
基金supported by the National Natural Science Foundation of China(91026019,91126006)
文摘Palladium（II） and chloride ions tend to form complexes in aqueous solution. Both theoretical and experimental （by UV spec- trum） results indicate that there are four complexes formed in aqueous solution containing 3 mol/L hydrochloric acid and 20 mmol/L PdC12. This work evaluates the kinetics of electrochemical deposition of palladium on a Platinum electrode. For this purpose, palladium electrodeposition was investigated by means of cyclic voltammetry （CV）, potentiostatic current-time tran- sients （CTTs） and Tafel curve. By CTTs curves, the regions corresponding to the charge transfer control, mixed control and diffusion control were identified. In the diffusion control region, palladium electrodeposition mechanism was characterized as progressive nucleation with three-dimensional （3D） growth under diffusion control; as for the mixed control region, an adsorp- tion （1Ads）, ion transfer （liT）, and nucleation and growth （ING） model were proposed to analyze the current-time transients quan- titatively, which could separate the IAds, lit and IN~ perfectly.
