Fluid typing from nuclear magnetic resonance(NMR)logging in oil-wet tight sandstone reservoirs is proving to be diffi cult;thus,research into the NMR logging response mechanism and analysis methods is critical.The NMR...Fluid typing from nuclear magnetic resonance(NMR)logging in oil-wet tight sandstone reservoirs is proving to be diffi cult;thus,research into the NMR logging response mechanism and analysis methods is critical.The NMR response mechanism and theoretical method were investigated based on the oil-water distribution in the pores under oil-wet conditions.The data processing method is studied based on NMR dual-TW activation principle,and the equations of macroscopic magnetization vector,fl uid volume,and relaxation parameters are derived,which is a nonlinear inversion problem.The simulated annealing algorithm is used,and the fl uid relaxation parameters,oil volume,and water volume of the fl ushing zone are calculated.An ideal reservoir model is set up,and simulation results indicate that the above-mentioned NMR relaxation theory and algorithms are valid.A case study is conducted in Huanjiang Oilfi eld in the Ordos Basin,China.The calculated oil saturation of the fl ushing zone is consistent with the oil saturation calculated using the Archie formula,and the test results indicated that the new method is applicable.Moreover,the fl uid-typing cross-plot combined with oil test data is constructed on the basis of the saturation of the fl ushing zone,improving the accuracy of fl uid identifi cation.展开更多
The interaction between N, N′-bis（dimethyldodecyl）-1,6-hexanediammoniumdibromide （G12-6-12） and cetyltrimethylammonium bromide （CTAB） in D20 aqueous medium has been investigated by NMR at 298 K. The G12-6-12 an...The interaction between N, N′-bis（dimethyldodecyl）-1,6-hexanediammoniumdibromide （G12-6-12） and cetyltrimethylammonium bromide （CTAB） in D20 aqueous medium has been investigated by NMR at 298 K. The G12-6-12 and CTAB are about 0.773 and measured critical micelle concentration （cmc） of 0.668 mmol/L, respectively. The cmc^＊ （cmc of mixture） values are less than CMC^＊ （cmc of ideally mixed solution） in the mixed system, and the interaction parameter βM〈0 at different molar fractions α of G12-6-12 in the mixed systems, but just when α≤0.3, cmc^＊ values are much smaller than CMC^＊, and βM satisfies the relation of ｜βM｜〉｜ln（cmc1/cmc2）｜ （cmcl： cmc of pure G12-6-12 and cmc2： cmc Of pure CTAB）. The results indicate that there exists synergism between G12-6-12 and CTAB, and they can form mixed micelles, which is further proven by 2D NOESY and self-diffusion coefficient D experiments. There are intermolecular cross peaks between G12-6-12 and CTAB in 2D NOESY, and the radius of micelles in mixed solution is bigger than that in G12-6-12 pure solution in D experiments, indicating there are mixed micelles. However, when α〉0.3, we find that cmc^＊≈CMC^＊, βM≈0, obviously, the two surfactants are almost ideal mixing fitting the pseudo-phase separation model and regular solution theory.展开更多
基金This work was supported by the National Natural Science Foundation of China(41774144)the National Science and Technology Major Project“The Demonstration Project for Exploration and Development of Large Lithostratigraphic Oil and Gas Reservoirs in the Ordos Basin(2016ZX05050).
文摘Fluid typing from nuclear magnetic resonance(NMR)logging in oil-wet tight sandstone reservoirs is proving to be diffi cult;thus,research into the NMR logging response mechanism and analysis methods is critical.The NMR response mechanism and theoretical method were investigated based on the oil-water distribution in the pores under oil-wet conditions.The data processing method is studied based on NMR dual-TW activation principle,and the equations of macroscopic magnetization vector,fl uid volume,and relaxation parameters are derived,which is a nonlinear inversion problem.The simulated annealing algorithm is used,and the fl uid relaxation parameters,oil volume,and water volume of the fl ushing zone are calculated.An ideal reservoir model is set up,and simulation results indicate that the above-mentioned NMR relaxation theory and algorithms are valid.A case study is conducted in Huanjiang Oilfi eld in the Ordos Basin,China.The calculated oil saturation of the fl ushing zone is consistent with the oil saturation calculated using the Archie formula,and the test results indicated that the new method is applicable.Moreover,the fl uid-typing cross-plot combined with oil test data is constructed on the basis of the saturation of the fl ushing zone,improving the accuracy of fl uid identifi cation.
文摘The interaction between N, N′-bis（dimethyldodecyl）-1,6-hexanediammoniumdibromide （G12-6-12） and cetyltrimethylammonium bromide （CTAB） in D20 aqueous medium has been investigated by NMR at 298 K. The G12-6-12 and CTAB are about 0.773 and measured critical micelle concentration （cmc） of 0.668 mmol/L, respectively. The cmc^＊ （cmc of mixture） values are less than CMC^＊ （cmc of ideally mixed solution） in the mixed system, and the interaction parameter βM〈0 at different molar fractions α of G12-6-12 in the mixed systems, but just when α≤0.3, cmc^＊ values are much smaller than CMC^＊, and βM satisfies the relation of ｜βM｜〉｜ln（cmc1/cmc2）｜ （cmcl： cmc of pure G12-6-12 and cmc2： cmc Of pure CTAB）. The results indicate that there exists synergism between G12-6-12 and CTAB, and they can form mixed micelles, which is further proven by 2D NOESY and self-diffusion coefficient D experiments. There are intermolecular cross peaks between G12-6-12 and CTAB in 2D NOESY, and the radius of micelles in mixed solution is bigger than that in G12-6-12 pure solution in D experiments, indicating there are mixed micelles. However, when α〉0.3, we find that cmc^＊≈CMC^＊, βM≈0, obviously, the two surfactants are almost ideal mixing fitting the pseudo-phase separation model and regular solution theory.
