In order to investigate the feasibility of BDS/GPS in the deformation monitoring of long-span bridges,analysis and research on aspects like number of visible satellites,PDOP value and monitoring precision are carried ...In order to investigate the feasibility of BDS/GPS in the deformation monitoring of long-span bridges,analysis and research on aspects like number of visible satellites,PDOP value and monitoring precision are carried out. To analyze daily deformation characteristics of steel box girder bridge,observation data for 48 consecutive hours is computed by self-programmed software. Experiment results show that the monitoring-points on the bridge demonstrate obvious periodicity and recoverability in vertical and horizontal directions,meanwhile,changes in the elevation direction are relatively stable. The deformation-monitoring results of BDS/GPS combination system and GPS single system show good consistency. However,in a complex environment of the bridge,especially under the condition that satellite signals are severely affected,the advantages of BDS/GPS combination over GPS single system are more obvious.展开更多
Two couples of enantiomerically pure chiral cyano-bridged heterobimetallic one-dimensional (1D) chain complexes: [Mn((R,R)-Salphen)Fe(Tp)(CN)3],, (1) and [Mn((S,S)-Salphen)Te(Tp)(CN)3]n (2) (Salphen = N,N'-l,2-dip...Two couples of enantiomerically pure chiral cyano-bridged heterobimetallic one-dimensional (1D) chain complexes: [Mn((R,R)-Salphen)Fe(Tp)(CN)3],, (1) and [Mn((S,S)-Salphen)Te(Tp)(CN)3]n (2) (Salphen = N,N'-l,2-diphenylethylenebis (salicylideneiminato) dianion, Tp = tris(pyrazolyl) hydroborate), [Mn((R,R)-Salphen)Fe(Tp*)(CN)3·2H2O],, (3) and [Mn((S,S)-Salphen)Fe(Tp*)(CN)3.2H20],, (4) (Tp* = hydridotris (3,5-dimethylpyrazol-l-yl) borate), have been successfully synthesized by the reactions of MnⅢ schiff-base complexes with the tricyanometalate building block, [(Lxp)Fe(CN)3]- (Lyp = Tp or Tp*). All complexes are made up of neutral cyano-bridged zigzag double chains with (-Fe-CN-Mn-NC-),, as the repeating unit. Circular dichroism (CD) spectra confirm the enantiomeric nature of the optically active complexes. Magnetic studies demonstrate that ferromagnetic interactions are operative in these complexes. The ferromagnetic couplings become weak in the chains with the bending of the Mn-N=C angles.展开更多
基金Supported by the National Natural Science Foundation of China(No.41604018)Research Project of the Production and Research Institute of Jiangsu Province(No.2015002-04)
文摘In order to investigate the feasibility of BDS/GPS in the deformation monitoring of long-span bridges,analysis and research on aspects like number of visible satellites,PDOP value and monitoring precision are carried out. To analyze daily deformation characteristics of steel box girder bridge,observation data for 48 consecutive hours is computed by self-programmed software. Experiment results show that the monitoring-points on the bridge demonstrate obvious periodicity and recoverability in vertical and horizontal directions,meanwhile,changes in the elevation direction are relatively stable. The deformation-monitoring results of BDS/GPS combination system and GPS single system show good consistency. However,in a complex environment of the bridge,especially under the condition that satellite signals are severely affected,the advantages of BDS/GPS combination over GPS single system are more obvious.
基金financially supported by the Major State Basic Research Development Program (2011CB808704)the National Natural Science Foundation of China (91022031)
文摘Two couples of enantiomerically pure chiral cyano-bridged heterobimetallic one-dimensional (1D) chain complexes: [Mn((R,R)-Salphen)Fe(Tp)(CN)3],, (1) and [Mn((S,S)-Salphen)Te(Tp)(CN)3]n (2) (Salphen = N,N'-l,2-diphenylethylenebis (salicylideneiminato) dianion, Tp = tris(pyrazolyl) hydroborate), [Mn((R,R)-Salphen)Fe(Tp*)(CN)3·2H2O],, (3) and [Mn((S,S)-Salphen)Fe(Tp*)(CN)3.2H20],, (4) (Tp* = hydridotris (3,5-dimethylpyrazol-l-yl) borate), have been successfully synthesized by the reactions of MnⅢ schiff-base complexes with the tricyanometalate building block, [(Lxp)Fe(CN)3]- (Lyp = Tp or Tp*). All complexes are made up of neutral cyano-bridged zigzag double chains with (-Fe-CN-Mn-NC-),, as the repeating unit. Circular dichroism (CD) spectra confirm the enantiomeric nature of the optically active complexes. Magnetic studies demonstrate that ferromagnetic interactions are operative in these complexes. The ferromagnetic couplings become weak in the chains with the bending of the Mn-N=C angles.
