A novel coordination polymer of [Ca(2-OPA)2(H2O)2]n (2-OPA-=2-oxo-1(4H)-pyridineacetate anion) was synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. The title complex cr...A novel coordination polymer of [Ca(2-OPA)2(H2O)2]n (2-OPA-=2-oxo-1(4H)-pyridineacetate anion) was synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. The title complex crystallizes in orthorhombic with space group Pna21, a=0.799 96(16) nm, b=0.823 77(16) nm, c=2.415 3(5) nm, V=1.591 6(6) nm3, Z=4, R=0.030 3, wR=0.070 0. The Ca atom is eight-coordinated by six O atoms of four 2-OPA- ligands and two water molecules, and displays a dodecahedron coordination geometry. Each 2-OPA- ligand bridges two adjacent Ca atoms, forming a infinite chain along the a direction. The Ca...Ca distance is 0.4102 2(8)nm. A two-dimensional supramolecular framework is further constructed by the hydrogen bonds and the weak π-π interactions. The results of TG analysis show the chain structure of the title complex was stable under 297.5 ℃. CCDC: 251669.展开更多
为解决PK I信任体系互联互通问题,在对比分析现有PK I常用5种信任模型优缺点的基础上,借鉴已有信任模型,特别是桥CA模型的优点,提出了一个新的模型——多级桥CA信任(m u ltileve l bridge certificate au thority,M BCA)模型.阐述了多级...为解决PK I信任体系互联互通问题,在对比分析现有PK I常用5种信任模型优缺点的基础上,借鉴已有信任模型,特别是桥CA模型的优点,提出了一个新的模型——多级桥CA信任(m u ltileve l bridge certificate au thority,M BCA)模型.阐述了多级桥CA信任模型的基本原理及其构建方法,给出了其总体架构;在总体框架下,对其原型系统中LDAP服务器进行了设计;并结合具体项目对方案的可行性进行了实验验证和分析.实验证明了该模型的可行性,有望对我国PK I建设工程有所帮助.展开更多
Smart parks serve as integral components of smart cities,where they play a pivotal role in the process of urban modernization.The demand for cross-domain cooperation among smart devices from various parks has witnesse...Smart parks serve as integral components of smart cities,where they play a pivotal role in the process of urban modernization.The demand for cross-domain cooperation among smart devices from various parks has witnessed a significant increase.To ensure secure communication,device identities must undergo authentication.The existing cross-domain authentication schemes face issues such as complex authentication paths and high certificate management costs for devices,making it impractical for resource-constrained devices.This paper proposes a blockchain-based lightweight and efficient cross-domain authentication protocol for smart parks,which simplifies the authentication interaction and requires every device to maintain only one certificate.To enhance cross-domain cooperation flexibility,a comprehensive certificate revocation mechanism is presented,significantly reducing certificate management costs while ensuring efficient and secure identity authentication.When a park needs to revoke access permissions of several cooperative partners,the revocation of numerous cross-domain certificates can be accomplished with a single blockchain write operation.The security analysis and experimental results demonstrate the security and effectiveness of our scheme.展开更多
文摘A novel coordination polymer of [Ca(2-OPA)2(H2O)2]n (2-OPA-=2-oxo-1(4H)-pyridineacetate anion) was synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. The title complex crystallizes in orthorhombic with space group Pna21, a=0.799 96(16) nm, b=0.823 77(16) nm, c=2.415 3(5) nm, V=1.591 6(6) nm3, Z=4, R=0.030 3, wR=0.070 0. The Ca atom is eight-coordinated by six O atoms of four 2-OPA- ligands and two water molecules, and displays a dodecahedron coordination geometry. Each 2-OPA- ligand bridges two adjacent Ca atoms, forming a infinite chain along the a direction. The Ca...Ca distance is 0.4102 2(8)nm. A two-dimensional supramolecular framework is further constructed by the hydrogen bonds and the weak π-π interactions. The results of TG analysis show the chain structure of the title complex was stable under 297.5 ℃. CCDC: 251669.
文摘为解决PK I信任体系互联互通问题,在对比分析现有PK I常用5种信任模型优缺点的基础上,借鉴已有信任模型,特别是桥CA模型的优点,提出了一个新的模型——多级桥CA信任(m u ltileve l bridge certificate au thority,M BCA)模型.阐述了多级桥CA信任模型的基本原理及其构建方法,给出了其总体架构;在总体框架下,对其原型系统中LDAP服务器进行了设计;并结合具体项目对方案的可行性进行了实验验证和分析.实验证明了该模型的可行性,有望对我国PK I建设工程有所帮助.
基金supported in part by the National Natural Science Foundation Project of China under Grant No.62062009the Guangxi Innovation-Driven Development Project under Grant Nos.AA17204058-17 and AA18118047-7.
文摘Smart parks serve as integral components of smart cities,where they play a pivotal role in the process of urban modernization.The demand for cross-domain cooperation among smart devices from various parks has witnessed a significant increase.To ensure secure communication,device identities must undergo authentication.The existing cross-domain authentication schemes face issues such as complex authentication paths and high certificate management costs for devices,making it impractical for resource-constrained devices.This paper proposes a blockchain-based lightweight and efficient cross-domain authentication protocol for smart parks,which simplifies the authentication interaction and requires every device to maintain only one certificate.To enhance cross-domain cooperation flexibility,a comprehensive certificate revocation mechanism is presented,significantly reducing certificate management costs while ensuring efficient and secure identity authentication.When a park needs to revoke access permissions of several cooperative partners,the revocation of numerous cross-domain certificates can be accomplished with a single blockchain write operation.The security analysis and experimental results demonstrate the security and effectiveness of our scheme.
