ZnS Quasi nanorods were successfully synthesized with artificial active membrane of celloidin as template by the cooperating effect of artificial active membrane and ethylenediamine. The results indicated that ZnS qua...ZnS Quasi nanorods were successfully synthesized with artificial active membrane of celloidin as template by the cooperating effect of artificial active membrane and ethylenediamine. The results indicated that ZnS quasi nanorods, which had a hexangular wurtzite structure, could be formed at room temperature with 0.1mol· L- 1 ZnSO4 which added suitable template reagent ethylenediamine and 0.1mol· L- 1 Na2S as reactants. The particles’ diameter was from 200nm to 500nm, and the average length was about 12μ m. The photics property study showed that the product reserved the properties of IR permeation and fluorescent luminescence in bulk materials, and the UV Vis spectrum showed that the furthest absorption peak was at 308nm having 42nm’s blue shift comparing to ZnS bulk material, which indicated that the particles had obvious quantum size effect.展开更多
文摘ZnS Quasi nanorods were successfully synthesized with artificial active membrane of celloidin as template by the cooperating effect of artificial active membrane and ethylenediamine. The results indicated that ZnS quasi nanorods, which had a hexangular wurtzite structure, could be formed at room temperature with 0.1mol· L- 1 ZnSO4 which added suitable template reagent ethylenediamine and 0.1mol· L- 1 Na2S as reactants. The particles’ diameter was from 200nm to 500nm, and the average length was about 12μ m. The photics property study showed that the product reserved the properties of IR permeation and fluorescent luminescence in bulk materials, and the UV Vis spectrum showed that the furthest absorption peak was at 308nm having 42nm’s blue shift comparing to ZnS bulk material, which indicated that the particles had obvious quantum size effect.
