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GC-MS法测定植物性样品中二硫代氨基甲酸酯类农药残留 被引量:3
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作者 高慧 汪洋 邢燕 《食品安全导刊》 2020年第12期124-124,共1页
建立测定植物性样品中二硫代氨基甲酸酯类农药残留的气相色谱-质谱联用仪法(GC-MS)。取匀浆的植物性样品,加入氯化亚锡-盐酸溶液,密闭水浴反应后,用正己烷萃取,GC-MS分析测定。并测定标准系列溶液,绘制标准曲线,其相关系数均大于0.999... 建立测定植物性样品中二硫代氨基甲酸酯类农药残留的气相色谱-质谱联用仪法(GC-MS)。取匀浆的植物性样品,加入氯化亚锡-盐酸溶液,密闭水浴反应后,用正己烷萃取,GC-MS分析测定。并测定标准系列溶液,绘制标准曲线,其相关系数均大于0.999。检出限为0.003μg/g,定量限为0.01μg/g。平均回收率在95.9%~99.8%,相对标准偏差为1.12%~5.12%。该方法适用于植物性样品中二硫代氨基甲酸酯类农药残留的测定。 展开更多
关键词 植物性样品 二硫代氨基甲酸酯类 GC-MS
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微波增压溶样-石墨炉原子吸收光谱法同时测定植物性样品中微量铅镉 被引量:22
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作者 张蕴光 于水军 《理化检验(化学分册)》 CAS CSCD 北大核心 2003年第4期226-228,共3页
使用微波增压溶样法 ,将样品用HNO3 HClO4 溶解后 ,用石墨炉原子吸收光谱法同时测定植物性样品中铅和镉。以磷酸二氢铵 硝酸镁作为基体改进剂 ,可使灰化温度大大提高 ,克服了基体的干扰。铅和镉的回收率分别为 95 .3% 10 4 .8%和 96 .2... 使用微波增压溶样法 ,将样品用HNO3 HClO4 溶解后 ,用石墨炉原子吸收光谱法同时测定植物性样品中铅和镉。以磷酸二氢铵 硝酸镁作为基体改进剂 ,可使灰化温度大大提高 ,克服了基体的干扰。铅和镉的回收率分别为 95 .3% 10 4 .8%和 96 .2 % 10 5 .5 % ,RSD分别为 4 .8% 7.2 %和 4 .3% 7.6 %。 展开更多
关键词 微波增压溶样 石墨炉原子吸收光谱法 同时测定 植物性样品 微量分析
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ICP—MS法测定植物性样品中痕量稀土元素含量的研究 被引量:4
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作者 孙玉岭 田阳 +1 位作者 卫锋 蒋晓光 《检验检疫科学》 2001年第2期10-11,5,共3页
关键词 ICP-MS法 植物性样品 稀土元素 含量测定 食品卫生
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气相色谱质谱联用仪法同时测定植物性样品中多组分农药残留 被引量:2
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作者 姚铭栋 《海峡预防医学杂志》 CAS 2020年第2期40-42,共3页
目的建立植物性样品中多组分农药残留的气相色谱质谱联用仪(GC-MS/MS)测定方法。方法样品用乙腈超声提取,Carb/NH2柱净化,外标法测定多组分农药残留含量。结果 17种农药残留32 min内分离流出,在0.05~5.0μg/mL浓度范围内线性良好,相关系... 目的建立植物性样品中多组分农药残留的气相色谱质谱联用仪(GC-MS/MS)测定方法。方法样品用乙腈超声提取,Carb/NH2柱净化,外标法测定多组分农药残留含量。结果 17种农药残留32 min内分离流出,在0.05~5.0μg/mL浓度范围内线性良好,相关系数r≥0.9980;方法检出限为1.0×10^-6~5.0×10^-3 mg/kg;在0.01~0.10 mg/kg添加水平下,此法的回收率为71.2%~116.1%,相对标准偏差(RSD)为2.1%~15.0%。用该法测定样品20份,毒死蜱和氯氟氰菊酯各检出1份。其他项目均未检出。结论气相色谱质谱联用仪(GC-MS/MS)法简便、快速、准确,适合植物性样品中多组分农药残留的测定,基本满足日常监测工作需要。 展开更多
关键词 农药残留 多组分农药 食品安全 气相色谱质谱联用仪 固相萃取 植物性样品
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氢化物发生-原子荧光法测定植物样品中的硒含量 被引量:1
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作者 李鸿 秦玉燕 +2 位作者 罗清 梁冬丽 谭秦亮 《农业研究与应用》 2018年第6期28-31,共4页
建立了氢化物发生-原子荧光法测定植物性样品中微量硒含量的方法。样品经微波消解完全后,先赶酸至1 mL,再用HCl在100℃还原10 min,然后以10 g/L的硼氢化钾(KBH4)为还原剂,5%HCl为载流,采用氢化物发生-原子荧光光谱仪进行测定。方法检测... 建立了氢化物发生-原子荧光法测定植物性样品中微量硒含量的方法。样品经微波消解完全后,先赶酸至1 mL,再用HCl在100℃还原10 min,然后以10 g/L的硼氢化钾(KBH4)为还原剂,5%HCl为载流,采用氢化物发生-原子荧光光谱仪进行测定。方法检测限为0.023μg/L,加标回收率为87.5%~105.0%,RSD小于1.0%,且标准物质测定结果均在推荐值范围内。该方法灵敏度和准确度高、稳定性好,适用于大量植物性样品中微量硒元素的测定。 展开更多
关键词 氢化物发生-原子荧光法 植物性样品
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Agro-biodiversity and Traditional Knowledge on Tunisian Coastal Oases 被引量:1
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作者 M.B. Salah 《Journal of Environmental Science and Engineering》 2011年第3期303-308,共6页
The Tunisian coastal oases constitute a model of very rich plant biodiversity, organized in different floors of cultivation. The date palm is the highest, the second is the diversified fruit trees and the smallest is ... The Tunisian coastal oases constitute a model of very rich plant biodiversity, organized in different floors of cultivation. The date palm is the highest, the second is the diversified fruit trees and the smallest is composed by various other productions. The present paper is the results of a RAA diagnosis and bibliographic analysis of nearly thirty years of work on oases. The aim of this study is to focus on the plant diversity and the traditions in using different products. The survey revealed the existence of nearly 45 local date palm varieties, about 26 fruit trees, 65 vegetables and divers other species. It also raises nearly 30 uses of dates and date palm by-products. This survey shows also that oases inhabitants keep in possessing, for a long time, a knowledge to make ingenious concerning use and conservation of the products and by products of the date palm. This survey has all as much demonstrated the risks from weakening this balance which has long been maintained. Some recommendations to maintain and conserve this system are also presented in this paper. 展开更多
关键词 Agro biodiversity oases traditional knowledge Tunisia conservation.
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Some Thoughts on Science-based Botanical Garden Establishment
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作者 Lou Zhiping Miao Haixia +1 位作者 Chen Jin Su Ronghui 《Bulletin of the Chinese Academy of Sciences》 2010年第4期235-239,共5页
Through analysis of the historical and present development of botanical gardens, both domestic and international, with particular focus on botanical garden practices within the Chinese Academy of Sciences (CAS), the a... Through analysis of the historical and present development of botanical gardens, both domestic and international, with particular focus on botanical garden practices within the Chinese Academy of Sciences (CAS), the authors propose that science-based botanical gardens (which differ from common public gardens), should be founded on plant diversity inventory and ex-situ conservation of wild plant species. Efforts should be directed to rarer species from biodiversity-rich areas and biodiversity hotspots, utilizing cutting-edge technologies to effectively preserve germplasm in living collections. Science-based botanical garden management should be directed by sound scientific evaluation of plant resources and guaranteed by innovative operational mechanisms. Science-based botanical gardens should also emphasize the establishment of identifiable and specialized living collections, research platforms and recruitment of qualified experts. In addition to curating living specimens, science-based botanical gardens should pursue research and development of new plant varieties or patents based on their plant collections, thus providing continual support to bio-industry. 展开更多
关键词 science-based botanical gardens ex situ conservation scientific evaluation sustainable utilization BIO-INDUSTRY
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Characterization and Drying of Green Mint
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作者 Belgacem Chandoul Bechir Dbira Ahmed Bellagi 《Journal of Chemistry and Chemical Engineering》 2014年第10期955-959,共5页
Mint is a medicinal and aromatic plant. It is very important for the pharmacopoeia, perfumes, confectionery and liquor industry. Some green mint leaves without rods are used as samples. Physical and mechanical propert... Mint is a medicinal and aromatic plant. It is very important for the pharmacopoeia, perfumes, confectionery and liquor industry. Some green mint leaves without rods are used as samples. Physical and mechanical properties of the sample such as the desorption isotherms, the density and volumetric withdrawal are determined. The kinetics of drying, where it follows the changes of the water content of the sample as a function of the drying time for the three temperatures 30, 40 and 50℃, is also presented and discussed. 展开更多
关键词 MINT ISOTHERM DESORPTION SHRINKAGE KINETICS drying.
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Soil microbial properties under different vegetation types on Mountain Han 被引量:11
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作者 WANG Miao QU LaiYe +1 位作者 MA KeMing YUAN Xiu 《Science China(Life Sciences)》 SCIE CAS 2013年第6期561-570,共10页
This study investigated the influence of broadleaf and conifer vegetation on soil microbial communities in a distinct vertical distribution belt in Northeast China.Soil samples were taken at 0-5,5-10 and 10-20 cm dept... This study investigated the influence of broadleaf and conifer vegetation on soil microbial communities in a distinct vertical distribution belt in Northeast China.Soil samples were taken at 0-5,5-10 and 10-20 cm depths from four vegetation types at different altitudes,which were characterized by poplar(Populus davidiana)(1250-1300 m),poplar(P.davidiana) mixed with birch(Betula platyphylla)(1370-1550 m),birch(B.platyphylla)(1550-1720 m),and larch(Larix principis-rupprechtii)(1840-1890 m).Microbial biomass and community structure were determined using the fumigation-extraction method and phospholipid fatty acid(PLFA) analysis,and soil fungal community level physiological profiles(CLPP) were characterized using Biolog FF Microplates.It was found that soil properties,especially soil organic carbon and water content,contributed significantly to the variations in soil microbes.With increasing soil depth,the soil microbial biomass,fungal biomass,and fungal catabolic ability diminished;however,the ratio of fungi to bacteria increased.The fungal ratio was higher under larch forests compared to that under poplar,birch,and their mixed forests,although the soil microbial biomass was lower.The direct contribution of vegetation types to the soil microbial community variation was 12%.If the indirect contribution through soil organic carbon was included,variations in the vegetation type had substantial influences on soil microbial composition and diversity. 展开更多
关键词 vegetation types soil organic carbon soil microbial composition fungal catabolic diversity
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Comparison of pretreatment,preservation and determination methods for foliar pH of plant samples
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作者 Sining Liu Jiashu Chen Wenxuan Han 《Journal of Plant Ecology》 SCIE CSCD 2022年第4期673-682,共10页
To compare current methods of pretreatment/determination for plant foliar pH,we proposed a method for longperiod sample preservation with little interference with the stability of foliar pH.Four hundred leaf samples f... To compare current methods of pretreatment/determination for plant foliar pH,we proposed a method for longperiod sample preservation with little interference with the stability of foliar pH.Four hundred leaf samples from 20 species were collected and four methods of pH determination were used:refrigerated(stored at 4°C for 4 days),frozen(stored at−16°C for 4 days),oven-dried and fresh green-leaf pH(control).To explore the effects of different leaf:water mixing ratio on the pH determination results,we measured oven-dried green-leaf pH by leaf:water volume ratio of 1:8 and mass ratio of 1:10,and measured frozen senesced-leaf pH by mass ratio of 1:10 and 1:15.The standard major axis regression was used to analyze the relationship and the conversion equation between the measured pH with different methods.Foliar pH of refrigerated and frozen green leaves did not signifcantly differ from that of fresh green-leaf,but drying always overrated fresh green-leaf pH.During the feld sampling,cryopreservation with a portable refrigerator was an advisable choice to get a precise pH.For long-duration feld sampling,freezing was the optimal choice,and refrigeration is the best choice for the shorttime preservation.The different leaf:water mixing ratio signifcantly infuenced the measured foliar pH.High dilution reduced the proton concentration and increased the measured pH.Our fndings provide the conversion relationships between the existing pretreatment and measurement methods,and establish a connection among pH determined by different methods.Our study can facilitate foliar pH measurement,thus contributing to understanding of this interesting plant functional trait. 展开更多
关键词 green/senesced leaf leaf pH plant functional traits sample preservation specifcation/standard/protocol leaf water ratio transformation/conversion equation
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