Al/α-PbO2/β-PbO2 composite electrodes doped with rare earth oxide （CeO2） were prepared by anodic oxidation method investigate the influence of nano-CeO2 dopants on the properties of Al/α-PbO2/β-PbO2-CeO2 electro...Al/α-PbO2/β-PbO2 composite electrodes doped with rare earth oxide （CeO2） were prepared by anodic oxidation method investigate the influence of nano-CeO2 dopants on the properties of Al/α-PbO2/β-PbO2-CeO2 electrodes and the impact of α-PbO2 as the intermediate layer. The results show that using α-PbO2 as the intermediate layer will benefit the crystallization of β-PbO2 and β-PbO2 is more suitable as the surface layer than α-PbO2. CeO2 dopants change the crystallite size and crystal structure, enhance the catalytic activity, and even change the deposition mechanism of PbO2. The doping of CeO2 in the PbO2 electrodes can enhance the electro-catalytic activity, which is helpful for oxygen evolution, and therefore reduce the cell voltage.展开更多
A systematic laboratory study was conducted on current efficiency and corrosion obtained in cryolite-alumina melts with SnO2-Sb203-CuO ceramic inert anodes. The current efficiency （CE） was determined by measuring th...A systematic laboratory study was conducted on current efficiency and corrosion obtained in cryolite-alumina melts with SnO2-Sb203-CuO ceramic inert anodes. The current efficiency （CE） was determined by measuring the total amount of oxygen evolved at the anode and was found to be ~ 95%. The influence of operating parameters （inter-elec- trode distance, temperature and current density） was evaluated. The quantitative interdependencies as well as the ranges of CE optima[ values were established （2-3 cm, 940-960 ℃ and 0.7-0.8 A.cm 2）. The corrosion process of these anodes was evaluated by the mass loss method. The evaluation also took care of the corrosion data, as the prob- lem of the anode corrosion appeared to be the main obstacle for the use of those anodes in the commercial cells.Low-ering of the ACD up to 2 cm did not aggravate anode corrosion.展开更多
We demonstrate a novel SOI-based photonic crystal（PC） double-heterostructure slot waveguide microcavity constructed by cascading three PC slot waveguides with different slot widths,and simulate the luminescence enha...We demonstrate a novel SOI-based photonic crystal（PC） double-heterostructure slot waveguide microcavity constructed by cascading three PC slot waveguides with different slot widths,and simulate the luminescence enhancement of sol-gel Er-doped SiO2 filled in the microcavity by finite-difference time-domain（FDTD） method.The calculated results indicate that a unique sharp resonant peak dominates in the spectrum at the expected telecommunication wavelength of 1.5509 mm,with very high normalized peak intensity of ~108.The electromagnetic field of the resonant mode exhibits the strongest in the microcavity,and decays rapidly to zero along both sides,which means that the resonant mode field is well confined in the microcavity.The simulation results fully verify the enhancement of luminescence by PC double-heterostructure slot waveguide microcavity theoretically,which is a promising way to realize the high-efficiency luminescence of Si-based materials.展开更多
基金Project(50964008)supported by the National Natural Science Foundation of ChinaProject(2010287)supported by Analysis and Testing Foundation of Kunming University of Science and Technology,China
文摘Al/α-PbO2/β-PbO2 composite electrodes doped with rare earth oxide （CeO2） were prepared by anodic oxidation method investigate the influence of nano-CeO2 dopants on the properties of Al/α-PbO2/β-PbO2-CeO2 electrodes and the impact of α-PbO2 as the intermediate layer. The results show that using α-PbO2 as the intermediate layer will benefit the crystallization of β-PbO2 and β-PbO2 is more suitable as the surface layer than α-PbO2. CeO2 dopants change the crystallite size and crystal structure, enhance the catalytic activity, and even change the deposition mechanism of PbO2. The doping of CeO2 in the PbO2 electrodes can enhance the electro-catalytic activity, which is helpful for oxygen evolution, and therefore reduce the cell voltage.
文摘A systematic laboratory study was conducted on current efficiency and corrosion obtained in cryolite-alumina melts with SnO2-Sb203-CuO ceramic inert anodes. The current efficiency （CE） was determined by measuring the total amount of oxygen evolved at the anode and was found to be ~ 95%. The influence of operating parameters （inter-elec- trode distance, temperature and current density） was evaluated. The quantitative interdependencies as well as the ranges of CE optima[ values were established （2-3 cm, 940-960 ℃ and 0.7-0.8 A.cm 2）. The corrosion process of these anodes was evaluated by the mass loss method. The evaluation also took care of the corrosion data, as the prob- lem of the anode corrosion appeared to be the main obstacle for the use of those anodes in the commercial cells.Low-ering of the ACD up to 2 cm did not aggravate anode corrosion.
基金supported by the National Key Basic Research Special Fund of China (No.2007CB613404)the National High Technology,Research and Development Program of China (No.2011AA010303)the National Natural Science Foundation of China (Nos.61090390,60837001,60977045,60877014 and 60776057)
文摘We demonstrate a novel SOI-based photonic crystal（PC） double-heterostructure slot waveguide microcavity constructed by cascading three PC slot waveguides with different slot widths,and simulate the luminescence enhancement of sol-gel Er-doped SiO2 filled in the microcavity by finite-difference time-domain（FDTD） method.The calculated results indicate that a unique sharp resonant peak dominates in the spectrum at the expected telecommunication wavelength of 1.5509 mm,with very high normalized peak intensity of ~108.The electromagnetic field of the resonant mode exhibits the strongest in the microcavity,and decays rapidly to zero along both sides,which means that the resonant mode field is well confined in the microcavity.The simulation results fully verify the enhancement of luminescence by PC double-heterostructure slot waveguide microcavity theoretically,which is a promising way to realize the high-efficiency luminescence of Si-based materials.
