The kinetic model of vacuum gas oil （VGO） hydrocracking based on discrete lumped approach was investigated, and some improvement was put forward at the same time in this article. A parallel reaction scheme to descri...The kinetic model of vacuum gas oil （VGO） hydrocracking based on discrete lumped approach was investigated, and some improvement was put forward at the same time in this article. A parallel reaction scheme to describe the conver- sion of VGO into products （gases, gasoline, and diesel） proposed by Orochko was used. The different experimental data were analyzed statistically and then the product distribution and kinetic parameters were simulated by available data. Fur- thermore, the kinetic parameters were correlated based on the feed property, reaction temperature, and catalyst activity. An optimization code in Matlab 2011b was written to fine-me these parameters. The model had a favorable ability to predict the product distribution and there was a good agreement between the model predictions and experiment data. Hence, the ki- netic parameters indeed had something to do with feed properties, reaction temperature and catalyst activity.展开更多
Through analyzing experimental data of gas explosions in excavation roadwaysand the forecast models of the literature, Found that there is no direct proportional linearcorrelation between overpressure and the square r...Through analyzing experimental data of gas explosions in excavation roadwaysand the forecast models of the literature, Found that there is no direct proportional linearcorrelation between overpressure and the square root of the accumulated volume of gas,the square root of the propagation distance multiplicative inverse.Also, attenuation speedof the forecast model calculation is faster than that of experimental data.Based on theoriginal forecast models and experimental data, deduced the relation of factors by introducinga correlation coefficient with concrete volume and distance, which had been verifiedby the roadway experiment data.The results show that it is closer to the roadway experimentaldata and the overpressure amount increases first then decreases with thepropagation distance.展开更多
基金the fund of"National‘Twelfth Five-Year’Plan for Science&Technology Support"(No.2012BAE05B04)"Research on Hydrocracking Catalysts Grading Technology"undertaken by Fushun Research Institute of Petroleum and Petrochemicals(FRIPP)supported by SINOPEC(No.101102)
文摘The kinetic model of vacuum gas oil （VGO） hydrocracking based on discrete lumped approach was investigated, and some improvement was put forward at the same time in this article. A parallel reaction scheme to describe the conver- sion of VGO into products （gases, gasoline, and diesel） proposed by Orochko was used. The different experimental data were analyzed statistically and then the product distribution and kinetic parameters were simulated by available data. Fur- thermore, the kinetic parameters were correlated based on the feed property, reaction temperature, and catalyst activity. An optimization code in Matlab 2011b was written to fine-me these parameters. The model had a favorable ability to predict the product distribution and there was a good agreement between the model predictions and experiment data. Hence, the ki- netic parameters indeed had something to do with feed properties, reaction temperature and catalyst activity.
基金Supported by the National Natural Science Foundation of China(50874005)Anhui Province College Young Teachers Scientific Research"Allotment Planning"Key Project(2009SQRZ067)
文摘Through analyzing experimental data of gas explosions in excavation roadwaysand the forecast models of the literature, Found that there is no direct proportional linearcorrelation between overpressure and the square root of the accumulated volume of gas,the square root of the propagation distance multiplicative inverse.Also, attenuation speedof the forecast model calculation is faster than that of experimental data.Based on theoriginal forecast models and experimental data, deduced the relation of factors by introducinga correlation coefficient with concrete volume and distance, which had been verifiedby the roadway experiment data.The results show that it is closer to the roadway experimentaldata and the overpressure amount increases first then decreases with thepropagation distance.
