100%green carbon foam from the fibrous fruits of Platanus Orientalis-L(Plane)along with the tar oil as binder has been prepared using a powder molding technique.The objective was to develop a porous monolithic carbon ...100%green carbon foam from the fibrous fruits of Platanus Orientalis-L(Plane)along with the tar oil as binder has been prepared using a powder molding technique.The objective was to develop a porous monolithic carbon from biomaterials with a considerable strength necessary for various physical,thermal and electromagnetic shielding applications.Fast carbonization was carried out at1000°C under the cover of Plane tree pyrolyzed seeds without using any external protective gas.For comparative analysis,some samples were mixed with5%(mass fraction)iron chloride during the molding process.Iron chloride being a graphitization catalyst and activating agent helped in increasing the specific surface area from88to294m2/g with a25%decrease in flexural strength.Thermal stability was improved due to the incorporation of more graphitic phases in the sample resulting in a little higher thermal conductivity from0.22to0.67W/(m·K).The catalytic carbon foam exhibited shielding effectiveness of more than20dB over the X-band frequency.Absorption was dominant with only8.26%?10.33%reflectance,indicating an absorption dominant shielding mechanism.The new material is quite suitable for high temperature thermal insulation being lightweight,highly porous with interconnected porous morphology most of which is preserved from the original biomaterial.展开更多
Materials with the same elastic modulus E and representative stress and strain （σr,εr） present similar indentation-loading curves, whatever the value of strain hardening exponent n. Based on this definition, a goo...Materials with the same elastic modulus E and representative stress and strain （σr,εr） present similar indentation-loading curves, whatever the value of strain hardening exponent n. Based on this definition, a good approach was proposed to extract the plastic properties or constitutive equations of metals from nanoindentation test combining finite element simulation. Firstly, without consideration of strain hardening, the representative stress was determined by varying assumed representative stress over a wide range until a good agreement was reached between the computed and experimental loading curves. Similarly, the corresponding representative strain was determined with different hypothetical values of strain hardening exponent in the range of 0-0.6. Through modulating assumed strain hardening exponent values to make the computed unloading curve coincide with that of the experiment, the real strain hardening exponent was acquired. Once the strain hardening exponent was determined, the initial yield stress ay of metals could be obtained by the power law constitution. The validity of the proposed methodology was verified by three real metals： AISI 304 steel, Fe andA1 alloy.展开更多
基金Project(CX201627) supported by the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University,China
文摘100%green carbon foam from the fibrous fruits of Platanus Orientalis-L(Plane)along with the tar oil as binder has been prepared using a powder molding technique.The objective was to develop a porous monolithic carbon from biomaterials with a considerable strength necessary for various physical,thermal and electromagnetic shielding applications.Fast carbonization was carried out at1000°C under the cover of Plane tree pyrolyzed seeds without using any external protective gas.For comparative analysis,some samples were mixed with5%(mass fraction)iron chloride during the molding process.Iron chloride being a graphitization catalyst and activating agent helped in increasing the specific surface area from88to294m2/g with a25%decrease in flexural strength.Thermal stability was improved due to the incorporation of more graphitic phases in the sample resulting in a little higher thermal conductivity from0.22to0.67W/(m·K).The catalytic carbon foam exhibited shielding effectiveness of more than20dB over the X-band frequency.Absorption was dominant with only8.26%?10.33%reflectance,indicating an absorption dominant shielding mechanism.The new material is quite suitable for high temperature thermal insulation being lightweight,highly porous with interconnected porous morphology most of which is preserved from the original biomaterial.
基金Project （51171125） supported by the National Natural Science Foundation of China Project （20110321051 ） supported by the Science and Technology Key Project of Shanxi Province, China
文摘Materials with the same elastic modulus E and representative stress and strain （σr,εr） present similar indentation-loading curves, whatever the value of strain hardening exponent n. Based on this definition, a good approach was proposed to extract the plastic properties or constitutive equations of metals from nanoindentation test combining finite element simulation. Firstly, without consideration of strain hardening, the representative stress was determined by varying assumed representative stress over a wide range until a good agreement was reached between the computed and experimental loading curves. Similarly, the corresponding representative strain was determined with different hypothetical values of strain hardening exponent in the range of 0-0.6. Through modulating assumed strain hardening exponent values to make the computed unloading curve coincide with that of the experiment, the real strain hardening exponent was acquired. Once the strain hardening exponent was determined, the initial yield stress ay of metals could be obtained by the power law constitution. The validity of the proposed methodology was verified by three real metals： AISI 304 steel, Fe andA1 alloy.
