The geometric structures and vibration frequencies of para-chlorofluorobenzene(p-Cl FPh)in the first excited state of neutral and ground state of cation were investigated by resonanceenhanced multiphoton ionization an...The geometric structures and vibration frequencies of para-chlorofluorobenzene(p-Cl FPh)in the first excited state of neutral and ground state of cation were investigated by resonanceenhanced multiphoton ionization and slow electron velocity-map imaging.The infrared spectrum of S0 state and absorption spectrum for S1←S0 transition in p-Cl FPh were also recorded.Based on the one-color resonant two-photon ionization spectrum and two-color resonant two-photon ionization spectrum,we obtained the adiabatic excited-state energy of p-Cl FPh as 36302±4 cm^-1.In the two-color resonant two-photon ionization slow electron velocity-map imagin spectra,the accurate adiabatic ionization potential of p-Cl FPh was extrapolated as 72937±8 cm^-1 via threshold ionization measurement.In addition,FranckCondon simulation was performed to help us confidently ascertain the main vibrational modes in the S1 and D0 states.Furthermore,the mixing of vibrational modes between S0→S1 and S1→D0 has been analyzed.展开更多
Based on the picture of nonJinear and non-parabolic symmetry response, i.e., Δn2 （I） ≈ ρ（ao ＋ a1x - a2 x^2）, we propose a model for the transversal beam intensity distribution of the nonlocal spatial soliton. ...Based on the picture of nonJinear and non-parabolic symmetry response, i.e., Δn2 （I） ≈ ρ（ao ＋ a1x - a2 x^2）, we propose a model for the transversal beam intensity distribution of the nonlocal spatial soliton. In this model, as a convolution response with non-parabolic symmetry, Δn2 （I）≈ρ（b0＋ b1f - b2 f^2 with b2/b1 〉 0 is assumed. Furthermore, instead of the wave function Ψ, the high-order nonlinear equation for the beam intensity distribution f has been derived and the bell-shaped soliton solution with the envelope form has been obtained. The results demonstrate that, since the existence of the terms of non-parabolic response, the nonlocal spatial soliton has the bistable state solution. If the frequency shift of wave number β satisfies 0 〈 4（β - ρbo/μ） 〈 3η0/8α, the bistable state soliton solution is stable against perturbation. It should be emphasized that the soliton solution arising from a parabolic-symmetry response kernel is trivial. The sufficient condition for the existence of bistable state soliton solution b2/b1〉 0 has been demonstrated.展开更多
Mus cypriaeus is a recently discovered endemic species that evolved about half a million years ago on the Cyprus Is- land in an absence of most mammalian predators and competitors. As on other Mediterranean islands, t...Mus cypriaeus is a recently discovered endemic species that evolved about half a million years ago on the Cyprus Is- land in an absence of most mammalian predators and competitors. As on other Mediterranean islands, the faunal composition was dramatically changed by the invasion of commensal and domestic species following Holocene colonization by humans. We exa- mined the behavioral responses of the Cypriot mouse to the odors of these new competitors （black and Norway rat, house mouse and spiny-mouse） and predator （domestic cat） as well as controls （Herb-field mouse, guinea pig）. We compared them with those of mainland population of house mouse from Syria with different coexistence history. Surprisingly, the Cypriot mouse failed to avoid the odor of its current main competitor, the black rat. Moreover, the response patterns of both the Cypriot and Syrian house mice to the examined odor sources appeared fairly comparable. There was a clear tendency to prefer odors of other murids over unscented sawdust as well as to avoid the odor of a domestic cat. In conclusion, neither the long-term isolation from predators nor the recent strong competition with black rats affected mice eompetitory and antipredatory responses fundamentally [Current Zoology 61 （4）： 781-791, 2015].展开更多
基金the National Natural Science Foundation of China(No.11674003,No.21873003,No.21503003,No.11704004,and No.61475001)Anhui Natural Science Foundation(No.1908085QA17)+1 种基金support from Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fund(the second phase)(No.U1501501)Super Computation Center of Shenzhen。
文摘The geometric structures and vibration frequencies of para-chlorofluorobenzene(p-Cl FPh)in the first excited state of neutral and ground state of cation were investigated by resonanceenhanced multiphoton ionization and slow electron velocity-map imaging.The infrared spectrum of S0 state and absorption spectrum for S1←S0 transition in p-Cl FPh were also recorded.Based on the one-color resonant two-photon ionization spectrum and two-color resonant two-photon ionization spectrum,we obtained the adiabatic excited-state energy of p-Cl FPh as 36302±4 cm^-1.In the two-color resonant two-photon ionization slow electron velocity-map imagin spectra,the accurate adiabatic ionization potential of p-Cl FPh was extrapolated as 72937±8 cm^-1 via threshold ionization measurement.In addition,FranckCondon simulation was performed to help us confidently ascertain the main vibrational modes in the S1 and D0 states.Furthermore,the mixing of vibrational modes between S0→S1 and S1→D0 has been analyzed.
基金The project supported by National Natural Science Foundation of China under Grant No.10574163
文摘Based on the picture of nonJinear and non-parabolic symmetry response, i.e., Δn2 （I） ≈ ρ（ao ＋ a1x - a2 x^2）, we propose a model for the transversal beam intensity distribution of the nonlocal spatial soliton. In this model, as a convolution response with non-parabolic symmetry, Δn2 （I）≈ρ（b0＋ b1f - b2 f^2 with b2/b1 〉 0 is assumed. Furthermore, instead of the wave function Ψ, the high-order nonlinear equation for the beam intensity distribution f has been derived and the bell-shaped soliton solution with the envelope form has been obtained. The results demonstrate that, since the existence of the terms of non-parabolic response, the nonlocal spatial soliton has the bistable state solution. If the frequency shift of wave number β satisfies 0 〈 4（β - ρbo/μ） 〈 3η0/8α, the bistable state soliton solution is stable against perturbation. It should be emphasized that the soliton solution arising from a parabolic-symmetry response kernel is trivial. The sufficient condition for the existence of bistable state soliton solution b2/b1〉 0 has been demonstrated.
文摘Mus cypriaeus is a recently discovered endemic species that evolved about half a million years ago on the Cyprus Is- land in an absence of most mammalian predators and competitors. As on other Mediterranean islands, the faunal composition was dramatically changed by the invasion of commensal and domestic species following Holocene colonization by humans. We exa- mined the behavioral responses of the Cypriot mouse to the odors of these new competitors （black and Norway rat, house mouse and spiny-mouse） and predator （domestic cat） as well as controls （Herb-field mouse, guinea pig）. We compared them with those of mainland population of house mouse from Syria with different coexistence history. Surprisingly, the Cypriot mouse failed to avoid the odor of its current main competitor, the black rat. Moreover, the response patterns of both the Cypriot and Syrian house mice to the examined odor sources appeared fairly comparable. There was a clear tendency to prefer odors of other murids over unscented sawdust as well as to avoid the odor of a domestic cat. In conclusion, neither the long-term isolation from predators nor the recent strong competition with black rats affected mice eompetitory and antipredatory responses fundamentally [Current Zoology 61 （4）： 781-791, 2015].
