The corrosion and leaching behaviors of Sn-0.75Cu solders and joints in NaCl-Na2SO4 and NaCl-Na2SO4-Na2CO3 simulated soil solutions were investigated compared with those in NaCl solution, aiming to assess the potentia...The corrosion and leaching behaviors of Sn-0.75Cu solders and joints in NaCl-Na2SO4 and NaCl-Na2SO4-Na2CO3 simulated soil solutions were investigated compared with those in NaCl solution, aiming to assess the potential risk from the electronic-waste disposed in soil. The leaching kinetics of Sn reveals that the leaching amount of Sn increases with increasing the time. The amount of Sn leached from the joint is the largest in NaCl solution.SO4^2- and CO3^2- inhibit the leaching of Sn from the joints, but accelerate that from the solders. Meanwhile, the corrosion layer of the joint in NaCl solution is more porous, and those immersed in NaCl-Na2SO4 and NaCl-Na2SO4-Na2CO3 solutions are compact. The XRD results indicate that the main corrosion products on the solders and joints surfaces are comprised of tin oxide, tin chloride and tin chloride hydroxide. The potentiodynamic polarization measurements for the solders were discussed in the simulated soil solutions.展开更多
To control the multicomponent reactions in extrusion, reactive-mixing flow in a co-rotating twin screw extruder was numerically studied in the present paper. Effects of initial species distribution, rotating speed and...To control the multicomponent reactions in extrusion, reactive-mixing flow in a co-rotating twin screw extruder was numerically studied in the present paper. Effects of initial species distribution, rotating speed and flow rate on a competitive-parallel reaction were investigated and the relationship between mixing and reactions was discussed from the view of chemical reaction engineering. The simulation results show the studied operational parameters, which determine residence time distribution, earliness of mixing and segregation degree of reactive-mixing flows, affect the local species concentration and reaction time and hence have significant influences on the reaction extent. Orthogonal test was adopted to clarify the significance of operational parameters.The analysis shows that initial species distribution and flow rate are the most important factors in the control of reaction extent, and effect of rotating speed is conditional depending on the micro-mixing status of the fluid.展开更多
A laboratory-scale sequencing batch reactor (SBR) is used to treat landfill leachate containing high concentration of ammonium nitrogen with municipal fecal supernatant. The SBR system is operated in the following seq...A laboratory-scale sequencing batch reactor (SBR) is used to treat landfill leachate containing high concentration of ammonium nitrogen with municipal fecal supernatant. The SBR system is operated in the following sequential phases: fill period, anoxic period, aeration period, settling period, decant and idle period. The results indicated that the average removal efficiencies of COD, BOD5, TN, NH 4+-N were 93.76%, 98.28%, 84.74% and 99.21%, respectively. The average sludge removal loading rates of COD, BOD5, TN and NH 4+-N were 0.24 kg/(kg SS?d), 0.08 kg/(kg SS?d), 0.04 kg/(kg SS?d) and 0.036 kg/(kg SS?d), respectively. Highly effective simultaneous nitrification and denitrification was achieved in the SBR system. The ratio of nitrification and denitrification was 99% and 84%, respectively. There was partial NO?2 denitrification in the system.展开更多
With an improved Rayleigh fading model and a zero-mean stochastic sinusoid as the scattering and specular components respectively,a stochastic simulation model is proposed for the generation of Rayleigh and Rician fad...With an improved Rayleigh fading model and a zero-mean stochastic sinusoid as the scattering and specular components respectively,a stochastic simulation model is proposed for the generation of Rayleigh and Rician fading waveforms.Compared with the existing stochastic models,the proposed simulator needs only one trial to obtain the desired statistical properties even if the number of samples is not large enough.Moreover,the proposed simulation model can directly generate multiple uncorrelated waveforms for different fading scenarios,such as single-input single-output frequency selective channels and multiple-input multiple-output channels.The performance evaluation and comparison show that the proposed simulator is efficient and accurate.展开更多
Differential scanning calorimetry (DSC) has been used extensively to study different solid state reactions. The signals measured in DSC are associated with the growth and dissolution of different precipitates during...Differential scanning calorimetry (DSC) has been used extensively to study different solid state reactions. The signals measured in DSC are associated with the growth and dissolution of different precipitates during a specific heat cycle. The time-temperature dependence of heat cycles and the corresponding heat flow evolution measured in the sample by DSC provide valuable experimental information about the phase evolution and the precipitation kinetics in the material. The thermo-kinetic computer simulation was used to predict the DSC signals of samples taken from 6xxx and 2xxx alloys. In the model, the evolution of different metastable and stable phases and the role and influence of excess quenched-in vacancies in the early stage of precipitation were taken into account. Transmission electron microscopy (TEM) and high-resolution TEM were used to verify the existence of precipitates, their size and number density at specific points of the DSC curves.展开更多
The hot compression test of 6063 Al alloy was performed on a Gleeble-1500 thermo-simulation machine, and the forming of 6063 rod cxtrudate in low-temperature high-speed extrusion was simulated with extrusion ratio of ...The hot compression test of 6063 Al alloy was performed on a Gleeble-1500 thermo-simulation machine, and the forming of 6063 rod cxtrudate in low-temperature high-speed extrusion was simulated with extrusion ratio of 25 on the platform of DEFORM 2D successfully. From the compression experimental results, the flow stress model of this Al alloy is obtained which could be the constitutive equation in the simulation of low-temperature high-speed extrusion process. From the numerical simulation results, there is a higher strain concentration at the entrance of the die and the exit temperature reaches up to 522 ℃ in low-temperature high-speed extrusion, which approaches to the quenching temperature of the 6063 Al alloy. The results show that the low-temperature high-speed extrusion method as a promsing one can reduce energy consumption effectively.展开更多
The least squares support vector regression (LS-SVR) is usually used for the modeling of single output system, but it is not well suitable for the actual multi-input-multi-output system. The paper aims at the modeling...The least squares support vector regression (LS-SVR) is usually used for the modeling of single output system, but it is not well suitable for the actual multi-input-multi-output system. The paper aims at the modeling of multi-output systems by LS-SVR. The multi-output LS-SVR is derived in detail. To avoid the inversion of large matrix, the recursive algorithm of the parameters is given, which makes the online algorithm of LS-SVR practical. Since the computing time increases with the number of training samples, the sparseness is studied based on the pro-jection of online LS-SVR. The residual of projection less than a threshold is omitted, so that a lot of samples are kept out of the training set and the sparseness is obtained. The standard LS-SVR, nonsparse online LS-SVR and sparse online LS-SVR with different threshold are used for modeling the isomerization of C8 aromatics. The root-mean-square-error (RMSE), number of support vectors and running time of three algorithms are compared and the result indicates that the performance of sparse online LS-SVR is more favorable.展开更多
In order to analyze the propagation characteristics of shock wave and gas flow induced by outburst intensity, the governing equations of shock wave and gas flow propagation were put forward, and the numerical simulati...In order to analyze the propagation characteristics of shock wave and gas flow induced by outburst intensity, the governing equations of shock wave and gas flow propagation were put forward, and the numerical simulation boundary condition was obtained based on outburst characteristics. The propagation characteristics of shock wave and gas flow were simulated by Fluent software, and the simulation results were verified by experiments. The results show that air shock wave is formed due to air medium compressed by the transient high pressure gas which rapidly expands in the roadway; the shock wave and gas flow with high velocity are formed behind the shock wave front, which significantly decays due to limiting effect of the roadway wall. The attenuation degree is greater in the early stage than that in the late stage, and the velocity of gas convection transport is lower than the speed of the shock wave.The greater the outburst intensity is, the greater the pressure of the shock wave front is, and the higher the speed of the shock wave and gas flow is.展开更多
A mathematical model for enargite bioleaching at 70℃ by Sulfolobus BC in shake-flasks has been constructed. The model included (1) the indirect leaching by Fe^3+ and Fe^3+ regeneration by suspended Sulfolobus, a...A mathematical model for enargite bioleaching at 70℃ by Sulfolobus BC in shake-flasks has been constructed. The model included (1) the indirect leaching by Fe^3+ and Fe^3+ regeneration by suspended Sulfolobus, and (2) the direct leaching by the attached Sulfolobus. The model parameters were optimized using genetic algorithm (GA). Simulations of the ferric leaching, and bioleaching processes were done using this model. The dynamic changes of the concentrations of Cu^2+, As^3+, As^5+, Fe^3+ and/or Fe^2+, as well as ferric-arsenate precipitation were accurately predicted.展开更多
An outburst of coal and gas is a major hazard in underground coal mining. It is generally accepted that an outburst occurs when certain conditions of stress, coal gassiness and physical-mechanical properties of coal a...An outburst of coal and gas is a major hazard in underground coal mining. It is generally accepted that an outburst occurs when certain conditions of stress, coal gassiness and physical-mechanical properties of coal are met. Outbursting is recognized as a two-step process, i.e., initiation and development. In this paper, we present a fully-coupled solid and fluid code to model the entire process of an outburst. The deformation, failure and fracture of solid (coal) are modeled with the discrete element method, and the flow of fluid (gas and water) such as free flow and Darcy flow are modeled with the lattice Boltzmann method. These two methods are coupled in a two-way process, i.e., the solid part provides a moving boundary condition and transfers momentum to the fluid, while the fluid exerts a dragging force upon the solid. Gas desorption from coal occurs at the solid-fluid boundary, and gas diffusion is implemented in the solid code where particles are assumed to be porous. A simple 2D example to simulate the process of an outburst with the model is also presented in this paper to demonstrate the capability of the coupled model.展开更多
Acoustic vector sensor consists of pressure and particle velocity sensors,which measure the three-dimensional acoustic particle velocity,as well as the pressure at one location at the same time.By preserving the ampli...Acoustic vector sensor consists of pressure and particle velocity sensors,which measure the three-dimensional acoustic particle velocity,as well as the pressure at one location at the same time.By preserving the amplitude and phase information of the pressure and particle velocity,they possess a number of advantages over traditional scalar sensors.Signal-to-noise ratio (SNR) gain (which is often called array gain) is one of such advantages and is always interested by all of us.But it is not unchangeable if the spatial correlation of the noise field varies.Much more important,it is difficult to be given if the noise becomes complex.In this paper,spatial correlation of the vector field of isotropic volume-noise and surface-generated noise has been introduced briefly.Based on the results,the combined SNR output of a vector linear array is investigated and the maximum gain is given in the specified noise.Computer simulation shows that the output of one array in the same noise is not the same in different gestures.And then we find the best gesture through SNR calculation and obtain the biggest gain,which has important meaning to guide how to deploy an array in practice.We also should use the array with respect to the characteristics of the real ambient noise,especially in anisotropic noise field.展开更多
An auxiliary gas control technology is described that can reduce coal and gas outburst accidents when there is no existing protective coal seam and gas pre-draining is not effective.Numerical simulation methods were u...An auxiliary gas control technology is described that can reduce coal and gas outburst accidents when there is no existing protective coal seam and gas pre-draining is not effective.Numerical simulation methods were used to study the stress distribution ahead of the roadway face for different in situ stresses.The results from the simulation can then provide a new gas control technology.The results show that a high stress concentration,high stresses,and high displacement gradients appear ahead of the roadway face when the maximum in situ stress is aligned perpendicular to the roadway axis.The risk of gas outburst is higher when the stresses decrease rapidly over distance and when the release of more energy occurs immediately after driving the roadway.The gas outburst risk is much smaller when the in situ stress is aligned parallel to the roadway axis.During design of the coal mine most of the coal roadways should be arranged to parallel the maximum in situ stress.This will decrease the outburst risk in general and may be considered a new gas outburst prevention method.展开更多
The paper deals with control of supply in pipe networks based on so-called Dynamic Virtual Distortion Method. Making use of the analytical network model of this installation and using presented below, the so-called Vi...The paper deals with control of supply in pipe networks based on so-called Dynamic Virtual Distortion Method. Making use of the analytical network model of this installation and using presented below, the so-called Virtual Distortion Method (VDM), the control of water supply can be performed. Minimization of supply pressure in inlets to the network, subject to inequality constraints imposed on outlet pressure (in chosen nodes) is discussed. Taking advantage of pre-computed influence vectors, the real-time control strategy can be realised with small computational effort and therefore, can be managed with use of hardware-based controllers. Non-linear constitutive relation (water flow vs. pressure head) has been assumed.展开更多
基金Project(2012FY113000)supported by the National Science and Technology Basic Project of the Ministry of Science and Technology of ChinaProjects(51171037+2 种基金5113401351101024)supported by the National Natural Science Foundation of ChinaProject(14B430009)supported by the Science Research Fund of Education Department of Henan Province,China
文摘The corrosion and leaching behaviors of Sn-0.75Cu solders and joints in NaCl-Na2SO4 and NaCl-Na2SO4-Na2CO3 simulated soil solutions were investigated compared with those in NaCl solution, aiming to assess the potential risk from the electronic-waste disposed in soil. The leaching kinetics of Sn reveals that the leaching amount of Sn increases with increasing the time. The amount of Sn leached from the joint is the largest in NaCl solution.SO4^2- and CO3^2- inhibit the leaching of Sn from the joints, but accelerate that from the solders. Meanwhile, the corrosion layer of the joint in NaCl solution is more porous, and those immersed in NaCl-Na2SO4 and NaCl-Na2SO4-Na2CO3 solutions are compact. The XRD results indicate that the main corrosion products on the solders and joints surfaces are comprised of tin oxide, tin chloride and tin chloride hydroxide. The potentiodynamic polarization measurements for the solders were discussed in the simulated soil solutions.
基金Supported by National Program on Key Basic Research Project(2011CB606100)the National Natural Science Foundation of China(21406059)
文摘To control the multicomponent reactions in extrusion, reactive-mixing flow in a co-rotating twin screw extruder was numerically studied in the present paper. Effects of initial species distribution, rotating speed and flow rate on a competitive-parallel reaction were investigated and the relationship between mixing and reactions was discussed from the view of chemical reaction engineering. The simulation results show the studied operational parameters, which determine residence time distribution, earliness of mixing and segregation degree of reactive-mixing flows, affect the local species concentration and reaction time and hence have significant influences on the reaction extent. Orthogonal test was adopted to clarify the significance of operational parameters.The analysis shows that initial species distribution and flow rate are the most important factors in the control of reaction extent, and effect of rotating speed is conditional depending on the micro-mixing status of the fluid.
基金Project supported by the National Natural Science Foundation of China (No. 20377013), Department of Science and Technology of Guangdong Province (Nos. 020959 and 2002C32108), and the New Century Outstanding Young Teacher Grant of Ministry of China
文摘A laboratory-scale sequencing batch reactor (SBR) is used to treat landfill leachate containing high concentration of ammonium nitrogen with municipal fecal supernatant. The SBR system is operated in the following sequential phases: fill period, anoxic period, aeration period, settling period, decant and idle period. The results indicated that the average removal efficiencies of COD, BOD5, TN, NH 4+-N were 93.76%, 98.28%, 84.74% and 99.21%, respectively. The average sludge removal loading rates of COD, BOD5, TN and NH 4+-N were 0.24 kg/(kg SS?d), 0.08 kg/(kg SS?d), 0.04 kg/(kg SS?d) and 0.036 kg/(kg SS?d), respectively. Highly effective simultaneous nitrification and denitrification was achieved in the SBR system. The ratio of nitrification and denitrification was 99% and 84%, respectively. There was partial NO?2 denitrification in the system.
基金Supported by the Science and Technology Innovation Foundation of Tianjin (No.10FDZDGX00400)
文摘With an improved Rayleigh fading model and a zero-mean stochastic sinusoid as the scattering and specular components respectively,a stochastic simulation model is proposed for the generation of Rayleigh and Rician fading waveforms.Compared with the existing stochastic models,the proposed simulator needs only one trial to obtain the desired statistical properties even if the number of samples is not large enough.Moreover,the proposed simulation model can directly generate multiple uncorrelated waveforms for different fading scenarios,such as single-input single-output frequency selective channels and multiple-input multiple-output channels.The performance evaluation and comparison show that the proposed simulator is efficient and accurate.
基金Financial support by the Austrian Federal Government (in particular from Bundesministerium für Verkehr, Innovation und Technologie and Bundesministerium für Wirtschaft, Familie und Jugend) represented by sterreichische Forschungsfrderungsgesellschaft mbHthe Styrian and the Tyrolean Provincial Government, represented by Steirische Wirtschaftsfrderungsgesellschaft mbH and Standortagentur Tirol, within the framework of the COMET Funding Programme is gratefully acknowledged
文摘Differential scanning calorimetry (DSC) has been used extensively to study different solid state reactions. The signals measured in DSC are associated with the growth and dissolution of different precipitates during a specific heat cycle. The time-temperature dependence of heat cycles and the corresponding heat flow evolution measured in the sample by DSC provide valuable experimental information about the phase evolution and the precipitation kinetics in the material. The thermo-kinetic computer simulation was used to predict the DSC signals of samples taken from 6xxx and 2xxx alloys. In the model, the evolution of different metastable and stable phases and the role and influence of excess quenched-in vacancies in the early stage of precipitation were taken into account. Transmission electron microscopy (TEM) and high-resolution TEM were used to verify the existence of precipitates, their size and number density at specific points of the DSC curves.
基金Project(2008A09030004) supported by the Major Science and Technology Project of Guangdong Province,ChinaProject(30815009) supported by the Foundation of State Key Laboratory of Advanced Design and Manufacture for Vehicle Body
文摘The hot compression test of 6063 Al alloy was performed on a Gleeble-1500 thermo-simulation machine, and the forming of 6063 rod cxtrudate in low-temperature high-speed extrusion was simulated with extrusion ratio of 25 on the platform of DEFORM 2D successfully. From the compression experimental results, the flow stress model of this Al alloy is obtained which could be the constitutive equation in the simulation of low-temperature high-speed extrusion process. From the numerical simulation results, there is a higher strain concentration at the entrance of the die and the exit temperature reaches up to 522 ℃ in low-temperature high-speed extrusion, which approaches to the quenching temperature of the 6063 Al alloy. The results show that the low-temperature high-speed extrusion method as a promsing one can reduce energy consumption effectively.
基金Supported by the National Creative Research Groups Science Foundation of China (60721062)the National Basic Research Program of China (2007CB714000)
文摘The least squares support vector regression (LS-SVR) is usually used for the modeling of single output system, but it is not well suitable for the actual multi-input-multi-output system. The paper aims at the modeling of multi-output systems by LS-SVR. The multi-output LS-SVR is derived in detail. To avoid the inversion of large matrix, the recursive algorithm of the parameters is given, which makes the online algorithm of LS-SVR practical. Since the computing time increases with the number of training samples, the sparseness is studied based on the pro-jection of online LS-SVR. The residual of projection less than a threshold is omitted, so that a lot of samples are kept out of the training set and the sparseness is obtained. The standard LS-SVR, nonsparse online LS-SVR and sparse online LS-SVR with different threshold are used for modeling the isomerization of C8 aromatics. The root-mean-square-error (RMSE), number of support vectors and running time of three algorithms are compared and the result indicates that the performance of sparse online LS-SVR is more favorable.
基金financially supported by the National Natural Science Foundation of China (Nos. 51174212, 51474219 and 51304213)the Special Research Foundation for Doctorate Disciplines in Universities of China (No. 20120023110006)State Key Laboratory for Coal Resources and Safe Mining, China University of Mining and Technology (No. SKLCRSM13KFB08)
文摘In order to analyze the propagation characteristics of shock wave and gas flow induced by outburst intensity, the governing equations of shock wave and gas flow propagation were put forward, and the numerical simulation boundary condition was obtained based on outburst characteristics. The propagation characteristics of shock wave and gas flow were simulated by Fluent software, and the simulation results were verified by experiments. The results show that air shock wave is formed due to air medium compressed by the transient high pressure gas which rapidly expands in the roadway; the shock wave and gas flow with high velocity are formed behind the shock wave front, which significantly decays due to limiting effect of the roadway wall. The attenuation degree is greater in the early stage than that in the late stage, and the velocity of gas convection transport is lower than the speed of the shock wave.The greater the outburst intensity is, the greater the pressure of the shock wave front is, and the higher the speed of the shock wave and gas flow is.
基金Supported by the State Key Development Program for Basic Research of China (2004CB619202) and the National Natural Science Foundation of China (50174034, 30170026).
文摘A mathematical model for enargite bioleaching at 70℃ by Sulfolobus BC in shake-flasks has been constructed. The model included (1) the indirect leaching by Fe^3+ and Fe^3+ regeneration by suspended Sulfolobus, and (2) the direct leaching by the attached Sulfolobus. The model parameters were optimized using genetic algorithm (GA). Simulations of the ferric leaching, and bioleaching processes were done using this model. The dynamic changes of the concentrations of Cu^2+, As^3+, As^5+, Fe^3+ and/or Fe^2+, as well as ferric-arsenate precipitation were accurately predicted.
文摘An outburst of coal and gas is a major hazard in underground coal mining. It is generally accepted that an outburst occurs when certain conditions of stress, coal gassiness and physical-mechanical properties of coal are met. Outbursting is recognized as a two-step process, i.e., initiation and development. In this paper, we present a fully-coupled solid and fluid code to model the entire process of an outburst. The deformation, failure and fracture of solid (coal) are modeled with the discrete element method, and the flow of fluid (gas and water) such as free flow and Darcy flow are modeled with the lattice Boltzmann method. These two methods are coupled in a two-way process, i.e., the solid part provides a moving boundary condition and transfers momentum to the fluid, while the fluid exerts a dragging force upon the solid. Gas desorption from coal occurs at the solid-fluid boundary, and gas diffusion is implemented in the solid code where particles are assumed to be porous. A simple 2D example to simulate the process of an outburst with the model is also presented in this paper to demonstrate the capability of the coupled model.
基金Supported by the National Natural Science Foundation of China under Grant No.50909028
文摘Acoustic vector sensor consists of pressure and particle velocity sensors,which measure the three-dimensional acoustic particle velocity,as well as the pressure at one location at the same time.By preserving the amplitude and phase information of the pressure and particle velocity,they possess a number of advantages over traditional scalar sensors.Signal-to-noise ratio (SNR) gain (which is often called array gain) is one of such advantages and is always interested by all of us.But it is not unchangeable if the spatial correlation of the noise field varies.Much more important,it is difficult to be given if the noise becomes complex.In this paper,spatial correlation of the vector field of isotropic volume-noise and surface-generated noise has been introduced briefly.Based on the results,the combined SNR output of a vector linear array is investigated and the maximum gain is given in the specified noise.Computer simulation shows that the output of one array in the same noise is not the same in different gestures.And then we find the best gesture through SNR calculation and obtain the biggest gain,which has important meaning to guide how to deploy an array in practice.We also should use the array with respect to the characteristics of the real ambient noise,especially in anisotropic noise field.
基金Financial support provided by the National Basic Research Program of China(No. 2011CB201205)the National Natural Science Foundation of China (No. 51074161)+2 种基金the Independent Research Fund of the State Key Laboratory of Coal Resources and Mine Safety(No. SKLCRSM08X03)the Research Fund of the State Key Laboratory of Coal Resources and Mine Safety, CUMT (No. 09KF09)the National Natural Science Foundation of Youth Science Foundationof China (No. 50804048)
文摘An auxiliary gas control technology is described that can reduce coal and gas outburst accidents when there is no existing protective coal seam and gas pre-draining is not effective.Numerical simulation methods were used to study the stress distribution ahead of the roadway face for different in situ stresses.The results from the simulation can then provide a new gas control technology.The results show that a high stress concentration,high stresses,and high displacement gradients appear ahead of the roadway face when the maximum in situ stress is aligned perpendicular to the roadway axis.The risk of gas outburst is higher when the stresses decrease rapidly over distance and when the release of more energy occurs immediately after driving the roadway.The gas outburst risk is much smaller when the in situ stress is aligned parallel to the roadway axis.During design of the coal mine most of the coal roadways should be arranged to parallel the maximum in situ stress.This will decrease the outburst risk in general and may be considered a new gas outburst prevention method.
文摘The paper deals with control of supply in pipe networks based on so-called Dynamic Virtual Distortion Method. Making use of the analytical network model of this installation and using presented below, the so-called Virtual Distortion Method (VDM), the control of water supply can be performed. Minimization of supply pressure in inlets to the network, subject to inequality constraints imposed on outlet pressure (in chosen nodes) is discussed. Taking advantage of pre-computed influence vectors, the real-time control strategy can be realised with small computational effort and therefore, can be managed with use of hardware-based controllers. Non-linear constitutive relation (water flow vs. pressure head) has been assumed.