The complex of[N,N,N ’ ,N ’- tetrakis(2 - benzimida zolyl methyl) - 1,4 - diethylene amino] - glycol ether(EGTB)with zinc (Ⅱ) ,[Zn 2 (EGTB)Cl 2 ](ClO 4 ) 2 · CH 3 OH · 3H 2 O was synthesized and character...The complex of[N,N,N ’ ,N ’- tetrakis(2 - benzimida zolyl methyl) - 1,4 - diethylene amino] - glycol ether(EGTB)with zinc (Ⅱ) ,[Zn 2 (EGTB)Cl 2 ](ClO 4 ) 2 · CH 3 OH · 3H 2 O was synthesized and characterized with element analysis,UV and IR spectroscopy,and X - ray diffraction method.The crystal belongs to monoclinic with space group of P2 1 /c.The cell parameters are a=1.4376(2)nm,b=2.52650(4)nm,c=1.43531(2)nm,β =101.7037(8) ° ,Z=4,F(000)=2376,D c =1.503g · cm -3 ,The final R=0.0804,wR 2 =0.2236.Biological activities of the complexe was traced by UV - Vis spectrum.The result demonstrates that the complexe has good catalytic abliliy.CCDC:180994.展开更多
A wave flume simulator was used to study internal nitrogen release from the surface sediment collected from Taihu Lake, China. Particulate nitrogen concentrations were positively correlated with the concentrations of ...A wave flume simulator was used to study internal nitrogen release from the surface sediment collected from Taihu Lake, China. Particulate nitrogen concentrations were positively correlated with the concentrations of suspended solids, primarily from surface erosion related to the shear stress and duration of wave action. In response to 4 cm- and 10 cm-high wave production representing waves generated in Taihu Lake by gentle and gusty winds, respectively, the mean dynamic release rate of ammonium （NH4＋） from the sediment to the overlying water was 1 × 10-3 mg/（m2.s） and the NH4＋ concentration in the overlying water increased by 0.016 mg/L, indicating that waves resulting from strong wind can induce the rapid release of dissolved nitrogen from Taihu Lake sediments. The decrease in interstitial NH4＋ concentrations at all sediment depths was associated with an increase in NH4＋ concentrations in the overlying water by 0.01 mg/L, showing that sediment below the eroded layer was the main source of internal nitrogen release. Changes in the interstitial dissolved oxygen and NH4＋ concentrations showed that wave-induced pore water movement can greatly increase the diffusion rate, and that these 15 cm. Diffusion induced by pore water movement sediment layer in Taihu Lake. effects can influence the sediment to a depth of at least may be very important for the formation of an active展开更多
By using the equipment designed and developed by ourselves, experiment of investigating the influence of dissolution on some geo-chemical parameters (such as δ13C,δD,and iC4/nC4 in water-dissolved gas (WDG) during m...By using the equipment designed and developed by ourselves, experiment of investigating the influence of dissolution on some geo-chemical parameters (such as δ13C,δD,and iC4/nC4 in water-dissolved gas (WDG) during migration) was performed. The result shows that, with the increase of distance, 1) the relative abundance of non-hydrocarbon (CO2) and hydrocarbon (CH4) increase while the relative abundance of hydrocarbon (C2+) decreases (the relative abundance of hydrocarbon (C5+) can be basically negligible); 2) the relative abundance of benzene and methylbenzene increase in the initial time and then decrease. The carbon and hydrogen isotopes of methane vary slightly, which can be regarded as indicators of gas dissolved in water formation.展开更多
Based on the characteristics of the strong volatility of physical property in vertical direction, high gas content, high resource abundance and large exploitation potentiality of coal reservoir in Bide-Santang basin o...Based on the characteristics of the strong volatility of physical property in vertical direction, high gas content, high resource abundance and large exploitation potentiality of coal reservoir in Bide-Santang basin of Zhina coal field, we study the generation mechanism of interlayer interference, propagation rules of reservoir pressure drop and influencing factors of gas productivity in CBM multi-seam drainage in the paper. On the basis of the actual production data of X-2 well of Zhucang syncline in Bide-Santang basin,by simulating the gas production process of a CBM well under the condition of multiple seam with COMET3 numerical simulation software, we analyze the influencing factors of gas productivity during the process of multi-seam drainage, and illuminate the interlayer interference mechanism of multiseam drainage. The results show that permeability, reservoir pressure gradient, critical desorption pressure and fluid supply capacity of stratum have great influence on gas productivity of multi-seam drainage while coal thickness has little influence on it. Permeability, reservoir pressure gradient and fluid supply capacity of stratum affect the propagation velocity of reservoir pressure drop and thereby affect the final gas productivity. Moreover, the influence of critical desorption pressure on gas productivity of multiseam drainage is reflected in the gas breakthrough time and effective desorption area.展开更多
The exothermic efficiency of microwave heating an electrolyte/water solution is remarkably high due to the dielectric heating by orientation polarization of water and resistance heating by the Joule process occurred s...The exothermic efficiency of microwave heating an electrolyte/water solution is remarkably high due to the dielectric heating by orientation polarization of water and resistance heating by the Joule process occurred simultaneously compared with pure water.A three-dimensional finite element numerical model of multi-feed microwave heating industrial liquids continuously flowing in a meter-scale circular tube is presented.The temperature field inside the applicator tube in the cavity is solved by COMSOL Multiphysics and professional programming to describe the momentum,energy and Maxwell's equations.The evaluations of the electromagnetic field,the temperature distribution and the velocity field are simulated for the fluids dynamically heated by singleand multi-feed microwave system,respectively.Both the pilot experimental investigations and numerical results of microwave with single-feed heating for fluids with different effective permittivity and flow rates show that the presented numerical modeling makes it possible to analyze dynamic process of multi-feed microwave heating the industrial liquid.The study aids in enhancing the understanding and optimizing of dynamic process in the use of multi-feed microwave heating industrial continuous flow for a variety of material properties and technical parameters.展开更多
In this work, a numerical study for designing a new kind of MHD （Magneto-Hydrn-Dynamic） pumps is presented. This technique makes a compromise between electrolysis prevention and high flow rate performance. This tech...In this work, a numerical study for designing a new kind of MHD （Magneto-Hydrn-Dynamic） pumps is presented. This technique makes a compromise between electrolysis prevention and high flow rate performance. This technique should eliminate electrolytic bubble generation, electrodes wear and fluid propriety modification. All these side phenomena are prevented by considering isolated electrodes. The numerical presented results in this paper demonstrate that continuous MHD pumping is possible with isolated electrodes. The MHD excitation combines a high frequency altering current with a low frequency altering magnetic field. In order to validate our results, two independent theoretical methods for computing flow rate are followed. The two presented independent approaches show that high flow rate is possible even with isolated electrodes. To overcome the problem of dimensioning this kind of pumps, a generic numerical analysis is proposed. Hence, the pump performances as functions of the external parameter are studied and tools to calculate for a given fluid and the optimal high frequency regime are provided.展开更多
The reduction of soil and water losses under furrow irrigation with saline water is important to environmental protection and agricultural production. The objective of this study was to determine the effect of polyacr...The reduction of soil and water losses under furrow irrigation with saline water is important to environmental protection and agricultural production. The objective of this study was to determine the effect of polyacrylamide (PAM) application on soil infiltration and erosion under simulated furrow irrigation with saline water. Polyacrylamide was applied by dissolving it in irrigation water at the rates of 1.5, 7.5, and 15.0 mg L-1 or spreading it as a powder on soil surface at the rates of 0.3, 1.5, 3.0, and 6.0 g m-2, respectively. The electrolyte concentration of tested irrigation water was 10 and 30 mmolc L-1 and its sodium adsorption ratio (SAR) was 0.5, 10.0, and 20.0 (mmolc L-1)0.5. Distilled water was used as a control for irrigation water quality. Results indicated that the electrolyte concentration and SAR generally did not significantly affect soil and water losses after PAM application. Infiltration rate and total infiltration volume decreased with the increase of PAM application rate. Polyacrylamide application in both methods significantly reduced soil erosion, but PAM application rate did not significantly affect it. The solution PAM application was more effective in controlling soil erosion than the powdered PAM application, but the former exerted a greater adverse influence on soil infiltration than the latter. Under the same total amounts, the powdered PAM application resulted in a 38.2%-139.6% greater infiltration volume but a soil mass loss of 1.3-3.4 times greater than the solution PAM application.展开更多
文摘The complex of[N,N,N ’ ,N ’- tetrakis(2 - benzimida zolyl methyl) - 1,4 - diethylene amino] - glycol ether(EGTB)with zinc (Ⅱ) ,[Zn 2 (EGTB)Cl 2 ](ClO 4 ) 2 · CH 3 OH · 3H 2 O was synthesized and characterized with element analysis,UV and IR spectroscopy,and X - ray diffraction method.The crystal belongs to monoclinic with space group of P2 1 /c.The cell parameters are a=1.4376(2)nm,b=2.52650(4)nm,c=1.43531(2)nm,β =101.7037(8) ° ,Z=4,F(000)=2376,D c =1.503g · cm -3 ,The final R=0.0804,wR 2 =0.2236.Biological activities of the complexe was traced by UV - Vis spectrum.The result demonstrates that the complexe has good catalytic abliliy.CCDC:180994.
基金Supported by the National Natural Science Foundation of China(Nos.41101458, 40825004,40871095,40801200)the Major Project for National Science and Technology Development(No.2010ZX03006-006)the "100-Talent Project" of Chinese Academy of Sciences,China(No.YOBROB045)
文摘A wave flume simulator was used to study internal nitrogen release from the surface sediment collected from Taihu Lake, China. Particulate nitrogen concentrations were positively correlated with the concentrations of suspended solids, primarily from surface erosion related to the shear stress and duration of wave action. In response to 4 cm- and 10 cm-high wave production representing waves generated in Taihu Lake by gentle and gusty winds, respectively, the mean dynamic release rate of ammonium （NH4＋） from the sediment to the overlying water was 1 × 10-3 mg/（m2.s） and the NH4＋ concentration in the overlying water increased by 0.016 mg/L, indicating that waves resulting from strong wind can induce the rapid release of dissolved nitrogen from Taihu Lake sediments. The decrease in interstitial NH4＋ concentrations at all sediment depths was associated with an increase in NH4＋ concentrations in the overlying water by 0.01 mg/L, showing that sediment below the eroded layer was the main source of internal nitrogen release. Changes in the interstitial dissolved oxygen and NH4＋ concentrations showed that wave-induced pore water movement can greatly increase the diffusion rate, and that these 15 cm. Diffusion induced by pore water movement sediment layer in Taihu Lake. effects can influence the sediment to a depth of at least may be very important for the formation of an active
文摘By using the equipment designed and developed by ourselves, experiment of investigating the influence of dissolution on some geo-chemical parameters (such as δ13C,δD,and iC4/nC4 in water-dissolved gas (WDG) during migration) was performed. The result shows that, with the increase of distance, 1) the relative abundance of non-hydrocarbon (CO2) and hydrocarbon (CH4) increase while the relative abundance of hydrocarbon (C2+) decreases (the relative abundance of hydrocarbon (C5+) can be basically negligible); 2) the relative abundance of benzene and methylbenzene increase in the initial time and then decrease. The carbon and hydrogen isotopes of methane vary slightly, which can be regarded as indicators of gas dissolved in water formation.
基金supported by the National Major Special Project of Science and Technology of China (No.2011ZX05034)the Innovation Projects of University Graduates in Jiangsu Province (No.CXLX13_948)+1 种基金the National Natural Science Foundation of China (No.41272178)the Natural Science Foundation of Hunan Province (No.2016JJ4031)
文摘Based on the characteristics of the strong volatility of physical property in vertical direction, high gas content, high resource abundance and large exploitation potentiality of coal reservoir in Bide-Santang basin of Zhina coal field, we study the generation mechanism of interlayer interference, propagation rules of reservoir pressure drop and influencing factors of gas productivity in CBM multi-seam drainage in the paper. On the basis of the actual production data of X-2 well of Zhucang syncline in Bide-Santang basin,by simulating the gas production process of a CBM well under the condition of multiple seam with COMET3 numerical simulation software, we analyze the influencing factors of gas productivity during the process of multi-seam drainage, and illuminate the interlayer interference mechanism of multiseam drainage. The results show that permeability, reservoir pressure gradient, critical desorption pressure and fluid supply capacity of stratum have great influence on gas productivity of multi-seam drainage while coal thickness has little influence on it. Permeability, reservoir pressure gradient and fluid supply capacity of stratum affect the propagation velocity of reservoir pressure drop and thereby affect the final gas productivity. Moreover, the influence of critical desorption pressure on gas productivity of multiseam drainage is reflected in the gas breakthrough time and effective desorption area.
基金Project(KKSY201503006)supported by Scientific Research Foundation of Kunming University of Science and Technology,ChinaProject(2014FD009)supported by the Applied Basic Research Foundation(Youth Program)of ChinaProject(51090385)supported by the National Natural Science Foundation of China
文摘The exothermic efficiency of microwave heating an electrolyte/water solution is remarkably high due to the dielectric heating by orientation polarization of water and resistance heating by the Joule process occurred simultaneously compared with pure water.A three-dimensional finite element numerical model of multi-feed microwave heating industrial liquids continuously flowing in a meter-scale circular tube is presented.The temperature field inside the applicator tube in the cavity is solved by COMSOL Multiphysics and professional programming to describe the momentum,energy and Maxwell's equations.The evaluations of the electromagnetic field,the temperature distribution and the velocity field are simulated for the fluids dynamically heated by singleand multi-feed microwave system,respectively.Both the pilot experimental investigations and numerical results of microwave with single-feed heating for fluids with different effective permittivity and flow rates show that the presented numerical modeling makes it possible to analyze dynamic process of multi-feed microwave heating the industrial liquid.The study aids in enhancing the understanding and optimizing of dynamic process in the use of multi-feed microwave heating industrial continuous flow for a variety of material properties and technical parameters.
文摘In this work, a numerical study for designing a new kind of MHD （Magneto-Hydrn-Dynamic） pumps is presented. This technique makes a compromise between electrolysis prevention and high flow rate performance. This technique should eliminate electrolytic bubble generation, electrodes wear and fluid propriety modification. All these side phenomena are prevented by considering isolated electrodes. The numerical presented results in this paper demonstrate that continuous MHD pumping is possible with isolated electrodes. The MHD excitation combines a high frequency altering current with a low frequency altering magnetic field. In order to validate our results, two independent theoretical methods for computing flow rate are followed. The two presented independent approaches show that high flow rate is possible even with isolated electrodes. To overcome the problem of dimensioning this kind of pumps, a generic numerical analysis is proposed. Hence, the pump performances as functions of the external parameter are studied and tools to calculate for a given fluid and the optimal high frequency regime are provided.
基金the National Natural Science Foundation of China (No.40635027)the State Key Laboratory of Soil Erosion and Dryland Farming on Loess Plateau of China (No.10501-169)
文摘The reduction of soil and water losses under furrow irrigation with saline water is important to environmental protection and agricultural production. The objective of this study was to determine the effect of polyacrylamide (PAM) application on soil infiltration and erosion under simulated furrow irrigation with saline water. Polyacrylamide was applied by dissolving it in irrigation water at the rates of 1.5, 7.5, and 15.0 mg L-1 or spreading it as a powder on soil surface at the rates of 0.3, 1.5, 3.0, and 6.0 g m-2, respectively. The electrolyte concentration of tested irrigation water was 10 and 30 mmolc L-1 and its sodium adsorption ratio (SAR) was 0.5, 10.0, and 20.0 (mmolc L-1)0.5. Distilled water was used as a control for irrigation water quality. Results indicated that the electrolyte concentration and SAR generally did not significantly affect soil and water losses after PAM application. Infiltration rate and total infiltration volume decreased with the increase of PAM application rate. Polyacrylamide application in both methods significantly reduced soil erosion, but PAM application rate did not significantly affect it. The solution PAM application was more effective in controlling soil erosion than the powdered PAM application, but the former exerted a greater adverse influence on soil infiltration than the latter. Under the same total amounts, the powdered PAM application resulted in a 38.2%-139.6% greater infiltration volume but a soil mass loss of 1.3-3.4 times greater than the solution PAM application.
