碱金属阳离子对手性硼磷酸铜锂化合物LiCu_2[BP_2O_8(OH)_2]晶化的影响

采用硼酸熔融法研究对映体过量的开放骨架硼磷酸铜锂化合物LiCu_2[BP_2O_8(OH)_2]的合成条件,并用Na和K源取代Li源合成该手性化合物.实验结果表明:水和Li^+是生成该手性化合物的关键因素,水过量会使Li^+无法参与晶化,少量的水会促进目标产物形成大单晶;Na^+不能取代Li^+合成该化合物,K^+仅可部分取代Li^+合成该化合物,所得产物均发生对称性破缺.

Simulation of type selection for 6-high cold tandem mill based on shape control ability

A theoretical method for selecting strip rolling mill type that considered shape control ability was established using the figure alteration range that was worked by the alteration track of vector expressing strip's cross section (crown) to express the shape control ability of rolling mill. With the mathematical models and simulation software that were developed by the authors' own models, four types of mills were aimed, including HCM (6-high middle rolls shift type HC (high crown) -mill), HCMW (6-high middle rolls and work rolls shift type HC-mill), UCM (6-high middle rolls shift type HC-mill with middle roll bender) and UCMW (6-high middle rolls and work rolls shift type HC-mill with middle roll bender), and the shape and crown control ability of every mill type was analyzed and compared. An appropriate arrangement mode of tandem mill was brought forward. The results show that UCMW mill is a perfect choice for controlling shape and crown, and the area of control characteristics curve of UCMW (or UCM) is twice than that of HCM, but UCM mill is also a good choice for its simple frame. In other word, the shape and crown controlling ability of UCMW mill is better than that of UCM mill, but the frame of UCM mill is simpler than that of UCMW mill. As for the final type of mill, should be synthetically decided by thinking over fund and equipment technology.

Evaluation of straightening capacity of plate roll straightener

Straightening machine is widely used for improving the quality of the defective mild steel plates.In general,the capacity of straightening machine is affected by material properties,the initial shape of the incoming plate and the plastic ratio.The mechanics model describing the capacity of the machine was developed.The deviation of the straightening capacity curves was studied.Then,the presented model was evaluated by comparative study to filed production data.Finally,the influences of overstretch,straightening speed,strengthening coefficient,elastic modulus,width of the plate on the straightening capacity were studied.It is convenient to determine whether the plate can be straightened or not by a series of straightening capacity curves.The straightening speed,width of the plate and elastic modulus of the material are more sensitive to the straightening capacity than the strengthening coefficient.

Determining the approach speed envelope of carrier aircraft

Many factors,such as deck motion and air wave,influence the determination of the approach speed which has an important effect on landing safety. Until recently,there are no design criteria about approach speed of carrier aircraft in the current standards and available publications. Therefore,the requirements of stall margin, longitudinal acceleration ability,altitude correction and field-of-view on approach speed were researched. Based on the flight dynamics model,the flight simulations were conducted to study the effect of the response time of engine,wave off requirements,elevator efficiency and deflection rate on the approach speed. The results presented that the approach longitudinal acceleration and altitude correction ability had crucial influence on the approach speed envelope of the aircraft. The limitations of the control requirements,field- of- view requirements and gear were also given through the simulation and analysis. Based on the above results,the approach speed envelope were determined.

Lateral load-carrying capacity analyses of composite shear walls with double steel plates and filled concrete with binding bars

A method is developed to predict the lateral load-carrying capacity of composite shear walls with double steel plates and filled concrete with binding bars(SCBs). Nonlinear finite element models of SCBs were established by using the finite element tool, Abaqus. Tie constraints were used to connect the binding bars and the steel plates. Surface-to-surface contact provided by the Abaqus was used to simulate the interaction between the steel plate and the core concrete. The established models could predict the lateral load-carrying capacity of SCBs with a reasonable degree of accuracy. A calculation method was developed by superposition principle to predict the lateral load-carrying capacity of SCBs for the engineering application. The concrete confined by steel plates and binding bars is under multi-axial compression; therefore, its shear strength was calculated by using the Guo-Wang concrete failure criterion. The shear strength of the steel plates of SCBs was calculated by using the von Mises yielding criterion without considering buckling. Results of the developed method are in good agreement with the testing and finite element results.

Introducing semantic information into motion graph

To improve motion graph based motion synthesis,semantic control was introduced.Hybrid motion features including both numerical and user-defined semantic relational features were extracted to encode the characteristic aspects contained in the character's poses of the given motion sequences.Motion templates were then automatically derived from the training motions for capturing the spatio-temporal characteristics of an entire given class of semantically related motions.The data streams of motion documents were automatically annotated with semantic motion class labels by matching their respective motion class templates.Finally,the semantic control was introduced into motion graph based human motion synthesis.Experiments of motion synthesis demonstrate the effectiveness of the approach which enables users higher level of semantically intuitive control and high quality in human motion synthesis from motion capture database.

Slat Noise Suppression Using Upstream Mass Injection

A new approach,mass injection near the slat cusp,is proposed for the suppression of slat noise.The mechanism and efciency of the slat noise suppression using upstream mass injection are numerically studied with hybrid Reynolds-averaged Navier-Stokes simulation/Large eddy simulation(RANS/LES)of a three-component high-lift model.Ffowcs-Williams and Hawking(FW-H)integration is employed to obtain far-field acoustic characteristics.Results show that with injection,aerodynamic capability of the high-lift devices is sustained.In addition,a considerable noise reduction is observed in the downward direction.With detailed analysis of the time-averaged and instantaneous flow fields,two mechanisms are identified as the reason accounting for the noise suppression:upstream mass injection significantly reduces the scale and strength of the vortices stemming from the cusp;the shear layer is lifted up,which relieves the shear layer impingement on the slat lower surface.