In order to detect whether the data conforms to the given model, it is necessary to diagnose the data in the statistical way. The diagnostic problem in generalized nonlinear models based on the maximum Lq-likelihood e...In order to detect whether the data conforms to the given model, it is necessary to diagnose the data in the statistical way. The diagnostic problem in generalized nonlinear models based on the maximum Lq-likelihood estimation is considered. Three diagnostic statistics are used to detect whether the outliers exist in the data set. Simulation results show that when the sample size is small, the values of diagnostic statistics based on the maximum Lq-likelihood estimation are greater than the values based on the maximum likelihood estimation. As the sample size increases, the difference between the values of the diagnostic statistics based on two estimation methods diminishes gradually. It means that the outliers can be distinguished easier through the maximum Lq-likelihood method than those through the maximum likelihood estimation method.展开更多
This study focused on the quantitative evaluation of the impact of the spatio-temporal scale used in data collection and grouping on the standardization of CPUE(catch per unit effort).We used the Chinese squid-jigging...This study focused on the quantitative evaluation of the impact of the spatio-temporal scale used in data collection and grouping on the standardization of CPUE(catch per unit effort).We used the Chinese squid-jigging fishery in the northwestern Pacific Ocean as an example to evaluate 24 scenarios at different spatio-temporal scales,with a combination of four levels of temporal scale(weekly,biweekly,monthly,and bimonthly)and six levels of spatial scale(longitude×latitude:0.5°×0.5°,0.5°×1°,0.5°×2°,1°×0.5°,1°×1°,and 1°×2°).We applied generalized additive models and generalized linear models to analyze the24 scenarios for CPUE standardization,and then the differences in the standardized CPUE among these scenarios were quantified.This study shows that combinations of different spatial and temporal scales could have different impacts on the standardization of CPUE.However,at a fine temporal scale(weekly)different spatial scales yielded similar results for standardized CPUE.The choice of spatio-temporal scale used in data collection and analysis may create added uncertainty in fisheries stock assessment and management.To identify a cost-effective spatio-temporal scale for data collection,we recommend a similar study be undertaken to facilitate the design of effective monitoring programs.展开更多
The first Chinese microwave ocean environment satellite HY-2A was launched successfully in August, 201 I. This study presents a quality assessment of HY-2A scatterometer (HYSCAT) data based on comparison with ocean ...The first Chinese microwave ocean environment satellite HY-2A was launched successfully in August, 201 I. This study presents a quality assessment of HY-2A scatterometer (HYSCAT) data based on comparison with ocean buoy data, the Advanced Scatterometer (ASCAT) data, and numerical model data from the National Centers for Environmental Prediction (NCEP). The in-situ observations include those from buoy arrays operated by the National Data Buoy Center (NDBC) and Tropical Atmosphere Ocean (TAO) project. Only buoys located offshore and in deep water were analyzed. The temporal and spatial collocation windows between HYSCAT data and buoy observations were 30 min and 25 km, respectively. The comparisons showed that the wind speeds and directions observed by HYSCAT agree well with the buoy data. The root-mean-squared errors (RMSEs) of wind speed and direction for the HYSCAT standard wind products are 1.90 m/s and 22.80°, respectively. For the HYSCAT-ASCAT comparison, the temporal and spatial differences were limited to 1 h and 25 km, respectively. This comparison yielded RMSEs of 1.68 m/s for wind speed and 19.1° for wind direction. We also compared HYSCAT winds with reanalysis data from NCEP. The results show that the RMSEs of wind speed and direction are 2.6 m/s and 26°, respectively. The global distribution of wind speed residuals (HYSCAT-NCEP) is also presented here for evaluation of the HYSCAT-retrieved wind field globally. Considering the large temporal and spatial differences of the collocated data, it is concluded that the HYSCAT-retrieved wind speed and direction met the mission requirements, which were 2 rn/s and 20° for wind speeds in the range 2-24 m/s. These encouraging assessment results show that the wind data obtained from HYSCAT will be useful for the scientific community.展开更多
In this letter,Constructive Neural Networks (CNN) is used in large-scale data mining. By introducing the principle and characteristics of CNN and pointing out its deficiencies,fuzzy theory is adopted to improve the co...In this letter,Constructive Neural Networks (CNN) is used in large-scale data mining. By introducing the principle and characteristics of CNN and pointing out its deficiencies,fuzzy theory is adopted to improve the covering algorithms. The threshold of covering algorithms is redefined. "Extended area" for test samples is built. The inference of the outlier is eliminated. Furthermore,"Sphere Neighborhood (SN)" are constructed. The membership functions of test samples are given and all of the test samples are determined accordingly. The method is used to mine large wireless monitor data (about 3×107 data points),and knowledge is found effectively.展开更多
To determine the distribution of positional error of a line segment, Monte Carlo approach is applied to simulate the probability density function of a line segment with the assumption that the error of endpoints in a ...To determine the distribution of positional error of a line segment, Monte Carlo approach is applied to simulate the probability density function of a line segment with the assumption that the error of endpoints in a line segment follows a two-dimensional normal distribution. For such purpose, a stochastic generator used for uncertain endpoints with the two-dimensional normal distribution is presented. This forms the basis of the generation of random line segment for the simulation of the error model of a whole line segment. The error models cover the cases where two endpoints are either independent or dependent to each other, also including a special case that the distance between two random endpoints in a line segment is close enough.展开更多
A fully flexible potential model for carbon dioxide has been developed to predict the vapor-liquid coexistence properties using the NVT-Gibbs ensemble Monte Carlo technique(GEMC).The average absolute deviation between...A fully flexible potential model for carbon dioxide has been developed to predict the vapor-liquid coexistence properties using the NVT-Gibbs ensemble Monte Carlo technique(GEMC).The average absolute deviation between our simulation and the literature experimental data for saturated liquid and vapor densities is 0.3% and 2.0%,respectively.Compared with the experimental data,our calculated results of critical properties(7.39 MPa,304.04 K,and 0.4679 g?cm-3) are acceptable and are better than those from the rescaling the potential parameters of elementary physical model(EPM2).The agreement of our simulated densities of supercritical carbon dioxide with the experimental data is acceptable in a wide range of pressure and temperature.The radial distribution function estimated at the supercritical conditions suggests that the carbon dioxide is a nonlinear molecule with the C O bond length of 0.117 nm and the O C O bond angle of 176.4°,which are consistent with Car-Parrinello molecular-dynamics(CPMD),whereas the EPM2 model shows large deviation at supercritical state.The predicted self-diffusion coefficients are in agreement with the experiments.展开更多
Spatial downscaling methods are widely used for the production of bioclimatic variables(e.g. temperature and precipitation) in studies related to species ecological niche and drainage basin management and planning. Th...Spatial downscaling methods are widely used for the production of bioclimatic variables(e.g. temperature and precipitation) in studies related to species ecological niche and drainage basin management and planning. This study applied three different statistical methods, i.e. the moving window regression(MWR), nonparametric multiplicative regression(NPMR), and generalized linear model(GLM), to downscale the annual mean temperature(Bio1) and annual precipitation(Bio12) in central Iran from coarse scale(1 km × 1 km) to fine scale(250 m ×250 m). Elevation, aspect, distance from sea and normalized difference vegetation index(NDVI) were used as covariates to create downscaled bioclimatic variables. Model assessment was performed by comparing model outcomes with observational data from weather stations. Coefficients of determination(R2), bias, and root-mean-square error(RMSE) were used to evaluate models and covariates. The elevation could effectively justify the changes in bioclimatic factors related to temperature and precipitation. Allthree models could downscale the mean annual temperature data with similar R2, RMSE, and bias values. The MWR had the best performance and highest accuracy in downscaling annual precipitation(R2=0.70; RMSE=123.44). In general, the two nonparametric models, i.e. MWR and NPMR, can be reliably used for the downscaling of bioclimatic variables which have wide applications in species distribution modeling.展开更多
A model to describe the hysteresis damping characteristic of rubber material was presented.It consists of a parallel spring and damper,whose coefficients change with the vibration amplitude and frequency.In order to a...A model to describe the hysteresis damping characteristic of rubber material was presented.It consists of a parallel spring and damper,whose coefficients change with the vibration amplitude and frequency.In order to acquire these relations,force decomposition was carried out according to some sine vibration measurement data of nonlinear forces changing with the deformation of the rubber material.The nonlinear force is decomposed into a spring force and a damper force,which are represented by the amplitude-and frequency-dependent spring and damper coefficients,respectively.Repeating this step for different measurements gives different coefficients corresponding to different amplitudes and frequencies.Then,the application of a parameter identification method provides the requested approximation functions over amplitude and frequency.Using those formulae,as an example,the dynamic characteristic of a hollow shaft system supported by rubber rings was analyzed and the acceleration response curve in the centroid position was calculated.Comparisons with the sine vibration experiments of the real system show a maximal inaccuracy of 8.5%.Application of this model and procedure can simplify the modeling and analysis of mechanical systems including rubber materials.展开更多
In this study the copper and lead adsorption efficiency onto banana peels powder was investigated. The agroindustrial waste recovery represents one of the Circular Economy pillars. In the view of the synthesis of an e...In this study the copper and lead adsorption efficiency onto banana peels powder was investigated. The agroindustrial waste recovery represents one of the Circular Economy pillars. In the view of the synthesis of an environmentally friendly adsorbent material, the powder was used without any preliminary chemical or thermal activation, but only after simple washing, drying and grinding. The bio-adsorbent was characterized by the FTIR technique and tested in batch mode on synthetic aqueous solutions containing Pb and Cu in the range 10–90 mg·L^(-1). A selection of two(Langmuir, Freundlich) and three(Sips, Redlich–Peterson, Koble–Corrigan) parameter isotherm models was chosen to fit adsorption equilibrium data by non-linear regression procedure. The best fit isotherm model was selected relying on the error function with the lowest average percentage error(APE) value, among those characterized by the highest R^2 values. As expected, the three-parameter models are found to better represent both metals bio-adsorption, with APE and R^2 values always lower and higher, respectively, than the corresponding values obtained for the two-parameter models.展开更多
A statistical downscaling approach based on multiple-linear-regression(MLR) for the prediction of summer precipitation anomaly in southeastern China was established,which was based on the outputs of seven operational ...A statistical downscaling approach based on multiple-linear-regression(MLR) for the prediction of summer precipitation anomaly in southeastern China was established,which was based on the outputs of seven operational dynamical models of Development of a European Multi-model Ensemble System for Seasonal to Interannual Prediction(DEMETER) and observed data.It was found that the anomaly correlation coefficients(ACCs) spatial pattern of June-July-August(JJA) precipitation over southeastern China between the seven models and the observation were increased significantly;especially in the central and the northeastern areas,the ACCs were all larger than 0.42(above 95% level) and 0.53(above 99% level).Meanwhile,the root-mean-square errors(RMSE) were reduced in each model along with the multi-model ensemble(MME) for some of the stations in the northeastern area;additionally,the value of RMSE difference between before and after downscaling at some stations were larger than 1 mm d-1.Regionally averaged JJA rainfall anomaly temporal series of the downscaling scheme can capture the main characteristics of observation,while the correlation coefficients(CCs) between the temporal variations of the observation and downscaling results varied from 0.52 to 0.69 with corresponding variations from-0.27 to 0.22 for CCs between the observation and outputs of the models.展开更多
The equilibrium constant (K0), change in free energy (△G), enthalpy (△H) and entropy (△S) of ammonium adsorption by a Cuban natural zeolite were estimated at the temperatures of 25, 35, 45 and 55℃ using ex...The equilibrium constant (K0), change in free energy (△G), enthalpy (△H) and entropy (△S) of ammonium adsorption by a Cuban natural zeolite were estimated at the temperatures of 25, 35, 45 and 55℃ using extensively used approaches. Equilibrium data were obtained in the concentration range 50-1,200 mg·L-1 of ammonium and used in the estimation of thermodynamic parameters. Freundlich's isotherm model was found as with the best adjustment to equilibrium data at 25, 45 and 55℃, whereas, Redlich-Peterson's model had a better performance at 35 ℃. A discontinuous and unusual behavior was observed on adsorption capacity of the zeolite, with an increase from 25 ℃ to 35 ℃ followed by a decrease from 35℃ to 55 ℃. K0 values presented differences that reached up to 105 from one methodology to other. Depending on the method considered, AS results indicated both increase or decrease in system degree of disorder and △G indicated both physisorption or chemisorption process, proving the poor correlation between the estimation proceedings of such important data. The results from Gaines and Thomas method were recognized as the most correlated to calorimetric studies, as well as to equilibrium data and observations related to system entropy.展开更多
The study deals with adsorption of Naphthol Green B on two unburned carbons and the parent coal,from which the UCs have been created in a fluidised-bed power station.Particular attention has been paid to the adsorptio...The study deals with adsorption of Naphthol Green B on two unburned carbons and the parent coal,from which the UCs have been created in a fluidised-bed power station.Particular attention has been paid to the adsorption equilibrium modelling:experimental data has been analysed using 2-parameter(Langmuir,Freundlich) and3-parameter(Redlich-Peterson) isotherms — both linear and non-linear regressions have been used for the estimation of the isotherm parameters.In the case of both UCs,the Langmuir isotherm model provides the worst fit,whereas 2-parameter Freundlich and 3-parameter Redlich-Peterson models are both good,from which 3-parameter Redlich-Peterson isotherm provides slightly better results(despite the penalty used for the higher number of parameters).In the case of both UCs,the linear regression of Freundlich and Redlich-Peterson models provides good results(comparable with non-linear regressions).Unlike both UCs,the best fit of the experimental data from the adsorption on the coal has been achieved by the Langmuir isotherm model.The results based on the Freundlich or Redlich-Peterson model were(in this case) somewhat worse.展开更多
At present, there are no reliable methods to evaluate uncertainty of model representation of magnetic field (MF) in the whole volume of the Earth's magnetosphere. Cosmic ray intensity distribution on the Earth surf...At present, there are no reliable methods to evaluate uncertainty of model representation of magnetic field (MF) in the whole volume of the Earth's magnetosphere. Cosmic ray intensity distribution on the Earth surface contains information on the space distribution of magnetospheric MF through which charged particles propagate. Feasibility and limitations of cosmic ray data to be a tool for the validation of magnetospheric MF models have been analyzed. The authors' approach is based on the fact that time variations of magnetospheric cosmic ray are related to the changes in geomagnetic cutoff rigidities. The obtained cutoff rigidity changes by the trajectory tracing method in the MF model with those obtained on the base of experimental cosmic ray data have also been compared. The obtained results have shown that cosmic ray data can be successfully used for validation of models in presenting the dynamic structure of magnetospheric MF at mid latitudes.展开更多
A linear mixed model is used to determine the explaining infant mortality rate data of United Nations countries. The HDI (human development index) has a significant negative linear relationship with infant mortality...A linear mixed model is used to determine the explaining infant mortality rate data of United Nations countries. The HDI (human development index) has a significant negative linear relationship with infant mortality rate. United Nations data shows that the infant mortality rate has a descending trend over the period 1990-2010. This study aims to assess the value of the HDI as a predictor of infant mortality rate. Findings in the paper suggest that significant percentage reductions in infant mortality might be possible for countries for controlling the HDI.展开更多
Fault monitoring of bioprocess is important to ensure safety of a reactor and maintain high quality of products. It is difficult to build an accurate mechanistic model for a bioprocess, so fault monitoring based on ri...Fault monitoring of bioprocess is important to ensure safety of a reactor and maintain high quality of products. It is difficult to build an accurate mechanistic model for a bioprocess, so fault monitoring based on rich historical or online database is an effective way. A group of data based on bootstrap method could be resampling stochastically, improving generalization capability of model. In this paper, online fault monitoring of generalized additive models (GAMs) combining with bootstrap is proposed for glutamate fermentation process. GAMs and bootstrap are first used to decide confidence interval based on the online and off-line normal sampled data from glutamate fermentation experiments. Then GAMs are used to online fault monitoring for time, dissolved oxygen, oxygen uptake rate, and carbon dioxide evolution rate. The method can provide accurate fault alarm online and is helpful to provide useful information for removing fault and abnormal phenomena in the fermentation.展开更多
In this paper we revise the moment theory for pattern recognition designed, to extract patterns from the noisy character datas, and develop unconstrained handwritten. Amazigh character recognition method based upon or...In this paper we revise the moment theory for pattern recognition designed, to extract patterns from the noisy character datas, and develop unconstrained handwritten. Amazigh character recognition method based upon orthogonal moments and neural networks classifier. We argue that, given the natural flexibility of neural network models and the extent of parallel processing that they allow, our algorithm is a step forward in character recognition. More importantly, following the approach proposed, we apply our system to two different databases, to examine the ability to recognize patterns under noise. We discover overwhelming support for different style of writing. Moreover, this basic conclusion appears to remain valid across different levels of smoothing and insensitive to the nuances of character patterns. Experiments tested the effect of set size on recognition accuracy which can reach 97.46%. The novelty of the proposed method is independence of size, slant, orientation, and translation. The performance of the proposed method is experimentally evaluated and the promising results and findings are presented. Our method is compared to K-NN (k-nearest neighbors) classifier algorithm; results show performances of our method.展开更多
In recent years, sedimentation conditions in Dongting Lake have varied greatly because of signifi cant changes in runoff and sediment load in the Changjiang(Yangtze) River following the construction of Three Gorges Da...In recent years, sedimentation conditions in Dongting Lake have varied greatly because of signifi cant changes in runoff and sediment load in the Changjiang(Yangtze) River following the construction of Three Gorges Dam. The topography of the lake bottom has changed rapidly because of the intense exchange of water and sediment between the lake and the Changjiang River. However, time series information on lake-bottom topographic change is lacking. In this study, we introduced a method that combines remote sensing data and in situ water level data to extract a record of Dongting Lake bottom topography from 2003 to 2011. Multi-temporal lake land/water boundaries were extracted from MODIS images using the linear spectral mixture model method. The elevation of water/land boundary points were calculated using water level data and spatial interpolation techniques. Digital elevation models of Dongting Lake bottom topography in different periods were then constructed with the multiple heighted waterlines. The mean root-mean-square error of the linear spectral mixture model was 0.036, and the mean predicted error for elevation interpolation was-0.19 m. Compared with fi eld measurement data and sediment load data, the method has proven to be most applicable. The results show that the topography of the bottom of Dongting Lake has exhibited uneven erosion and deposition in terms of time and space over the last nine years. Moreover, lake-bottom topography has undergone a slight erosion trend within this period, with 58.2% and 41.8% of the lake-bottom area being eroded and deposited, respectively.展开更多
The generalized linear model is an indispensable tool for analyzing non-Gaussian response data, with both canonical and non-canonical link functions comprehensively used. When missing values are present, many existing...The generalized linear model is an indispensable tool for analyzing non-Gaussian response data, with both canonical and non-canonical link functions comprehensively used. When missing values are present, many existing methods in the literature heavily depend on an unverifiable assumption of the missing data mechanism, and they fail when the assumption is violated. This paper proposes a missing data mechanism that is as generally applicable as possible, which includes both ignorable and nonignorable missing data cases, as well as both scenarios of missing values in response and covariate.Under this general missing data mechanism, the authors adopt an approximate conditional likelihood method to estimate unknown parameters. The authors rigorously establish the regularity conditions under which the unknown parameters are identifiable under the approximate conditional likelihood approach. For parameters that are identifiable, the authors prove the asymptotic normality of the estimators obtained by maximizing the approximate conditional likelihood. Some simulation studies are conducted to evaluate finite sample performance of the proposed estimators as well as estimators from some existing methods. Finally, the authors present a biomarker analysis in prostate cancer study to illustrate the proposed method.展开更多
基金The National Natural Science Foundation of China(No.11171065)the Natural Science Foundation of Jiangsu Province(No.BK2011058)
文摘In order to detect whether the data conforms to the given model, it is necessary to diagnose the data in the statistical way. The diagnostic problem in generalized nonlinear models based on the maximum Lq-likelihood estimation is considered. Three diagnostic statistics are used to detect whether the outliers exist in the data set. Simulation results show that when the sample size is small, the values of diagnostic statistics based on the maximum Lq-likelihood estimation are greater than the values based on the maximum likelihood estimation. As the sample size increases, the difference between the values of the diagnostic statistics based on two estimation methods diminishes gradually. It means that the outliers can be distinguished easier through the maximum Lq-likelihood method than those through the maximum likelihood estimation method.
基金Supported by Shanghai Universities First-class Disciplines Project,Discipline name:Fisheries(A),the National Natural Science Foundation of China(No.NSFC41276156)the National High Technology Research and Development Program of China(863 Program)(No.2012AA092303)+1 种基金the Shanghai Science and Technology Innovation Program(No.12231203900)CHEN Yong’s involvement was supported by the Shanghai Ocean University
文摘This study focused on the quantitative evaluation of the impact of the spatio-temporal scale used in data collection and grouping on the standardization of CPUE(catch per unit effort).We used the Chinese squid-jigging fishery in the northwestern Pacific Ocean as an example to evaluate 24 scenarios at different spatio-temporal scales,with a combination of four levels of temporal scale(weekly,biweekly,monthly,and bimonthly)and six levels of spatial scale(longitude×latitude:0.5°×0.5°,0.5°×1°,0.5°×2°,1°×0.5°,1°×1°,and 1°×2°).We applied generalized additive models and generalized linear models to analyze the24 scenarios for CPUE standardization,and then the differences in the standardized CPUE among these scenarios were quantified.This study shows that combinations of different spatial and temporal scales could have different impacts on the standardization of CPUE.However,at a fine temporal scale(weekly)different spatial scales yielded similar results for standardized CPUE.The choice of spatio-temporal scale used in data collection and analysis may create added uncertainty in fisheries stock assessment and management.To identify a cost-effective spatio-temporal scale for data collection,we recommend a similar study be undertaken to facilitate the design of effective monitoring programs.
基金Supported by the National High Technology Research and Development Program of China(863 Program)(No.2013AA09A505)the National Natural Science Foundation of China(No.40906091)the Open Project of School of Marine Sciences,Nanjing University of Information Science and Technology(No.KHYS1304)
文摘The first Chinese microwave ocean environment satellite HY-2A was launched successfully in August, 201 I. This study presents a quality assessment of HY-2A scatterometer (HYSCAT) data based on comparison with ocean buoy data, the Advanced Scatterometer (ASCAT) data, and numerical model data from the National Centers for Environmental Prediction (NCEP). The in-situ observations include those from buoy arrays operated by the National Data Buoy Center (NDBC) and Tropical Atmosphere Ocean (TAO) project. Only buoys located offshore and in deep water were analyzed. The temporal and spatial collocation windows between HYSCAT data and buoy observations were 30 min and 25 km, respectively. The comparisons showed that the wind speeds and directions observed by HYSCAT agree well with the buoy data. The root-mean-squared errors (RMSEs) of wind speed and direction for the HYSCAT standard wind products are 1.90 m/s and 22.80°, respectively. For the HYSCAT-ASCAT comparison, the temporal and spatial differences were limited to 1 h and 25 km, respectively. This comparison yielded RMSEs of 1.68 m/s for wind speed and 19.1° for wind direction. We also compared HYSCAT winds with reanalysis data from NCEP. The results show that the RMSEs of wind speed and direction are 2.6 m/s and 26°, respectively. The global distribution of wind speed residuals (HYSCAT-NCEP) is also presented here for evaluation of the HYSCAT-retrieved wind field globally. Considering the large temporal and spatial differences of the collocated data, it is concluded that the HYSCAT-retrieved wind speed and direction met the mission requirements, which were 2 rn/s and 20° for wind speeds in the range 2-24 m/s. These encouraging assessment results show that the wind data obtained from HYSCAT will be useful for the scientific community.
基金Supported by the National Natural Science Foundation of China (No.60135010)partially supported by the National Grand Fundamental Research 973 Program of China (No.G1998030509).
文摘In this letter,Constructive Neural Networks (CNN) is used in large-scale data mining. By introducing the principle and characteristics of CNN and pointing out its deficiencies,fuzzy theory is adopted to improve the covering algorithms. The threshold of covering algorithms is redefined. "Extended area" for test samples is built. The inference of the outlier is eliminated. Furthermore,"Sphere Neighborhood (SN)" are constructed. The membership functions of test samples are given and all of the test samples are determined accordingly. The method is used to mine large wireless monitor data (about 3×107 data points),and knowledge is found effectively.
基金Funded by the National Natural Science Foundation of China (N0. 40501053), the Open Research Fund Program of LIESMARS (No. WKL040304) and theOpen Research Fund Program of Key Laboratory of Geomatics and Digital Technology, Shandong Province (No. SD040201)
文摘To determine the distribution of positional error of a line segment, Monte Carlo approach is applied to simulate the probability density function of a line segment with the assumption that the error of endpoints in a line segment follows a two-dimensional normal distribution. For such purpose, a stochastic generator used for uncertain endpoints with the two-dimensional normal distribution is presented. This forms the basis of the generation of random line segment for the simulation of the error model of a whole line segment. The error models cover the cases where two endpoints are either independent or dependent to each other, also including a special case that the distance between two random endpoints in a line segment is close enough.
基金Supported by the National Natural Science Foundation of China (50573063), the Program for New Century Excellent Talents in University of the State Ministry of Education (NCET-05-0566) and the Specialized Research Fund for the Doctoral Program of Higher Education of China (2005038401).
文摘A fully flexible potential model for carbon dioxide has been developed to predict the vapor-liquid coexistence properties using the NVT-Gibbs ensemble Monte Carlo technique(GEMC).The average absolute deviation between our simulation and the literature experimental data for saturated liquid and vapor densities is 0.3% and 2.0%,respectively.Compared with the experimental data,our calculated results of critical properties(7.39 MPa,304.04 K,and 0.4679 g?cm-3) are acceptable and are better than those from the rescaling the potential parameters of elementary physical model(EPM2).The agreement of our simulated densities of supercritical carbon dioxide with the experimental data is acceptable in a wide range of pressure and temperature.The radial distribution function estimated at the supercritical conditions suggests that the carbon dioxide is a nonlinear molecule with the C O bond length of 0.117 nm and the O C O bond angle of 176.4°,which are consistent with Car-Parrinello molecular-dynamics(CPMD),whereas the EPM2 model shows large deviation at supercritical state.The predicted self-diffusion coefficients are in agreement with the experiments.
文摘Spatial downscaling methods are widely used for the production of bioclimatic variables(e.g. temperature and precipitation) in studies related to species ecological niche and drainage basin management and planning. This study applied three different statistical methods, i.e. the moving window regression(MWR), nonparametric multiplicative regression(NPMR), and generalized linear model(GLM), to downscale the annual mean temperature(Bio1) and annual precipitation(Bio12) in central Iran from coarse scale(1 km × 1 km) to fine scale(250 m ×250 m). Elevation, aspect, distance from sea and normalized difference vegetation index(NDVI) were used as covariates to create downscaled bioclimatic variables. Model assessment was performed by comparing model outcomes with observational data from weather stations. Coefficients of determination(R2), bias, and root-mean-square error(RMSE) were used to evaluate models and covariates. The elevation could effectively justify the changes in bioclimatic factors related to temperature and precipitation. Allthree models could downscale the mean annual temperature data with similar R2, RMSE, and bias values. The MWR had the best performance and highest accuracy in downscaling annual precipitation(R2=0.70; RMSE=123.44). In general, the two nonparametric models, i.e. MWR and NPMR, can be reliably used for the downscaling of bioclimatic variables which have wide applications in species distribution modeling.
基金Project(50675042) supported by the National Natural Science Foundation of China
文摘A model to describe the hysteresis damping characteristic of rubber material was presented.It consists of a parallel spring and damper,whose coefficients change with the vibration amplitude and frequency.In order to acquire these relations,force decomposition was carried out according to some sine vibration measurement data of nonlinear forces changing with the deformation of the rubber material.The nonlinear force is decomposed into a spring force and a damper force,which are represented by the amplitude-and frequency-dependent spring and damper coefficients,respectively.Repeating this step for different measurements gives different coefficients corresponding to different amplitudes and frequencies.Then,the application of a parameter identification method provides the requested approximation functions over amplitude and frequency.Using those formulae,as an example,the dynamic characteristic of a hollow shaft system supported by rubber rings was analyzed and the acceleration response curve in the centroid position was calculated.Comparisons with the sine vibration experiments of the real system show a maximal inaccuracy of 8.5%.Application of this model and procedure can simplify the modeling and analysis of mechanical systems including rubber materials.
基金the Dept. of Chemical Engineering Materials Environment of Sapienza University of Rome
文摘In this study the copper and lead adsorption efficiency onto banana peels powder was investigated. The agroindustrial waste recovery represents one of the Circular Economy pillars. In the view of the synthesis of an environmentally friendly adsorbent material, the powder was used without any preliminary chemical or thermal activation, but only after simple washing, drying and grinding. The bio-adsorbent was characterized by the FTIR technique and tested in batch mode on synthetic aqueous solutions containing Pb and Cu in the range 10–90 mg·L^(-1). A selection of two(Langmuir, Freundlich) and three(Sips, Redlich–Peterson, Koble–Corrigan) parameter isotherm models was chosen to fit adsorption equilibrium data by non-linear regression procedure. The best fit isotherm model was selected relying on the error function with the lowest average percentage error(APE) value, among those characterized by the highest R^2 values. As expected, the three-parameter models are found to better represent both metals bio-adsorption, with APE and R^2 values always lower and higher, respectively, than the corresponding values obtained for the two-parameter models.
基金supported by the special Fund for Public Welfare Industry (Meteorology) (Grant No. GYHY200906018)the National Basic Research Program of China (Grant Nos. 2010CB950304 and 2009CB421406)the Knowl-edge Innovation Program of the Chinese Academy of Sciences (Grant No. KZCX2-YW-QN202)
文摘A statistical downscaling approach based on multiple-linear-regression(MLR) for the prediction of summer precipitation anomaly in southeastern China was established,which was based on the outputs of seven operational dynamical models of Development of a European Multi-model Ensemble System for Seasonal to Interannual Prediction(DEMETER) and observed data.It was found that the anomaly correlation coefficients(ACCs) spatial pattern of June-July-August(JJA) precipitation over southeastern China between the seven models and the observation were increased significantly;especially in the central and the northeastern areas,the ACCs were all larger than 0.42(above 95% level) and 0.53(above 99% level).Meanwhile,the root-mean-square errors(RMSE) were reduced in each model along with the multi-model ensemble(MME) for some of the stations in the northeastern area;additionally,the value of RMSE difference between before and after downscaling at some stations were larger than 1 mm d-1.Regionally averaged JJA rainfall anomaly temporal series of the downscaling scheme can capture the main characteristics of observation,while the correlation coefficients(CCs) between the temporal variations of the observation and downscaling results varied from 0.52 to 0.69 with corresponding variations from-0.27 to 0.22 for CCs between the observation and outputs of the models.
文摘The equilibrium constant (K0), change in free energy (△G), enthalpy (△H) and entropy (△S) of ammonium adsorption by a Cuban natural zeolite were estimated at the temperatures of 25, 35, 45 and 55℃ using extensively used approaches. Equilibrium data were obtained in the concentration range 50-1,200 mg·L-1 of ammonium and used in the estimation of thermodynamic parameters. Freundlich's isotherm model was found as with the best adjustment to equilibrium data at 25, 45 and 55℃, whereas, Redlich-Peterson's model had a better performance at 35 ℃. A discontinuous and unusual behavior was observed on adsorption capacity of the zeolite, with an increase from 25 ℃ to 35 ℃ followed by a decrease from 35℃ to 55 ℃. K0 values presented differences that reached up to 105 from one methodology to other. Depending on the method considered, AS results indicated both increase or decrease in system degree of disorder and △G indicated both physisorption or chemisorption process, proving the poor correlation between the estimation proceedings of such important data. The results from Gaines and Thomas method were recognized as the most correlated to calorimetric studies, as well as to equilibrium data and observations related to system entropy.
基金Supported by the project No.LO1404(Sustainable Development of Center ENET-Energy Units for the Utilization of Non-Traditional Energy Sources)project No.LO 1203(Regional Materials Science and Technology Centre-Feasibility Program)+1 种基金the project No.LO1406(Institute of Clean Technologies for Mining and Utilization of Raw Materials for Energy Use-Sustainability Programsupported by the National Programme for Sustainability I 2013-2020
文摘The study deals with adsorption of Naphthol Green B on two unburned carbons and the parent coal,from which the UCs have been created in a fluidised-bed power station.Particular attention has been paid to the adsorption equilibrium modelling:experimental data has been analysed using 2-parameter(Langmuir,Freundlich) and3-parameter(Redlich-Peterson) isotherms — both linear and non-linear regressions have been used for the estimation of the isotherm parameters.In the case of both UCs,the Langmuir isotherm model provides the worst fit,whereas 2-parameter Freundlich and 3-parameter Redlich-Peterson models are both good,from which 3-parameter Redlich-Peterson isotherm provides slightly better results(despite the penalty used for the higher number of parameters).In the case of both UCs,the linear regression of Freundlich and Redlich-Peterson models provides good results(comparable with non-linear regressions).Unlike both UCs,the best fit of the experimental data from the adsorption on the coal has been achieved by the Langmuir isotherm model.The results based on the Freundlich or Redlich-Peterson model were(in this case) somewhat worse.
文摘At present, there are no reliable methods to evaluate uncertainty of model representation of magnetic field (MF) in the whole volume of the Earth's magnetosphere. Cosmic ray intensity distribution on the Earth surface contains information on the space distribution of magnetospheric MF through which charged particles propagate. Feasibility and limitations of cosmic ray data to be a tool for the validation of magnetospheric MF models have been analyzed. The authors' approach is based on the fact that time variations of magnetospheric cosmic ray are related to the changes in geomagnetic cutoff rigidities. The obtained cutoff rigidity changes by the trajectory tracing method in the MF model with those obtained on the base of experimental cosmic ray data have also been compared. The obtained results have shown that cosmic ray data can be successfully used for validation of models in presenting the dynamic structure of magnetospheric MF at mid latitudes.
文摘A linear mixed model is used to determine the explaining infant mortality rate data of United Nations countries. The HDI (human development index) has a significant negative linear relationship with infant mortality rate. United Nations data shows that the infant mortality rate has a descending trend over the period 1990-2010. This study aims to assess the value of the HDI as a predictor of infant mortality rate. Findings in the paper suggest that significant percentage reductions in infant mortality might be possible for countries for controlling the HDI.
基金Supported by the National Natural Science Foundation of China (61273131) 111 Project (B12018)+1 种基金 the Innovation Project of Graduate in Jiangsu Province (CXZZ12_0741) the Fundamental Research Funds for the Central Universities (JUDCF12034)
文摘Fault monitoring of bioprocess is important to ensure safety of a reactor and maintain high quality of products. It is difficult to build an accurate mechanistic model for a bioprocess, so fault monitoring based on rich historical or online database is an effective way. A group of data based on bootstrap method could be resampling stochastically, improving generalization capability of model. In this paper, online fault monitoring of generalized additive models (GAMs) combining with bootstrap is proposed for glutamate fermentation process. GAMs and bootstrap are first used to decide confidence interval based on the online and off-line normal sampled data from glutamate fermentation experiments. Then GAMs are used to online fault monitoring for time, dissolved oxygen, oxygen uptake rate, and carbon dioxide evolution rate. The method can provide accurate fault alarm online and is helpful to provide useful information for removing fault and abnormal phenomena in the fermentation.
文摘In this paper we revise the moment theory for pattern recognition designed, to extract patterns from the noisy character datas, and develop unconstrained handwritten. Amazigh character recognition method based upon orthogonal moments and neural networks classifier. We argue that, given the natural flexibility of neural network models and the extent of parallel processing that they allow, our algorithm is a step forward in character recognition. More importantly, following the approach proposed, we apply our system to two different databases, to examine the ability to recognize patterns under noise. We discover overwhelming support for different style of writing. Moreover, this basic conclusion appears to remain valid across different levels of smoothing and insensitive to the nuances of character patterns. Experiments tested the effect of set size on recognition accuracy which can reach 97.46%. The novelty of the proposed method is independence of size, slant, orientation, and translation. The performance of the proposed method is experimentally evaluated and the promising results and findings are presented. Our method is compared to K-NN (k-nearest neighbors) classifier algorithm; results show performances of our method.
基金Supported by the National Basic Research Program of China(973 Program)(No.2012CB417001)the National Natural Science Foundation of China(No.41271125)
文摘In recent years, sedimentation conditions in Dongting Lake have varied greatly because of signifi cant changes in runoff and sediment load in the Changjiang(Yangtze) River following the construction of Three Gorges Dam. The topography of the lake bottom has changed rapidly because of the intense exchange of water and sediment between the lake and the Changjiang River. However, time series information on lake-bottom topographic change is lacking. In this study, we introduced a method that combines remote sensing data and in situ water level data to extract a record of Dongting Lake bottom topography from 2003 to 2011. Multi-temporal lake land/water boundaries were extracted from MODIS images using the linear spectral mixture model method. The elevation of water/land boundary points were calculated using water level data and spatial interpolation techniques. Digital elevation models of Dongting Lake bottom topography in different periods were then constructed with the multiple heighted waterlines. The mean root-mean-square error of the linear spectral mixture model was 0.036, and the mean predicted error for elevation interpolation was-0.19 m. Compared with fi eld measurement data and sediment load data, the method has proven to be most applicable. The results show that the topography of the bottom of Dongting Lake has exhibited uneven erosion and deposition in terms of time and space over the last nine years. Moreover, lake-bottom topography has undergone a slight erosion trend within this period, with 58.2% and 41.8% of the lake-bottom area being eroded and deposited, respectively.
基金supported by the Chinese 111 Project B14019the US National Science Foundation under Grant Nos.DMS-1305474 and DMS-1612873the US National Institutes of Health Award UL1TR001412
文摘The generalized linear model is an indispensable tool for analyzing non-Gaussian response data, with both canonical and non-canonical link functions comprehensively used. When missing values are present, many existing methods in the literature heavily depend on an unverifiable assumption of the missing data mechanism, and they fail when the assumption is violated. This paper proposes a missing data mechanism that is as generally applicable as possible, which includes both ignorable and nonignorable missing data cases, as well as both scenarios of missing values in response and covariate.Under this general missing data mechanism, the authors adopt an approximate conditional likelihood method to estimate unknown parameters. The authors rigorously establish the regularity conditions under which the unknown parameters are identifiable under the approximate conditional likelihood approach. For parameters that are identifiable, the authors prove the asymptotic normality of the estimators obtained by maximizing the approximate conditional likelihood. Some simulation studies are conducted to evaluate finite sample performance of the proposed estimators as well as estimators from some existing methods. Finally, the authors present a biomarker analysis in prostate cancer study to illustrate the proposed method.