To satisfy the requirements for various electric systems and energy storage devices with both high energy density and power density as well as long lifespan, sodium-ion capacitors(SICs) consisting of battery anode and...To satisfy the requirements for various electric systems and energy storage devices with both high energy density and power density as well as long lifespan, sodium-ion capacitors(SICs) consisting of battery anode and supercapacitor cathode, have attracted much attention due to the abundant resources and low cost of sodium source. SICs bridge the gap between the batteries and the supercapacitors,which can be used as competitive candidates for large-scale energy storage. In this review, the battery-type anode materials and the capacitor-type cathode materials are classified and introduced in detail. The advantages of various electrolytes including organic electrolytes, aqueous electrolytes and ion liquid electrolytes are also discussed sequentially. In addition, from the perspective of practical value, the presentations of the SICs at the current situation and the potential application in urban rail are displayed. Finally, the challenge,future research and prospects towards the SICs are put forward.展开更多
Along with the explosive growth in the market of new energy electric vehicles,the demand for Li-ion batteries(LIBs)has correspondingly expanded.Given the limited life of LIBs,numbers of spent LIBs are bound to be prod...Along with the explosive growth in the market of new energy electric vehicles,the demand for Li-ion batteries(LIBs)has correspondingly expanded.Given the limited life of LIBs,numbers of spent LIBs are bound to be produced.Because of the severe threats and challenges of spent LIBs to the environment,resources,and global sustainable development,the recycling and reuse of spent LIBs have become urgent.Herein,we propose a novel green and efficient direct recycling method,which realizes the concurrent reuse of LiFePO_(4)(LFP)cathode and graphite anode from spent LFP batteries.By optimizing the proportion of LFP and graphite,a hybrid LFP/graphite(LFPG)cathode was designed for a new type of dualion battery(DIB)that can achieve co-participation in the storage of both anions and cations.The hybrid LFPG cathode combines the excellent stability of LFP and the high conductivity of graphite to exhibit an extraordinary electrochemical performance.The best compound,i.e.,LFP:graphite=3:1,with the highest reversible capacity(~130 mAhg^(-1) at 25 mAg^(-1)),high voltage platform of 4.95 V,and outstanding cycle performance,was achieved.The specific diffusion behavior of Li^(+) and PF_(6)^(-) in the hybrid cathode was studied using electrode kinetic tests,further clarifying the working mechanism of DIBs.This study provides a new strategy toward the large-scale recycling of positive and negative electrodes of spent LIBs and establishes a precedent for designing new hybrid cathode materials for DIBs with superior performance using spent LIBs.展开更多
Li-ion hybrid supercapacitors （Li-HECs） facilitate effective combination of the advantages of supercapacitors and Li-ion batteries （LIBs）. However, challenges remain in designing and preparing suitable anode and c...Li-ion hybrid supercapacitors （Li-HECs） facilitate effective combination of the advantages of supercapacitors and Li-ion batteries （LIBs）. However, challenges remain in designing and preparing suitable anode and cathode materials, which often require tedious and expensive procedures. Herein, we demonstrated that hollow N-doped carbon capsules （HNC） with and without a Fe304 nanoparticle core can respectively function as the anode and the cathode in very-high-performance Li-HECs. The Fe3Oa@NC anode exhibited a high reversible specific capacity exceeding 1530 mA h g^-1 at 100 mA g^-1 and excellent rate capability （45% capacity retention from 0.1 to 5 A g^-1） and cycle stability （〉97% retention after 100 cycles）. Moreover, high rate performance was achieved in a full-cell using the HNC cathode. By combining the respective structural advantages of the components, the hybrid device with Fe3Oa@NC//HN C exhibited a remark- able energy density of 185 W h kg^-1 at a power density of 39 W kg^-1. The hybrid device furnished a battery-inaccessible power density of 28 kW kg^-1 with rapid charging/discharging within 9 s at an energy density of 95 W h kg^-1.展开更多
基金financially supported by the National Natural Science Foundation of China (51672308, 51972025 and 61888102)
文摘To satisfy the requirements for various electric systems and energy storage devices with both high energy density and power density as well as long lifespan, sodium-ion capacitors(SICs) consisting of battery anode and supercapacitor cathode, have attracted much attention due to the abundant resources and low cost of sodium source. SICs bridge the gap between the batteries and the supercapacitors,which can be used as competitive candidates for large-scale energy storage. In this review, the battery-type anode materials and the capacitor-type cathode materials are classified and introduced in detail. The advantages of various electrolytes including organic electrolytes, aqueous electrolytes and ion liquid electrolytes are also discussed sequentially. In addition, from the perspective of practical value, the presentations of the SICs at the current situation and the potential application in urban rail are displayed. Finally, the challenge,future research and prospects towards the SICs are put forward.
基金supported by the National Natural Science Foundation of China(52173246 and 91963118)the 111 Project(B13013)。
文摘Along with the explosive growth in the market of new energy electric vehicles,the demand for Li-ion batteries(LIBs)has correspondingly expanded.Given the limited life of LIBs,numbers of spent LIBs are bound to be produced.Because of the severe threats and challenges of spent LIBs to the environment,resources,and global sustainable development,the recycling and reuse of spent LIBs have become urgent.Herein,we propose a novel green and efficient direct recycling method,which realizes the concurrent reuse of LiFePO_(4)(LFP)cathode and graphite anode from spent LFP batteries.By optimizing the proportion of LFP and graphite,a hybrid LFP/graphite(LFPG)cathode was designed for a new type of dualion battery(DIB)that can achieve co-participation in the storage of both anions and cations.The hybrid LFPG cathode combines the excellent stability of LFP and the high conductivity of graphite to exhibit an extraordinary electrochemical performance.The best compound,i.e.,LFP:graphite=3:1,with the highest reversible capacity(~130 mAhg^(-1) at 25 mAg^(-1)),high voltage platform of 4.95 V,and outstanding cycle performance,was achieved.The specific diffusion behavior of Li^(+) and PF_(6)^(-) in the hybrid cathode was studied using electrode kinetic tests,further clarifying the working mechanism of DIBs.This study provides a new strategy toward the large-scale recycling of positive and negative electrodes of spent LIBs and establishes a precedent for designing new hybrid cathode materials for DIBs with superior performance using spent LIBs.
基金supported by the National Natural Science Foundation of China (51601127, 21603162 and 51671145)China Post-doctoral Science Fund (2015M581304)+1 种基金Tianjin Municipal Education Commission, Tianjin Municipal Science and Technology Commission (16ZXCLGX00120)the Fundamental Research Funds of Tianjin University of Technology
文摘Li-ion hybrid supercapacitors （Li-HECs） facilitate effective combination of the advantages of supercapacitors and Li-ion batteries （LIBs）. However, challenges remain in designing and preparing suitable anode and cathode materials, which often require tedious and expensive procedures. Herein, we demonstrated that hollow N-doped carbon capsules （HNC） with and without a Fe304 nanoparticle core can respectively function as the anode and the cathode in very-high-performance Li-HECs. The Fe3Oa@NC anode exhibited a high reversible specific capacity exceeding 1530 mA h g^-1 at 100 mA g^-1 and excellent rate capability （45% capacity retention from 0.1 to 5 A g^-1） and cycle stability （〉97% retention after 100 cycles）. Moreover, high rate performance was achieved in a full-cell using the HNC cathode. By combining the respective structural advantages of the components, the hybrid device with Fe3Oa@NC//HN C exhibited a remark- able energy density of 185 W h kg^-1 at a power density of 39 W kg^-1. The hybrid device furnished a battery-inaccessible power density of 28 kW kg^-1 with rapid charging/discharging within 9 s at an energy density of 95 W h kg^-1.
