Based on orthogonal experiments,the effects of voltage,frequency,duty ratio and their interactions on the thickness and corrosion resistance of coatings prepared by plasma electrolytic oxidation(PEO)on aluminum in an ...Based on orthogonal experiments,the effects of voltage,frequency,duty ratio and their interactions on the thickness and corrosion resistance of coatings prepared by plasma electrolytic oxidation(PEO)on aluminum in an alkaline silicate-containing electrolyte were investigated.The thicknesses of these coatings were obtained by measuring their cross-section using Image J software.Their corrosion resistances were evaluated in HCl and NaCl media through spot test and electrochemical test.The results show that the experimental design of this study is the key to investigate the interactions among these electrical parameters.Additionally,not only each independent factor,but also their interactions exhibit a remarkable influence on the coatings.The combination of high voltage,low frequency and large duty ratio significantly increases the coating thickness and content of the corrosion resistance phase,and thus improves the corrosion resistance of the coating in HNO3 medium.Conversely,the coating possessing the densest microstructure and best corrosion resistance in NaCl medium is obtained when low voltage and high frequency match with a small duty ratio.展开更多
An analysis of the Ishii ocean heat content(OHC) in the tropical Indian Ocean from the surface to 700-m depth shows that the OHC changes dramatically on the interannual timescale in the Indian Ocean.The first mode of ...An analysis of the Ishii ocean heat content(OHC) in the tropical Indian Ocean from the surface to 700-m depth shows that the OHC changes dramatically on the interannual timescale in the Indian Ocean.The first mode of empirical orthogonal function(EOF1) of the OHC shows that there is a strong air-sea interaction pattern in the Indian Ocean with a positive(negative) loading in the east and a negative(positive) loading in the west.This seesaw oscillation pattern influences the summer precipitation in China with a North-South reversed distribution.Composite analysis shows that during a positive(negative) OHC episode,an anomalous cyclonic(anticyclonic) circulation over the western Pacific and South China weakens(enhances) the monsoonal northward flow in the lower troposphere;meanwhile,anomalous meridional circulation connects the descending(ascending) branch over the Southeast Indian Ocean and the ascending(descending) branch in South China as well as a descending(ascending) branch over North China.Analysis of the mechanism behind these features suggests that(1) the accumulation of OHC-induced vorticity is related to the wave activity over the mid-latitudes and that(2) the meridional teleconnection induced by the Indo-Pacific air-OHC interaction appears over East Asia and the western Pacific.Both of these patterns can cause summer precipitation anomalies in China.展开更多
The dissolution behaviors of Ta2O5,Nb2O5 and their mixture in KOH and H2O system were investigated.A L9(34) orthogonal design was used to study the effects of reaction temperature,mass ratio of KOH to Ta2O5,and reacti...The dissolution behaviors of Ta2O5,Nb2O5 and their mixture in KOH and H2O system were investigated.A L9(34) orthogonal design was used to study the effects of reaction temperature,mass ratio of KOH to Ta2O5,and reaction time on the dissolution rate of tantalum.It was found that the effect of reaction temperature on the dissolution rate of tantalum was much greater than that of the other factors.The results of factorial experiments showed that Ta2O5 was mainly transformed into insoluble potassium tantalate at low temperature(350 ℃) and transformed into soluble potassium tantalate at high temperature(450 ℃).The insoluble potassium tantalate was analyzed by XRD,which was proved to be KTaO3.Differently,almost all Nb2O5 was transformed into soluble potassium niobate at 350-450℃.As for the mixture of Ta2O5 and Nb2O5,the dissolution rate of tantalum increased and the dissolution rate of niobium decreased as an interaction existed between niobium and tantalum.And increasing the mole ratio of Nb2O5 to Ta2O5 in the mixture was beneficial to the dissolution of both Ta2O5 and Nb2O5.In addition,the mechanism of the interaction between niobium and tantalum was also investigated through phase and chemical analysis.展开更多
The Proper Orthogonal Decomposition method is applied to the instantaneous velocity field within the rotor-stator inter-row region of a high-speed high-pressure centrifugal compressor. The processed data come from exp...The Proper Orthogonal Decomposition method is applied to the instantaneous velocity field within the rotor-stator inter-row region of a high-speed high-pressure centrifugal compressor. The processed data come from experiments and numerical simulations. In comparison with a Fourier transform, the POD gives the best modal approximation for both initial fields, in terms of the energy expressed on any given number of modes to be taken into account: to reach 98% of the total energy of the velocity field, the required number of POD modes is around nine times smaller than the number of Fourier harmonics. The individual POD modes are given and show that the unsteady rotor-stator interaction is already present in the very first modes.展开更多
We suggest that cobalt-oxychalcogenide layers constructed by vertex sharing CoA_2O_2(A = S, Se, Te) tetrahedra, such as BaCoAO, are strongly correlated multi-orbitals electron systems that can provide important clues ...We suggest that cobalt-oxychalcogenide layers constructed by vertex sharing CoA_2O_2(A = S, Se, Te) tetrahedra, such as BaCoAO, are strongly correlated multi-orbitals electron systems that can provide important clues on the cause of unconventional superconductivity. Differing from cuprates and iron-based superconductors, these systems lack of the D_(4h) symmetry classification. However, their parental compounds possess antiferromagnetic(AFM) Mott insulating states through pure superexchange interactions and the low energy physics near Fermi surfaces upon doping is mainly attributed to the three t_(2g) orbitals that dominate the AFM interactions. We derive a low energy effective model for these systems and predict that a d-wave-like superconducting state with reasonable high transition temperature can emerge by suppressing the AFM ordering even if the pairing symmetry can not be classified by the rotational symmetry any more.展开更多
基金Project(1111RJDA011)supported by the Creative Research Group Fund of Gansu Province,ChinaProject(SKLAB02015006)supported by the State Key Laboratory Open Fund of Advanced Processing and Recycling of Nonferrous Metals,China。
文摘Based on orthogonal experiments,the effects of voltage,frequency,duty ratio and their interactions on the thickness and corrosion resistance of coatings prepared by plasma electrolytic oxidation(PEO)on aluminum in an alkaline silicate-containing electrolyte were investigated.The thicknesses of these coatings were obtained by measuring their cross-section using Image J software.Their corrosion resistances were evaluated in HCl and NaCl media through spot test and electrochemical test.The results show that the experimental design of this study is the key to investigate the interactions among these electrical parameters.Additionally,not only each independent factor,but also their interactions exhibit a remarkable influence on the coatings.The combination of high voltage,low frequency and large duty ratio significantly increases the coating thickness and content of the corrosion resistance phase,and thus improves the corrosion resistance of the coating in HNO3 medium.Conversely,the coating possessing the densest microstructure and best corrosion resistance in NaCl medium is obtained when low voltage and high frequency match with a small duty ratio.
基金supported by the National Basic Research Program of China(973 Program):The impact of Southern Ocean-Indian Ocean air-sea processes on East Asia and the global climate change(Grant No.2010CB950300)National Foundation of the Indian Ocean Opening Voyage Project(Grant Nos. 41149903 and 41049908)+2 种基金the Knowledge Innovation Project for Distinguished Young Scholar of the Chinese Academy of Sciences (Grant No.KZCX2-EW-QN203)the Knowledge Innovation Program of the Chinese Academy of Sciences(Grant No.KZCX2-YWQ11-02)the National Natural Science Foundation of China (Grant No.40906010)
文摘An analysis of the Ishii ocean heat content(OHC) in the tropical Indian Ocean from the surface to 700-m depth shows that the OHC changes dramatically on the interannual timescale in the Indian Ocean.The first mode of empirical orthogonal function(EOF1) of the OHC shows that there is a strong air-sea interaction pattern in the Indian Ocean with a positive(negative) loading in the east and a negative(positive) loading in the west.This seesaw oscillation pattern influences the summer precipitation in China with a North-South reversed distribution.Composite analysis shows that during a positive(negative) OHC episode,an anomalous cyclonic(anticyclonic) circulation over the western Pacific and South China weakens(enhances) the monsoonal northward flow in the lower troposphere;meanwhile,anomalous meridional circulation connects the descending(ascending) branch over the Southeast Indian Ocean and the ascending(descending) branch in South China as well as a descending(ascending) branch over North China.Analysis of the mechanism behind these features suggests that(1) the accumulation of OHC-induced vorticity is related to the wave activity over the mid-latitudes and that(2) the meridional teleconnection induced by the Indo-Pacific air-OHC interaction appears over East Asia and the western Pacific.Both of these patterns can cause summer precipitation anomalies in China.
基金Project(2009AA06Z103) supported by the National High-tech Research and Development Program of ChinaProject(51004094) supported by the National Natural Science Foundation of ChinaProject(2007CB613501) supported by the National Basic Research Program of China
文摘The dissolution behaviors of Ta2O5,Nb2O5 and their mixture in KOH and H2O system were investigated.A L9(34) orthogonal design was used to study the effects of reaction temperature,mass ratio of KOH to Ta2O5,and reaction time on the dissolution rate of tantalum.It was found that the effect of reaction temperature on the dissolution rate of tantalum was much greater than that of the other factors.The results of factorial experiments showed that Ta2O5 was mainly transformed into insoluble potassium tantalate at low temperature(350 ℃) and transformed into soluble potassium tantalate at high temperature(450 ℃).The insoluble potassium tantalate was analyzed by XRD,which was proved to be KTaO3.Differently,almost all Nb2O5 was transformed into soluble potassium niobate at 350-450℃.As for the mixture of Ta2O5 and Nb2O5,the dissolution rate of tantalum increased and the dissolution rate of niobium decreased as an interaction existed between niobium and tantalum.And increasing the mole ratio of Nb2O5 to Ta2O5 in the mixture was beneficial to the dissolution of both Ta2O5 and Nb2O5.In addition,the mechanism of the interaction between niobium and tantalum was also investigated through phase and chemical analysis.
文摘The Proper Orthogonal Decomposition method is applied to the instantaneous velocity field within the rotor-stator inter-row region of a high-speed high-pressure centrifugal compressor. The processed data come from experiments and numerical simulations. In comparison with a Fourier transform, the POD gives the best modal approximation for both initial fields, in terms of the energy expressed on any given number of modes to be taken into account: to reach 98% of the total energy of the velocity field, the required number of POD modes is around nine times smaller than the number of Fourier harmonics. The individual POD modes are given and show that the unsteady rotor-stator interaction is already present in the very first modes.
基金supported by the National Basic Research Program of China (2015CB921300)the National Natural Science Foundation of China (11334012)the Strategic Priority Research Program of Chinese Academy of Sciences (XDB07000000)
文摘We suggest that cobalt-oxychalcogenide layers constructed by vertex sharing CoA_2O_2(A = S, Se, Te) tetrahedra, such as BaCoAO, are strongly correlated multi-orbitals electron systems that can provide important clues on the cause of unconventional superconductivity. Differing from cuprates and iron-based superconductors, these systems lack of the D_(4h) symmetry classification. However, their parental compounds possess antiferromagnetic(AFM) Mott insulating states through pure superexchange interactions and the low energy physics near Fermi surfaces upon doping is mainly attributed to the three t_(2g) orbitals that dominate the AFM interactions. We derive a low energy effective model for these systems and predict that a d-wave-like superconducting state with reasonable high transition temperature can emerge by suppressing the AFM ordering even if the pairing symmetry can not be classified by the rotational symmetry any more.