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低硅铝比ZSM-48分子筛合成及其正构十二烷临氢异构催化性能研究 被引量:5
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作者 向江南 刘伟 +5 位作者 刘成连 王琰 陈树伟 毕士楠 范彬彬 李瑞丰 《燃料化学学报》 EI CAS CSCD 北大核心 2020年第1期83-90,I0006,共9页
通过静态水热合成法,溴化六甲二铵作为结构导向剂合成出系列低硅铝比的ZSM-48沸石分子筛(Si/Al<100),所合成样品中最低硅铝比为38.6(ICP-AES),这将拓宽ZSM-48高硅沸石分子筛的应用范围。制备Pt负载双功能催化剂,用于正构十二烷临氢... 通过静态水热合成法,溴化六甲二铵作为结构导向剂合成出系列低硅铝比的ZSM-48沸石分子筛(Si/Al<100),所合成样品中最低硅铝比为38.6(ICP-AES),这将拓宽ZSM-48高硅沸石分子筛的应用范围。制备Pt负载双功能催化剂,用于正构十二烷临氢异构催化反应。结果表明,硅铝比的改变可以影响催化剂的活性,投料硅铝比为70的双功能催化剂具有最优的催化性能,但硅铝比改变对异构产物的分布没有明显的影响,其异构产物以支链在中间位的异构体为主。 展开更多
关键词 ZSM-48分子筛 低硅铝比 正构十二烷 临氢异 双功能催化剂
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Phase Behavior and Structural Transitions in Sodium Dodecyl Sulfonate Microemulsions 被引量:1
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作者 杨根生 施介华 +2 位作者 李景华 王普 姚善泾 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2002年第6期670-672,共3页
The forming mechanism of microemulsion of sodium dodecyl sulfonate, alcohols,water and isooctane was studied, with particular emphasis on the effect of molecular weight andconcentration of alcohols. Phase diagram of t... The forming mechanism of microemulsion of sodium dodecyl sulfonate, alcohols,water and isooctane was studied, with particular emphasis on the effect of molecular weight andconcentration of alcohols. Phase diagram of the four components, alcohol, sodium dodecyl sulfonate,water and isooctane, was used as a means of study, through which the microemulsion regions weredetermined. Phase diagram of sodium dodecyl sulfonate/n-pentanol/isooctane/water system at κ_m = 2(κ_m = W_(n-pentanol)/W_(SDS)) is presented. The variation of conductivities of differentmicroemulsion samples with water was measured. From the conductivities we investigated a change instructure from water droplets in oil (W/O) at low water content to liquid crystal at intermediatewater content and a stricture of oil droplets in water (O/W) at high water content. 展开更多
关键词 sodium dodecyl sulfonate ALCOHOL MICROEMULSION phase behavior CONDUCTIVITY
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