This study was conducted to determine the safety of bensulfuron-methyl and mefenacet in rice ecosystem. A field experiment was carried to reveal residual dynamics and final residue of bensulfuron-methyl.mefenacet 4.2 ...This study was conducted to determine the safety of bensulfuron-methyl and mefenacet in rice ecosystem. A field experiment was carried to reveal residual dynamics and final residue of bensulfuron-methyl.mefenacet 4.2 g/kg granule in rice and paddy system in Hangzhou, Changsha and Nanning of China during 2010 to 2011. The results showed that the average recoveries of bensulfuron-methyl and mefenacet spiked in the paddy soil, paddy water, rice, husk and rice plant at the 3 concentration levels of 0.05, 0.10 and 1.00 mg/kg ranged from 70.78% to 116.06% with the relative standard deviations of 0.91%-10.24%. The limit of detection （LOD） values of bensulfuron-methyl and mefenacet were 0.02 mg/L, and the minimum de- tection quantities were 4.0×10-9 g. The degradation dynamics test was done by spraying at a high dose （270 kg/hm2, bensulfuron-methyl active ingredient was 64.8 g/hm2, mefenacet active ingredient was 1 069.2 g/hm2） by direct spreading method 5-7 d after transplanting, and the final residual test carried out at a low dose （180 kg/hm2, bensuifuron-methyl active ingredient was 43.2 g/hm2, mefenacet active in- gredient was 712.8 g/hm2） and a high dose （270 kg/hm2）. The degradation research of bensulfuron-methyl and mefenacet in paddy water, soil and rice plant suggested that the degradation curves accorded with the first-order kinetics equation, the aver- age half life of bensulfuron-methyl was 5.35, 3.05 and 3.71 d in water, soil and rice plant, respectively, and the average half life of mefenacet was 3.61, 3.29 and 3.88 d in water, soil and rice plant, respectively. The final residues of bensulfuron-methyl and mefenacet were not detected in normal harvest paddy soil, rice straw, husk and brown rice.展开更多
[Objective] The paper was to detect the residue of buprofezin in citrus and soil.[Method] Gas chromatography（GC）method was used to measure the residue of buprofezin in citrus and soil.[Result] The average recovery r...[Objective] The paper was to detect the residue of buprofezin in citrus and soil.[Method] Gas chromatography（GC）method was used to measure the residue of buprofezin in citrus and soil.[Result] The average recovery rate of buprofezin in entire citrus fruit was 96.17%-97.38%,and the variation coefficient was 6.10%-9.07%;the average recovery rate in pulp was 95.24%-105.46%,and the variation coefficient was 3.30%-6.01%;the average recovery rate in peel was 88.76%-93.64%,and the variation coefficient was 5.12%-6.27%;the average recovery rate in soil was 97.79%-104.3%,and the variation coefficient was 2.45%-9.21%.The degradation dynamics and the final residue results of buprofezin in citrus and soil showed that the degradation half-lives in citrus in Changsha（Hunan）,Hangzhou（Zhejiang）and Guiyang（Guizhou）were 7.65,7.64 and 8.40 d,and the degradation half-lives in soil in three places were 13.75,9.97 and 10.18 d,respectively.[Conclusion] When 25% buprofezin SC watered agent were sprayed in citrus fruits for 2-3 times according to the recommended dose of 166.7-250.0 mg/L,the safe period of buprofezin in citrus could be set as 14 d.展开更多
A field experiment was employed to study the degradation of triadimefon and difenoconazole residues in strawberry and soil. The results showed that the degradation of both the two kinds of pesticides was in accordance...A field experiment was employed to study the degradation of triadimefon and difenoconazole residues in strawberry and soil. The results showed that the degradation of both the two kinds of pesticides was in accordance with the first order kinetic equation. The half-lives of difenoconazole in strawberry fruit, strawberry stem leaf and soil were 4.09, 8.21 and 13.38 d, respectively; and the half-lives of triadimefon in strawberry fruit, strawberry stem and leaf and soil were 3.38, 5.31 and 15.64 d, respectively. The maximum residue limit （MRL） of difenoconazole in strawberry was recommended as 0.5 mg/kg, and 10% difenoconazole WG and 20% triadimefon EC should be applied four times with a safety interval of 7 d according to the amounts of 100 and 60 g a. i./hm2,respectively.展开更多
The decomposition of plant materials in soil, along with the factors affecting it, has been frequently studied, and much information has been accumulated. Most reports indicated that the decomposition of organic mater...The decomposition of plant materials in soil, along with the factors affecting it, has been frequently studied, and much information has been accumulated. Most reports indicated that the decomposition of organic materials proceeded more slowly in paddy soil than in upland soil because of the insufficient 02 supply, the lower soil temperature and the weaker activity of aquatic invertebrates in the former as compared with those in展开更多
This study was aimed to do the prediction of pesticide residues based on fuzzy system. Taking chlorpyrifos as an example, the Mathematic Fuzzy System was established by using the MRL values （maximum residue limits of...This study was aimed to do the prediction of pesticide residues based on fuzzy system. Taking chlorpyrifos as an example, the Mathematic Fuzzy System was established by using the MRL values （maximum residue limits of all kinds of pesticides in food） of the Matlab Fuzzy Toolbox to analyze and predict the degra- dation degree of pesticide residues of the same crop at different time periods of bagging treatment, with the aim to provide some theoretical guidances for solving practical problems in real life.展开更多
The FG 9307 cell line derived from the gill of flounder Paralichthys olivaceus was used in the present study to determine the acute cytotoxic effects of the organophosphorous pesticide, profenofos. It was found that t...The FG 9307 cell line derived from the gill of flounder Paralichthys olivaceus was used in the present study to determine the acute cytotoxic effects of the organophosphorous pesticide, profenofos. It was found that the cell growth rate was markedly reduced by profenofos at the concentrations of 2.5, 5 and 7.5 mg/L tested; and that the fine structures of the cells were also altered by profenofos, as evidenced by dilation of nuclear membranes and mitochondria cristae, and presence of enlarged lysosomes with engulfed organelles and numerous vacuoles in the cytoplasm. Probably, mitochondria, the cell energy generating sites, are the most prominent sites of profenofos cytotoxity in the cells. This seems to be the first report of the use of marine fish cell line for evaluation of the acute in vitro cytotoxicity of organophosphorus pesticide.展开更多
基金Supported Nanning Major Scientific and Technological Project of New Patented Product Industrialization(201106055D)Agrochemical Residual Test Project of Ministry of China(2010H216)Youth Science Foundation of Hunan Agricultural University(15QN30)~~
文摘This study was conducted to determine the safety of bensulfuron-methyl and mefenacet in rice ecosystem. A field experiment was carried to reveal residual dynamics and final residue of bensulfuron-methyl.mefenacet 4.2 g/kg granule in rice and paddy system in Hangzhou, Changsha and Nanning of China during 2010 to 2011. The results showed that the average recoveries of bensulfuron-methyl and mefenacet spiked in the paddy soil, paddy water, rice, husk and rice plant at the 3 concentration levels of 0.05, 0.10 and 1.00 mg/kg ranged from 70.78% to 116.06% with the relative standard deviations of 0.91%-10.24%. The limit of detection （LOD） values of bensulfuron-methyl and mefenacet were 0.02 mg/L, and the minimum de- tection quantities were 4.0×10-9 g. The degradation dynamics test was done by spraying at a high dose （270 kg/hm2, bensulfuron-methyl active ingredient was 64.8 g/hm2, mefenacet active ingredient was 1 069.2 g/hm2） by direct spreading method 5-7 d after transplanting, and the final residual test carried out at a low dose （180 kg/hm2, bensuifuron-methyl active ingredient was 43.2 g/hm2, mefenacet active in- gredient was 712.8 g/hm2） and a high dose （270 kg/hm2）. The degradation research of bensulfuron-methyl and mefenacet in paddy water, soil and rice plant suggested that the degradation curves accorded with the first-order kinetics equation, the aver- age half life of bensulfuron-methyl was 5.35, 3.05 and 3.71 d in water, soil and rice plant, respectively, and the average half life of mefenacet was 3.61, 3.29 and 3.88 d in water, soil and rice plant, respectively. The final residues of bensulfuron-methyl and mefenacet were not detected in normal harvest paddy soil, rice straw, husk and brown rice.
基金Supported by Pesticide Testing Project of Ministry of Agriculture(NYCL20080368)~~
文摘[Objective] The paper was to detect the residue of buprofezin in citrus and soil.[Method] Gas chromatography（GC）method was used to measure the residue of buprofezin in citrus and soil.[Result] The average recovery rate of buprofezin in entire citrus fruit was 96.17%-97.38%,and the variation coefficient was 6.10%-9.07%;the average recovery rate in pulp was 95.24%-105.46%,and the variation coefficient was 3.30%-6.01%;the average recovery rate in peel was 88.76%-93.64%,and the variation coefficient was 5.12%-6.27%;the average recovery rate in soil was 97.79%-104.3%,and the variation coefficient was 2.45%-9.21%.The degradation dynamics and the final residue results of buprofezin in citrus and soil showed that the degradation half-lives in citrus in Changsha（Hunan）,Hangzhou（Zhejiang）and Guiyang（Guizhou）were 7.65,7.64 and 8.40 d,and the degradation half-lives in soil in three places were 13.75,9.97 and 10.18 d,respectively.[Conclusion] When 25% buprofezin SC watered agent were sprayed in citrus fruits for 2-3 times according to the recommended dose of 166.7-250.0 mg/L,the safe period of buprofezin in citrus could be set as 14 d.
基金Supported by Tripartite Joint Fund of Science and Technology Department of Guizhou Province(LH[2016]7278)Agricultural Science and Technology Project of Science and Technology Department of Guizhou Province(NZ[2013]3029)+1 种基金Tripartite Joint Fund of Science and Technology Department of Guizhou Province(Key Project)(JLKA[2012]03)Natural Science Research Project of Department of Education of Guizhou Province(2011054)~~
文摘A field experiment was employed to study the degradation of triadimefon and difenoconazole residues in strawberry and soil. The results showed that the degradation of both the two kinds of pesticides was in accordance with the first order kinetic equation. The half-lives of difenoconazole in strawberry fruit, strawberry stem leaf and soil were 4.09, 8.21 and 13.38 d, respectively; and the half-lives of triadimefon in strawberry fruit, strawberry stem and leaf and soil were 3.38, 5.31 and 15.64 d, respectively. The maximum residue limit （MRL） of difenoconazole in strawberry was recommended as 0.5 mg/kg, and 10% difenoconazole WG and 20% triadimefon EC should be applied four times with a safety interval of 7 d according to the amounts of 100 and 60 g a. i./hm2,respectively.
文摘The decomposition of plant materials in soil, along with the factors affecting it, has been frequently studied, and much information has been accumulated. Most reports indicated that the decomposition of organic materials proceeded more slowly in paddy soil than in upland soil because of the insufficient 02 supply, the lower soil temperature and the weaker activity of aquatic invertebrates in the former as compared with those in
基金The Youth Foundation of the Department of Education of Hebei Province in 2016(QN2016243)
文摘This study was aimed to do the prediction of pesticide residues based on fuzzy system. Taking chlorpyrifos as an example, the Mathematic Fuzzy System was established by using the MRL values （maximum residue limits of all kinds of pesticides in food） of the Matlab Fuzzy Toolbox to analyze and predict the degra- dation degree of pesticide residues of the same crop at different time periods of bagging treatment, with the aim to provide some theoretical guidances for solving practical problems in real life.
文摘The FG 9307 cell line derived from the gill of flounder Paralichthys olivaceus was used in the present study to determine the acute cytotoxic effects of the organophosphorous pesticide, profenofos. It was found that the cell growth rate was markedly reduced by profenofos at the concentrations of 2.5, 5 and 7.5 mg/L tested; and that the fine structures of the cells were also altered by profenofos, as evidenced by dilation of nuclear membranes and mitochondria cristae, and presence of enlarged lysosomes with engulfed organelles and numerous vacuoles in the cytoplasm. Probably, mitochondria, the cell energy generating sites, are the most prominent sites of profenofos cytotoxity in the cells. This seems to be the first report of the use of marine fish cell line for evaluation of the acute in vitro cytotoxicity of organophosphorus pesticide.
