微孔塑料挤出发泡数值模拟

微孔塑料连续挤出发泡中的熔体压力和压力降速率是比较重要的参数,一般而言越大的压力降和压力降速率越有利于微孔连续挤出发泡成型。文章通过对毛细管口模的模拟,总结了几种提高熔体压力和压力降速率的方法,分析了熔体温度和熔体中CO_2的溶解度对熔体流动的影响。研究发现,可以通过缩小毛细管直径、增加毛细管长度、降低熔体温度、降低熔体中的CO_2溶解含量、增加质量流率来提高熔体压力;可以通过缩小口模直径,降低熔体温度、降低CO_2溶解含量、增加质量流率来增加熔体的压力降速率。

基于核磁共振T_(2)时间分布快速预测不同干密度土体的渗透系数

不同干密度土体因孔隙结构的差异导致其渗透系数不同。同一工程不同位置土体的孔隙结构差异较大,为获得不同位置土体的渗透系数需要对每个位置的土样做变水头试验,这是一个耗时的过程。因此,提出一种快速预测土体不同孔隙结构条件下的渗透系数具有重要的理论和实践意义。基于核磁共振能快速测定孔径分布的优点,建立了一个基于土体T_(2)时间分布快速预测土体渗透系数的毛细管模型。该模型能够利用某一干密度土体的渗透系数,结合土体任意干密度条件下的T_(2)时间分布曲线预测该干密度条件下的渗透系数。研究结果表明:该毛细管模型在预测其他干密度土体渗透系数时,不需要计算横向表面弛豫强度ρ_(2),进而提高计算渗透系数的效率;核磁共振的每个T_(2)时间概率分布和对应孔隙直径的概率分布相同,将T_(2)时间代入毛细管模型就能直接计算渗透系数;预测的渗透系数和实测值较为一致,说明该方法具有快捷、可靠且不受人为因素干扰的优点。

Wavefield simulation in porous media saturated with two immiscible fluids

Wavefields in porous media saturated by two immiscible fluids are simulated in this paper.Based on the sealed system theory,the medium model considers both the relative motion between the fluids and the solid skeleton and the relaxation mechanisms of porosity and saturation（capillary pressure）.So it accurately simulates the numerical attenuation property of the wavefields and is much closer to actual earth media in exploration than the equivalent liquid model and the unsaturated porous medium model on the basis of open system theory.The velocity and attenuation for different wave modes in this medium have been discussed in previous literature but studies of the complete wave-field have not been reported.In our work,wave equations with the relaxation mechanisms of capillary pressure and the porosity are derived.Furthermore,the wavefield and its characteristics are studied using the numerical finite element method.The results show that the slow P3-wave in the non-wetting phase can be observed clearly in the seismic band.The relaxation of capillary pressure and the porosity greatly affect the displacement of the non-wetting phase.More specifically,the displacement decreases with increasing relaxation coefficient.

A Peptides Migration Model in capillary Zone Electrophoresis

A peptides migration model based on the principle of mechanics is presented in capillary zone electrophoresis (CZE). It is shown that the migration that the (tr) is a function of electric (Q), relative molecular mass (Mr), conformation parameter (Rc) of peptides and electrophoretic condition parameter(A). The conformation parameter is introduced to characterize multifarious shapes owing to the complex conlormation and the various kinds of macromolecules, where Rc≥1/3. The parameters A and Rc can be obtained from experimental data. The times of migration of the nine standard peptides were measured in pH 2.5buffer on different electrophoretic conditions in CZE. The experimental results agreed well with the theoretical prediction.

Effect of absorption boundary layer on nonlinear flow in low permeability porous media

Taking low permeability cores of Daqing oilfield for example,the flow characteristics at low velocity were studied with the self-designed micro-flux measuring instrument.Considering the throat distribution and capillary model,the thickness of fluid boundary layer under different pressure gradients was calculated,and the mechanism and influencing factors of nonlinear percolation were discussed.The results show that the percolation curve of ultra-low rocks is nonlinear,and apparent permeability is not a constant which increases with pressure gradient.The absorption boundary layer decreases with the increase of pressure gradient,and changes significantly especially in low pressure gradient,which is the essence of nonlinear percolation.The absorption boundary layer is also found to be impacted by the surface property of rocks.

Slope wavenumber spectrum models of capillary and capillary-gravity waves

Capillary and capillary-gravity waves possess a random character, and the slope wavenumber spectra of them can be used to represent mean distributions of wave energy with respect to spatial scale of variability. But simple and practical models of the slope wavenumber spectra have not been put forward so far. In this article, we address the accurate definition of the slope wavenumber spectra of water surface capillary and capillary-gravity waves. By combining the existing slope wavenumber models and using the dispersion relation of water surface waves, we derive the slope wavenumber spectrum models of capillary and capillary-gravity waves. Simultaneously, by using the slope wavenumber models, the dependence of the slope wavenumber spectrum on wind speed is analyzed using data obtained in an experiment which was performed in a laboratory wind wave tank. Generally speaking, the slope wavenumber spectra are influenced profoundly by the wind speed above water surface. The slope wavenumber spectrum increases with wind speed obviously and do not cross each other for different wind speeds. But, for the same wind speed, the slope wavenumber spectra are essentially identical, even though the capillary and capillary-gravity waves are excited at different times and locations. Furthermore, the slope wavenumber spectra obtained from the models agree quite well with experimental results as regards both the values and the shape of the curve.

Differential Capillary Effect Model of Fabric and Its Application

The concept of the differential capillary effect was presented by foreign scholars several years ago, and the principle was used to design sportswear fabrics with good wet permeability and good drying functions for famous sports teams. Because the differential capillary effect model was not established in theory,it was impossible to fulfill the best functions. In this paper, by setting up the differential capillary effect of fabric, the factors to influence wet permeability and drying functions of the model is discussed in theory, and the means to optimize the design of the fabric is presented and proven practically by the experiment. The optimum fabric with good permeability and good drying functions can be designed using the model at last.

Numerical Modelling of Performance of R22 and R290 in Adiabatic Capillary Tubes Considering Metastable Two-Phase Region ——Theoretical Model Description and Validation

A homogeneous theoretical model is developed to predict the performance of R22 and R290 in adiabatic capillary tubes. The model is based on conservation equations of mass, momentum and energy. Metastable both liquid and two-phase flow regions are considered in the model. In metastable two-phase region, superheated liquid is introduced into the metastable mixture viscosity and two methods are presented to evaluate it. The model is validated by comparing the predicted pressure and temperature profile and mass flow rate with several investigators′ experimental data of R22 and one of its alternatives R290 reported in literature. All of the predicted mass flow rates are within ±800 of measured values. Comparisons are also made between the present model and other investigators′ models or sizing correlation. The model can be used for design or simulation calculation of adiabatic capillary tubes.

Wet Transfer Model of Woven Fabric

To investigate wet permeability of woven fabric, a wet transfer model of woven fabric is built up and by means of the model, the main factors which have significant influences on its wet permeability function, including liquid/material contact angle, fiber diameter, fiber cross-section configuration, the number of fibers, yarn’s twisting angle and woven density, are discussed. Finally it is derived from the argument that optimal design of wet transfer function of woven fabric can be obtained.

Analysis of the shape of heavy droplets on flat and spherical surface

In this study,a theoretical model was established for predicting the equilibrium shape of the droplet on flat and spherical surfaces.The theoretical equilibrium shape of heavy droplets could be obtained once contact angle and volume of droplets were given.It showed that the predictions of the theoretical flat model were in good agreement with the shape obtained by Surface Evolver when the contact angle is below 120 and the droplet size is on the order of capillary length.This available range will decrease and increase when the heavy droplet is on convex and concave spherical surface,respectively,in contrast to that on flat surface.The available range will decrease more for higher curvature of convex spherical surfaces.

Study on asymmetric interior corner flow in microgravity condition

The capillary flow in asymmetric interior corner consisting of straight vane and curved wall is studied with analytical solution.The concept of equivalent interior corner angle is proposed to convert the asymmetric interior corner model into symmetric interior corner model.Then the governing equations of interior corner flow are established,and based on which the interior corner flow is calculated.This method is used to analyze the capillary flow in cylindrical vane-type surface tension tank with outer vanes.The research can provide beneficial reference to the design of vane-type surface tension tank.

Simulation of Thermocapillary Convection in a TwoLayer Immiscible Fluid System Using a Boundary Element Method

A boundary element method for simulating thermocapillary convection in a two-layer immiscible fluid system with flat and free interface has been developed.The divergence theorem is applied to the non-linear convective volume integral of the boundary element formulation with the pressure penalty function.Consequently,velocity gradients are eliminated and the complete formulation is written in terms of velocity.This avoids the difficulty of convective discretizations and provides considerable reductions in storage and computational requirements while improving accuracy.In this paper,we give the influence of different parameters(Marangoni number, Reynolds number)on thermocapillary convection in cavity with two-layer immiscible fluids.As shown by the numerical results,when the physical parameters between liquid encapsulant and melt are chosen appropriately, the detrimental flow in the bottom melt layer can be greatly suppressed.The influence of the free interface on thermocapillary convection is also shown.

Optimal mode of capillary electrophoresis for the impurity analysis of β-lactam antibiotics

In order to determine the optimal mode of capillary electrophoresis for the impurity control of β-lactam antibiotics, different modes and various electrophoresis conditions for the separation of impurities were compared.The results showed that micellar electrokinetic capillary chromatography（MEKC） was the optimal separation mode for the impurity profiling of β-lactam antibiotics.In MEKC,not only the common R and S isomers,Δ-2 andΔ-3 isomers,and Z and E isomers,but also the impurities of β-lactam antibiotics could be well separated compared with the capillary zone electrophoresis.Therefore,MECK is the first choice for the separation of impurities of β-lactam antibiotics with capillary electrophoresis（CE）.The optimal separation could be achieved in MEKC by optimizing the pH and the concentrations of buffered saline,micelles and organic solvent（methanol） in running buffer.

Supplement and optimization of classical capillary number experimental curve for enhanced oil recovery by combination flooding

In the middle of the last century,American scientists put forward the concept of capillary number and obtained the relation curve between capillary number and residual oil through experiments.They revealed that the corresponding residual oil saturation decreased with increasing of capillary number;after capillary number reached up to a limit,residual oil saturation would become stable and did not decrease.These important achievements laid a theoretical base for enhanced oil recovery with chemical flooding.On the basis of the theory,scholars developed chemical flooding numerical simulation software UTCHEM.During the numerical simulation study of combination flooding,the authors found that as the capillary number is higher than the limit capillary number,the changes of the residual oil saturation along with the capillary number differ from the classical capillary number curve.Oil displacement experiments prove that there are defects in classic capillary number experimental curve and it is necessary to mend and improve.Capillary number‘calculation’curve is obtained with a method of numerical simulation calculation and a complete description of capillary number curve is provided;On this basis,combination flooding capillary number experimental curve QL is obtained through experiments,which is different from the classical capillary curve;and based on which,an expression of corresponding combination flooding relative permeability curve QL is given and the corresponding relative permeability parameters are determined with experiments.Further oil displacement experiment research recognizes the cause of the singular changes of the capillary number curve."Combination flooding capillary number experimental curve QL"and"combination flooding relative permeability curve QL"are written in combination flooding software IMCFS,providing an effective technical support for the application of combination flooding technical research.