With the aim to find an absorbing liquid suitable for the gas cleaning system in the application of gasification unit in a remote area, three types of oil were tested using a bubble column and a wetted wall column. Ai...With the aim to find an absorbing liquid suitable for the gas cleaning system in the application of gasification unit in a remote area, three types of oil were tested using a bubble column and a wetted wall column. Air streams containing toluene vapour with flowrates of 13.6 mL-min1 or 27.6 mL.min^-1 were bubbled through a 50 mL static oil in a glass tube at a temperature of 30 ℃ or 60 ℃. In experiments using the wetted wall column, air streams containing toluene were contacted with a falling thin film ofoil on the outer wall of a column with a diameter of 6.4 cm and two different contacting heights of 60 cm or 80 cm. Toluene concentrations in the air stream were adjusted in the range of 700-3000 ppm corresponding to a typical tars concentration in the producer gas. The phase equilibrium of toluene was represented as values of 1/tl of 326, 220 and 182 respectively for lubrication oil, palm oil and sunflower oil （H is Henry＇s constant with the toluene concentrations in g.L^-1 for liquid phase and g.Nm^-3 for gas phase）. From experiments using the bubble column, it was found that the overall mass transfer coefficient （Kc, a） was in the order of 10.3 cm3-min^-1 and the overall liquid phase mass transfer coefficient （KLa）was about 10.3 cm3.min^-1. Although lubrication oil had a slightly better absorption capacity than the other two tested oils, it had a lower mass trasfer coefficient than that of palm oil. All three proposed oils had a much better absorption capacity and absorption rate than that of water used conventionally as a scrubbing liquid in a small biomass gasification plant.展开更多
Noble and active gases are released from geological samples during gas extraction for noble gas isotope analyses. The active gases should be removed before inletting to mass spectrometers for the analyses. The normal ...Noble and active gases are released from geological samples during gas extraction for noble gas isotope analyses. The active gases should be removed before inletting to mass spectrometers for the analyses. The normal noble gas preparation systems can clean up most geological samples. However, authigenic minerals from sedimentary rocks in oil/gas fields contain organic matter, which cannot be cleaned up by the normal preparation systems and thus influence the noble gas analyses. We introduce a novel gas purification system （PRC patent No. ZL201320117751.2）, which includes several reversible purification pumps with different absorbing and degassing temperatures. It can well clean up water steam, carbon dioxide and organic gas- es. Mica minerals are often used for 40Ar/39Ar dating. A muscovite sample （2082MS） which could not be cleaned up by the normal preparation system with two SAES NP10 getters, becomes the test sample for a comparative experiment in this study. The experiment is assigned into 4 sections with the organic gas removal system （OGRS） ＂Closed/Opened＂ in turn. When the OGRS is closed only with two NP10 getters for purification, the 40At intensities increase in curves with inlet time because of impurities, the 40Ar/39Ar dating results yield age errors about ＋2%-±1% （20-）. When the OGRS is opened for purification, in contrast, the 40Ar intensities decrease linearly with inlet time. This indicates that the gases have been cleaned up effectively, and the 40Ar/39Ar results yield ages with errors in ±0.4%. The OGRS is very helpful to obtain high-quality analysis data.展开更多
文摘With the aim to find an absorbing liquid suitable for the gas cleaning system in the application of gasification unit in a remote area, three types of oil were tested using a bubble column and a wetted wall column. Air streams containing toluene vapour with flowrates of 13.6 mL-min1 or 27.6 mL.min^-1 were bubbled through a 50 mL static oil in a glass tube at a temperature of 30 ℃ or 60 ℃. In experiments using the wetted wall column, air streams containing toluene were contacted with a falling thin film ofoil on the outer wall of a column with a diameter of 6.4 cm and two different contacting heights of 60 cm or 80 cm. Toluene concentrations in the air stream were adjusted in the range of 700-3000 ppm corresponding to a typical tars concentration in the producer gas. The phase equilibrium of toluene was represented as values of 1/tl of 326, 220 and 182 respectively for lubrication oil, palm oil and sunflower oil （H is Henry＇s constant with the toluene concentrations in g.L^-1 for liquid phase and g.Nm^-3 for gas phase）. From experiments using the bubble column, it was found that the overall mass transfer coefficient （Kc, a） was in the order of 10.3 cm3-min^-1 and the overall liquid phase mass transfer coefficient （KLa）was about 10.3 cm3.min^-1. Although lubrication oil had a slightly better absorption capacity than the other two tested oils, it had a lower mass trasfer coefficient than that of palm oil. All three proposed oils had a much better absorption capacity and absorption rate than that of water used conventionally as a scrubbing liquid in a small biomass gasification plant.
基金the National Science and Technology Major Project of China(Grant No.2011ZX05025-003-007)the 135 program of Chinese Academy of Sciences(Grant No.GIGCAS-135Y234151001)
文摘Noble and active gases are released from geological samples during gas extraction for noble gas isotope analyses. The active gases should be removed before inletting to mass spectrometers for the analyses. The normal noble gas preparation systems can clean up most geological samples. However, authigenic minerals from sedimentary rocks in oil/gas fields contain organic matter, which cannot be cleaned up by the normal preparation systems and thus influence the noble gas analyses. We introduce a novel gas purification system （PRC patent No. ZL201320117751.2）, which includes several reversible purification pumps with different absorbing and degassing temperatures. It can well clean up water steam, carbon dioxide and organic gas- es. Mica minerals are often used for 40Ar/39Ar dating. A muscovite sample （2082MS） which could not be cleaned up by the normal preparation system with two SAES NP10 getters, becomes the test sample for a comparative experiment in this study. The experiment is assigned into 4 sections with the organic gas removal system （OGRS） ＂Closed/Opened＂ in turn. When the OGRS is closed only with two NP10 getters for purification, the 40At intensities increase in curves with inlet time because of impurities, the 40Ar/39Ar dating results yield age errors about ＋2%-±1% （20-）. When the OGRS is opened for purification, in contrast, the 40Ar intensities decrease linearly with inlet time. This indicates that the gases have been cleaned up effectively, and the 40Ar/39Ar results yield ages with errors in ±0.4%. The OGRS is very helpful to obtain high-quality analysis data.
