A new gas clean-up process called 'integrated sintered metal screen moving granular bed' (ISMSMGB) for the integrated gasification combined cycle (IGCC) and pressured fluidized bed combustion (PFBC) was develo...A new gas clean-up process called 'integrated sintered metal screen moving granular bed' (ISMSMGB) for the integrated gasification combined cycle (IGCC) and pressured fluidized bed combustion (PFBC) was developed on the basis of a sintered metal candle filter and a cross-flow moving granular bed filter. This is a combination of the surface and deep bed filtering processes. A set of facilities was established and a series of cold model tests were carried out. The dust removal efficiency and the pressure drop of the filter were measured and analyzed. The results show that this process features the advantages of the moving bed for high capacity as well as high inlet dust load and the surface filter for high efficiency. Meanwhile, the granules moving downward cleans the cake on the screen surface, so that the system is operated at steady state.展开更多
New approaches for facility distribution in chemical plants are proposed including an improved non-overlapping constraint based on projection relationships of facilities and a novel toxic gas dispersion constraint. In...New approaches for facility distribution in chemical plants are proposed including an improved non-overlapping constraint based on projection relationships of facilities and a novel toxic gas dispersion constraint. In consideration of the large number of variables in the plant layout model, our new method can significantly reduce the number of variables with their own projection relationships. Also, as toxic gas dispersion is a usual incident in a chemical plant, a simple approach to describe the gas leakage is proposed, which can clearly represent the constraints of potential emission source and sitting facilities. For solving the plant layout model, an improved genetic algorithm (GA) based on infeasible solution fix technique is proposed, which improves the globe search ability of GA. The case study and experiment show that a better layout plan can be obtained with our method, and the safety factors such as gas dispersion and minimum distances can be well handled in the solution.展开更多
Chemical-looping gasification （CLG） is a novel process for syngas generation from solid fuels, sharing the same basic principles as chemical-looping combustion （CLC）. It also uses oxygen carriers （mainly metal ox...Chemical-looping gasification （CLG） is a novel process for syngas generation from solid fuels, sharing the same basic principles as chemical-looping combustion （CLC）. It also uses oxygen carriers （mainly metal oxide and calcium sulfate） to transfer heat and oxygen to the fuel. In this paper, the primary investigation into the CLG process with CaSO4 as oxygen carrier was carried out by thermodynamic analysis and experiments in the tube reactor. Sulfur-contained gas emission was mainly H2S rather than SO2 in the CLG process, showing some different features from the CLC. The mass and heat balance of CLG processes were calculated thermodynamically to determinate the auto-thermal operating conditions with different CaSO4/C and steam/C molar ratios. It was found that the CaSO4/C molar ratio should be higher than 0.2 to reach auto-thermal balance. The effect of temperature on the reactions between oxygen carrier and coal was investigated based on Gibbs free energy minimum method and ex- perimental results. It indicated that high temperature favored the CLG process in the fuel reactor and part of syngas was consumed to compensate for auto-thermal system.展开更多
In this work, a mathematical model is established to describe the axial variation of the characteristic flow parameters (particle velocity, solid holdup and pressure gradient) in a downer. An empirical correlation is ...In this work, a mathematical model is established to describe the axial variation of the characteristic flow parameters (particle velocity, solid holdup and pressure gradient) in a downer. An empirical correlation is developed to estimate the particle velocity at the constant velocity section. Experimental investigations are made to validate the downer model. The model simulations have a good agreement with experimental data. Moreover, a formula is derived to predict the first acceleration section length and the whole acceleration section length.展开更多
基金Chinese Special Funds for Major State Basic Research Projects 973 (No. G1999022104).
文摘A new gas clean-up process called 'integrated sintered metal screen moving granular bed' (ISMSMGB) for the integrated gasification combined cycle (IGCC) and pressured fluidized bed combustion (PFBC) was developed on the basis of a sintered metal candle filter and a cross-flow moving granular bed filter. This is a combination of the surface and deep bed filtering processes. A set of facilities was established and a series of cold model tests were carried out. The dust removal efficiency and the pressure drop of the filter were measured and analyzed. The results show that this process features the advantages of the moving bed for high capacity as well as high inlet dust load and the surface filter for high efficiency. Meanwhile, the granules moving downward cleans the cake on the screen surface, so that the system is operated at steady state.
基金Supported by the National Natural Science Foundation of China （61074153, 61104131）, and the Fundamental Research Funds for Central Universities of China （ZY1111, JD1104）.
文摘New approaches for facility distribution in chemical plants are proposed including an improved non-overlapping constraint based on projection relationships of facilities and a novel toxic gas dispersion constraint. In consideration of the large number of variables in the plant layout model, our new method can significantly reduce the number of variables with their own projection relationships. Also, as toxic gas dispersion is a usual incident in a chemical plant, a simple approach to describe the gas leakage is proposed, which can clearly represent the constraints of potential emission source and sitting facilities. For solving the plant layout model, an improved genetic algorithm (GA) based on infeasible solution fix technique is proposed, which improves the globe search ability of GA. The case study and experiment show that a better layout plan can be obtained with our method, and the safety factors such as gas dispersion and minimum distances can be well handled in the solution.
基金Supported by the National~ Natural Science Foundation of China （20876079）, the Natural Science Funds for Distinguished Young Scholar in Shandong Province （JQ200904）, and Shandong Province Key Technologies Research and Development Program of China （2008GG 10006010, 2009GG 10007001）.
文摘Chemical-looping gasification （CLG） is a novel process for syngas generation from solid fuels, sharing the same basic principles as chemical-looping combustion （CLC）. It also uses oxygen carriers （mainly metal oxide and calcium sulfate） to transfer heat and oxygen to the fuel. In this paper, the primary investigation into the CLG process with CaSO4 as oxygen carrier was carried out by thermodynamic analysis and experiments in the tube reactor. Sulfur-contained gas emission was mainly H2S rather than SO2 in the CLG process, showing some different features from the CLC. The mass and heat balance of CLG processes were calculated thermodynamically to determinate the auto-thermal operating conditions with different CaSO4/C and steam/C molar ratios. It was found that the CaSO4/C molar ratio should be higher than 0.2 to reach auto-thermal balance. The effect of temperature on the reactions between oxygen carrier and coal was investigated based on Gibbs free energy minimum method and ex- perimental results. It indicated that high temperature favored the CLG process in the fuel reactor and part of syngas was consumed to compensate for auto-thermal system.
基金the National Program of Basic Research (No. G1999022103) the National Natural Science Foundation of China (No. 29936090).
文摘In this work, a mathematical model is established to describe the axial variation of the characteristic flow parameters (particle velocity, solid holdup and pressure gradient) in a downer. An empirical correlation is developed to estimate the particle velocity at the constant velocity section. Experimental investigations are made to validate the downer model. The model simulations have a good agreement with experimental data. Moreover, a formula is derived to predict the first acceleration section length and the whole acceleration section length.
