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被动采样法测定室内空气环境中的二氧化氮 被引量:5
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作者 郑丹 安从俊 +2 位作者 杨波 丁宗洲 高翠琴 《分析试验室》 CAS CSCD 北大核心 2002年第6期24-28,共5页
用基于气体分子扩散理论研制的被动采样器 (Passivesampler) ,结合Saltzman法 ,离子色谱法 (IC)分析、测定室内空气环境中的NO2 ,利用风洞实验装置进行模拟曝露实验 ,着重研究捕集液的种类、浓度和风洞内NO2 初始浓度、湿度对捕集NO2 ... 用基于气体分子扩散理论研制的被动采样器 (Passivesampler) ,结合Saltzman法 ,离子色谱法 (IC)分析、测定室内空气环境中的NO2 ,利用风洞实验装置进行模拟曝露实验 ,着重研究捕集液的种类、浓度和风洞内NO2 初始浓度、湿度对捕集NO2 能力的影响以及采样器的材料、结构与采样性能的关系。结果表明 ,本文研制的采样器在空气中曝露数个小时后 ,测定空气中NO2 浓度可达n×1 0 μg/L ,与用NOx 分析仪直接测定结果比较误差在 2 0 %以内。本采样器体积小、质量小、结构简单 ,不仅适用于生活环境中NO2 的测定 ,也适用于NO2 展开更多
关键词 测定 室内空气环境 气体分子扩散理论 被动采样器 二氧化氮 空气污染物 环境监测
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采动含瓦斯煤岩体固-气耦合数学模型及耦合效应分析 被引量:1
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作者 郭平 《煤矿安全》 CAS 北大核心 2018年第8期198-202,共5页
以弹塑性力学理论、渗流力学理论、气体扩散理论、固-气耦合理论等为研究基础,构建了采动含瓦斯煤岩体固-气耦合数学模型;以渝阳煤矿为研究背景,利用COMSOL Multiphysics数值分析软件开展了采动影响条件下固-气耦合效应数值模拟试验。... 以弹塑性力学理论、渗流力学理论、气体扩散理论、固-气耦合理论等为研究基础,构建了采动含瓦斯煤岩体固-气耦合数学模型;以渝阳煤矿为研究背景,利用COMSOL Multiphysics数值分析软件开展了采动影响条件下固-气耦合效应数值模拟试验。试验结果表明,该耦合模型能全面地反应了采动含瓦斯煤岩体变形场中的骨架变形、应力变化和流动场中的瓦斯运移过程的耦合作用机制。 展开更多
关键词 固-气耦合 气体扩散理论 含瓦斯煤岩体 瓦斯运移 数值分析
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Mechanism model for shale gas transport considering diffusion, adsorption/desorption and Darcy flow 被引量:10
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作者 WEI Ming-qiang DUAN Yong-gang +3 位作者 FANG Quan-tang WANG Rong YU Bo-ming YU Chun-sheng 《Journal of Central South University》 SCIE EI CAS 2013年第7期1928-1937,共10页
To improve the understanding of the transport mechanism in shale gas reservoirs and build a theoretical basic for further researches on productivity evaluation and efficient exploitation, various gas transport mechani... To improve the understanding of the transport mechanism in shale gas reservoirs and build a theoretical basic for further researches on productivity evaluation and efficient exploitation, various gas transport mechanisms within a shale gas reservoir exploited by a horizontal well were thoroughly investigated, which took diffusion, adsorption/desorption and Darcy flow into account. The characteristics of diffusion in nano-scale pores in matrix and desorption on the matrix surface were both considered in the improved differential equations for seepage flow. By integrating the Langmuir isotherm desorption items into the new total dimensionless compression coefficient in matrix, the transport function and seepage flow could be formalized, simplified and consistent with the conventional form of diffusion equation. Furthermore, by utilizing the Laplace change and Sethfest inversion changes, the calculated results were obtained and further discussions indicated that transfer mechanisms were influenced by diffusion, adsorption/desorption. The research shows that when the matrix permeability is closed to magnitude of 10^-9D, the matrix flow only occurs near the surfacial matrix; as to the actual production, the central matrix blocks are barely involved in the production; the closer to the surface of matrix, the lower the pressure is and the more obvious the diffusion effect is; the behavior of adsorption/desorption can increase the matrix flow rate significantly and slow down the pressure of horizontal well obviously. 展开更多
关键词 shale gas DIFFUSION ADSORPTION/DESORPTION transport mechanism horizontal well
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