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巧设辅助态突破气体计算难点
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作者 杨新国 《化学教学》 CAS 北大核心 1996年第7期44-44,共1页
巧设辅助态突破气体计算难点四川省内江二中(641000)杨新国多年的教学经验表明,涉及气体体积、压强变化的题型,因学生不能正确运用阿佛加德罗定律分析气体各变化的参数之间的关系,致使他们求解该类题时主要仍停留在“依样画... 巧设辅助态突破气体计算难点四川省内江二中(641000)杨新国多年的教学经验表明,涉及气体体积、压强变化的题型,因学生不能正确运用阿佛加德罗定律分析气体各变化的参数之间的关系,致使他们求解该类题时主要仍停留在“依样画葫芦”上,不能自如应付.主要原因:... 展开更多
关键词 气体计 气体体积 压强 波义耳定律 四川省 变化的参数 微量的水 正确运用 教学经验 辅助线
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利用FinniganMAT-252气体同位素质谱计分析碳酸盐氧同位素的结果校正 被引量:4
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作者 陈永权 蒋少涌 +2 位作者 凌洪飞 潘家永 赖鸣远 《质谱学报》 EI CAS CSCD 2005年第2期115-118,共4页
利用FinniganMAT-252气体同位素质谱计在进行C、O同位素的分析测试过程中,如果待测样品反应过程中的同位素分馏(α2)与工作气体标定反应过程中同位素分馏(α1)不相等,则气体同位素质谱计系统输出结果与样品实际同位素值之间存在偏差。... 利用FinniganMAT-252气体同位素质谱计在进行C、O同位素的分析测试过程中,如果待测样品反应过程中的同位素分馏(α2)与工作气体标定反应过程中同位素分馏(α1)不相等,则气体同位素质谱计系统输出结果与样品实际同位素值之间存在偏差。本文提出了一种校正方法校正这种偏差,公式为:真实值=系统输出值+103ln(α1/α2)。对标准物质在不同条件下进行分析测试,再利用此方法进行校正,得到的校正值与标准物质的真实值之间的误差在±0.2‰之内。 展开更多
关键词 MAT-252气体同位素质谱 氧同位素 结果校正
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高分辨气体质谱计灵敏度不稳的故障分析
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作者 齐连柱 郭文胜 +2 位作者 李洁 宋晓晶 李庆松 《核电子学与探测技术》 CAS CSCD 北大核心 2010年第11期1480-1482,1487,共4页
MAT高分辨气体同位素质谱计出现发射电流灯丝频繁烧断和灵敏度不稳定的故障,根据故障现象对相关单元电路的参数进行了检测,分析出仪器故障是由于电源高压不稳定和离子源污染引起的,通过对高压电路的清洁和离子源的清洗,最终排除了故障。
关键词 高分辨气体质谱 灵敏度 发射电流 故障分析
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便携式有害气体检测计
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作者 季梅兰 《低温与特气》 CAS 1988年第4期74-74,共1页
保加利亚卫生与职业病研究所研制出一种命名为《ГИГИTECT》的仪表,用来显示并测定空气中有害气体或蒸汽的浓度。仪表共有52个型号,分别用于检测空气中可能含有的各种有害物质,例如氯、氨、氯化氢、汽油、汞蒸汽等。
关键词 便携式 有害气体检测 保加利亚卫生与职业病研究所 功能
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MAT-251质谱计在^(13)CO_(2)呼气检查法中的应用
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作者 文启彬 曹文炳 《质谱学报》 EI CAS CSCD 1996年第2期57-62,共6页
本文简要介绍了MAT-251气体质谱计的结构特点、测试方法及其主要性能指标,并从13CO2呼气检查法的试验方法以及对质谱仪器的性能指标要求两个方面阐述了MAT-251气体质谱计在13CO2呼气检查法中的应用。
关键词 二氧化碳 呼气检查法 丰度灵敏度 气体质谱
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质量流量计的现状及发展
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作者 刘刚 李志伟 《经济技术协作信息》 2002年第9期34-34,共1页
关键词 质量流量 仪表工业 热式气体质量流 液体充量
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基于MM1200B质谱系统的MDD模式^(40)Ar/^(39)Ar实验技术及其在阿尔金山中生代冷却中研究中的应用 被引量:6
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作者 陈文 郭彦如 +3 位作者 崔彬 刘新宇 张彦 张思红 《质谱学报》 EI CAS CSCD 2001年第3期8-14,共7页
基于MM1 2 0 0B惰性气体质谱系统 ,建立多重扩散域 (MDD)模式40 Ar 39Ar热年代学实验方法 ,应用该方法的实验结果结合其它年代学数据 ,讨论了阿尔金山中生代的冷却历史。
关键词 惰性气体质谱 多重扩散域模式 氩40 氩39 ^40Ar/^39Ar热年代学 冷却历史 阿尔金山 中生代 同位素年代学
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苯-正庚烷系统等压积分汽化焓的测定与关联 被引量:1
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作者 艾俊华 林瑞森 +1 位作者 俞庆森 宗汉兴 《天然气化工—C1化学与化工》 CAS CSCD 北大核心 1996年第2期54-56,共3页
用气体流动量热计测定并关联了苯-正庚烷二元体系的等压积分汽化焓;根据相关的热力学数据计算了该二元系的等压(101.32kpa)积分汽化焓,测定值、关联值和计算值有较好的一致性.
关键词 气体流动量热 汽化焓 正庚烷
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Effects of the profile of a supercavitating vehicle's front-end on supercavity generation 被引量:2
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作者 张博 张宇文 袁绪龙 《Journal of Marine Science and Application》 2009年第4期323-327,共5页
The authors designed three different front profiles for supercavitating vehicles based on cavity theory and the Granville streamlined equation are designed. Experiments were done using these front profiles in the Nort... The authors designed three different front profiles for supercavitating vehicles based on cavity theory and the Granville streamlined equation are designed. Experiments were done using these front profiles in the Northwestern Polytechnical University high-speed water tunnel. The experiments indicated that the critical volume of gas required for supercavitation is affected by the axial distribution of the front-end's slope. The experimental data showed critical gas flow rates required for the three designs were less than rood-l, with the greatest decrease 24%. The experimental results also showed the supercavitation generation speeds of the models were faster than mod-1 by up to 32.4%. This verifies that the front profile of a supercaviting vehicle effects supercavity generation speed and critical gas flow rates. The smaller the changes in axial distribution of pressure, the higher the supercavity generation speed. The smaller the changes in curvature distribution of axial, the smaller the critical gas flow rates. 展开更多
关键词 CAVITATION supercavitating vehicle volumetric gas flow rate front profile supercavitation generation speed
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Air interaction around outdoor air-cooled condensers 被引量:1
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作者 王树刚 张腾飞 张剑 《Journal of Southeast University(English Edition)》 EI CAS 2010年第2期222-226,共5页
In order to increase cooling or heating efficiency,a porous computational fluid dynamics(CFD)model is employed to predict the thermo-fluid status and optimize the placement of outdoor units.A full scale model is est... In order to increase cooling or heating efficiency,a porous computational fluid dynamics(CFD)model is employed to predict the thermo-fluid status and optimize the placement of outdoor units.A full scale model is established to validate the accuracy of CFD simulation in terms of velocity and temperature distributions.The comparison between the measurement and the simulation shows a good agreement.By evaluating the condensers' sucked air temperature with CFD for three units installed in a row,it is found that the minimum separation distance among neighboring units is 0.2 m;a vertical wall should be apart from the unit line by at least 0.8 m;and large different operating pressures among units do not impact the flow rate and the heat transfer of the other units meaningfully. 展开更多
关键词 air-cooled condensers flow interaction heat transfer optimization computational fluid dynamics(CFD) MEASUREMENT
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Calculation of Transport Properties of CF4+Noble Gas Mixtures 被引量:2
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作者 Soodabeh Nikmanesh Jalil Moghadasi Mohammad Mehdi Papari 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第5期814-821,共8页
The present work is concerned with determining the viscosity,diffusion,thermal diffusion factor and thermal conductivity of five equimolar binary gas mixtures including:CF4-He,CF4-Ne,CF4-Ar,CF4-Kr,CF4-Xe from the prin... The present work is concerned with determining the viscosity,diffusion,thermal diffusion factor and thermal conductivity of five equimolar binary gas mixtures including:CF4-He,CF4-Ne,CF4-Ar,CF4-Kr,CF4-Xe from the principle of corresponding states of viscosity by the inversion technique.The Lennard-Jones (12-6) model potential is used as the initial model potential.The calculated interaction potential energies obtained from the inversion procedure is employed to reproduce the viscosities,diffusions,thermal diffusion factors,and thermal conductivities.The accuracies of the calculated viscosity and diffusion coefficients were 1% and 4%,respectively. 展开更多
关键词 corresponding states principle DIFFUSION inversion method kinetic theory of gases thermal conductivity transport properties VISCOSITY
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Hepatic portal venous gas: Physiopathology, etiology, prognosis and treatment 被引量:32
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作者 Bassam Abboud Jad El Hachem +1 位作者 Thierry Yazbeck Corinne Doumit 《World Journal of Gastroenterology》 SCIE CAS CSCD 2009年第29期3585-3590,共6页
Hepatic portal venous gas (HPVG), an ominous radiologic sign, is associated in some cases with a severe underlying abdominal disease requiring urgent operative intervention. HPVG has been reported with increasing freq... Hepatic portal venous gas (HPVG), an ominous radiologic sign, is associated in some cases with a severe underlying abdominal disease requiring urgent operative intervention. HPVG has been reported with increasing frequency in medical literature and usually accompanies severe or lethal conditions. The diagnosis of HPVG is usually made by plain abdominal radiography, sonography, color Doppler flow imaging or computed tomography (CT) scan. Currently, the increased use of CT scan and ultrasound in the inpatient setting allows early and highly sensitive detection of such severe illnesses and also the recognition of an increasing number of benign and non-life threatening causes of HPVG. HPVG is not by itself a surgical indication and the treatment depends mainly on the underlying disease. The prognosis is related to the pathology itself and is not influenced by the presence of HPVG. Based on a review of the literature, we discuss in this paper the pathophysiology, risk factors, radiographic findings, management, and prognosis of pathologies associated with HPVG. 展开更多
关键词 Hepatic portal venous gas Bowel ischemia/necrosis DIVERTICULITIS Gastric pathologies Ulcerativecolitis Abdominal computed tomography scan Crohn'sdisease Liver transplantation Chemotherapy
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HTPB推进剂“脱湿”性能表征及影响因素试验研究 被引量:6
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作者 张镇国 张宏亮 +2 位作者 侯晓 阎涛 郜婕 《固体火箭技术》 EI CAS CSCD 北大核心 2020年第3期265-270,共6页
为研究HTPB推进剂的"脱湿"性能,基于气体膨胀计原理研制了复合固体推进剂"脱湿"性能测试装置,并采用该装置开展了配方及应变率对推进剂"脱湿"性能影响的试验研究。采用起始"脱湿"点、特征"... 为研究HTPB推进剂的"脱湿"性能,基于气体膨胀计原理研制了复合固体推进剂"脱湿"性能测试装置,并采用该装置开展了配方及应变率对推进剂"脱湿"性能影响的试验研究。采用起始"脱湿"点、特征"脱湿"点和特征"脱湿"速率来表征推进剂的"脱湿"性能,试验结果表明,推进剂的"脱湿"性能具有明显的率相关性,应变率越高,推进剂的起始"脱湿"点和特征"脱湿"点越小,特征"脱湿"速率越大,但是推进剂的内部"脱湿"速率存在一个上限;HTPB推进剂中AP含量对推进剂"脱湿"性能的影响占主导地位,AP含量越高,则推进剂的起始"脱湿"点和特征"脱湿"点越小,特征"脱湿"速率越大。所建立的试验方法和"脱湿"性能表征方法对药柱结构完整性、药柱力学性能预示及可靠性评估均具有重要实用意义。 展开更多
关键词 HTPB推进剂 “脱湿”点 “脱湿”性能 气体膨胀 特征“脱湿”速率
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Computational fluid dynamics simulation on the longwall gob breathing 被引量:5
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作者 Samuel A.Lolon Jürgen F.Brune +3 位作者 Gregory E.Bogin Jr. John W.Grubb Saqib A.Saki Aditya Juganda 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2017年第2期185-189,共5页
In longwall mines, atmospheric pressure fluctuations can disturb the pressure balance between the gob and the ventilated working area, resulting in a phenomenon known as ‘‘gob breathing". Gob breathing triggers... In longwall mines, atmospheric pressure fluctuations can disturb the pressure balance between the gob and the ventilated working area, resulting in a phenomenon known as ‘‘gob breathing". Gob breathing triggers gas flows across the gob and the working areas and may result in a condition where an oxygen deficient mixture or a methane accumulation in the gob flows into the face area. Computational Fluid Dynamics(CFDs) modeling was carried out to analyze this phenomenon and its impact on the development of an explosive mixture in a bleeder-ventilated panel scheme. Simulation results indicate that the outgassing and ingassing across the gob and the formation of Explosive Gas Zones(EGZs) are directly affected by atmospheric pressure changes. In the location where methane zones interface with mine air, EGZ fringes may form along the face and in the bleeder entries. These findings help assess the methane ignition and explosion risks associated with fluctuating atmospheric pressures. 展开更多
关键词 CFDs Gob breathing barometric pressure Explosive gas zone Longwall mine Methane explosion
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Gas Geothermometry in the Hveragerdi High-Temperature Geothermal Field, SW Iceland 被引量:1
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作者 孙占学 HALLDORARMANNSON 《Chinese Journal Of Geochemistry》 EI CAS 2000年第4期341-348,共8页
Five gas geothermometers based on the concentrations of CO\-2, H\-2S, H\-2, CH\-4, N\-2 and Ar in fumaroles and wet\|steam wells are applied to estimating subsurface temperatures in the Hveragerdi high\|temperature ge... Five gas geothermometers based on the concentrations of CO\-2, H\-2S, H\-2, CH\-4, N\-2 and Ar in fumaroles and wet\|steam wells are applied to estimating subsurface temperatures in the Hveragerdi high\|temperature geothermal field, SW Iceland. The results for fumaroles indicate that the calculated subsurface temperatures decrease from the northern part to the southern part of the field. The CO\-2\|geothermometer gives the highest temperature values, with an average of 256℃ for the northern part, and 247℃ for the southern part. The H\-2S\|geothermometer reveals an aquifer temperature of 211℃ for the northern part, and 203℃ for the southern part. The H\-2\|geothermometer gives an average subsurface temperature of 229℃ for the northern part, and 184℃ for the southern part, which agrees excellently with the measured temperatures in wet\|steam wells. The measured borehole temperatures in the field range from 215℃ to 230℃ for the northern part, and from 167℃ to 198℃ for the southern part. The CO\-2/H\-2\|geothermometer gives the lowest subsurface temperature values, with an average of 203℃ for the northern part, and 143℃ for the southern part. The CO\-2/N\-2\|geothermometer gives 249℃ for the northern part and 235℃ for the southern part. For the data from wells, the CO\-2\|, H\-2S\|, and H\-2\|geothermometers, give average subsurface temperatures of 247℃ for the northern part and 246℃ for the southern part, 213℃ for the northern part and 220℃ for the southern part, and 217℃ for the northern part and 216℃ for the southern part, respectively. The CO\-2/H\-2\|geothermometer indicates an average subsurface temperature of about 200℃ for both the northern part and the southern part. The CO\-2/N\-2\|geothermometer gives an average subsurface temperature of 180℃ for the northern part and 259℃ for the southern part. The discrepancy between the estimated subsurface temperatures obtained by the various gas geothermometers has been explained in this paper. By integrating the solute geothermometric results, mixing model studies and gas geothermometric results, the maximum subsurface temperatures of the Hveragerdi high\|temperature geothermal system may be considered to be about 240-260℃. 展开更多
关键词 气体地温 地球化学 地热 冰岛
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Physical modelling and scale effects of air-water flows on stepped spillways 被引量:5
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作者 CHANSON Hubert GONZALEZ Carlos A. 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2005年第3期243-250,共8页
During the last three decades, the introduction of new construction materials (e.g. RCC (Roller Compacted Concrete), strengthened gabions) has increased the interest for stepped channels and spillways. However stepped... During the last three decades, the introduction of new construction materials (e.g. RCC (Roller Compacted Concrete), strengthened gabions) has increased the interest for stepped channels and spillways. However stepped chute hydraulics is not simple, because of different flow regimes and importantly because of very-strong interactions between entrained air and turbu- lence. In this study, new air-water flow measurements were conducted in two large-size stepped chute facilities with two step heights in each facility to study experimental distortion caused by scale effects and the soundness of result extrapolation to pro- totypes. Experimental data included distributions of air concentration, air-water flow velocity, bubble frequency, bubble chord length and air-water flow turbulence intensity. For a Froude similitude, the results implied that scale effects were observed in both facilities, although the geometric scaling ratio was only Lr=2 in each case. The selection of the criterion for scale effects is a critical issue. For example, major differences (i.e. scale effects) were observed in terms of bubble chord sizes and turbulence levels al- though little scale effects were seen in terms of void fraction and velocity distributions. Overall the findings emphasize that physical modelling of stepped chutes based upon a Froude similitude is more sensitive to scale effects than classical smooth-invert chute studies, and this is consistent with basic dimensional analysis developed herein. 展开更多
关键词 Physical modelling Scale effects Stepped spillways Air entrainment Air-water flow measurements
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Experimental Studies of the Effect of Wall Roughness on Particle Behavior in Gas-Particle Flows 被引量:1
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作者 周力行 张夏 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2004年第3期330-334,共5页
The effect of wall roughness on particle behavior in two-phase flows in a horizontal backward-facing step is studied using a phase-Doppler particle anemometer. The results show that the wall roughness widens the parti... The effect of wall roughness on particle behavior in two-phase flows in a horizontal backward-facing step is studied using a phase-Doppler particle anemometer. The results show that the wall roughness widens the particle velocity probability density distribution, enhances the redistribution of particle velocity into different directions, reduces the particle longitudinal mean velocity and increases the longitudinal and transverse fluctuation velocities and Reynolds shear stress. The effect of roughness on particle motion in the recirculation zone is weaker than that in the fully developed flow region. The effect of roughness for small particles is restricted only in the near-wall region, while that for large particles diffuses to the whole flow field. 展开更多
关键词 phase-Doppler particle anemometer measurements particle behavior wall roughness
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Horizontal gas mixing in rectangular fluidized bed:A novel method for gas dispersion coefficients in various conditions and distributor designs 被引量:2
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作者 Asheesh Nautiyal Chien-Song Chyang +1 位作者 Pin-Wei Li Hsin-Yung Hou 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2017年第7期848-861,共14页
In a rectangular fluidized bed combustor, the tracer gas is injected continuously into the bed from a point source at the center of the distributor plate. In this study, a general governing equation is formulated for ... In a rectangular fluidized bed combustor, the tracer gas is injected continuously into the bed from a point source at the center of the distributor plate. In this study, a general governing equation is formulated for tracer gas dispersion in the bed. An analytical solution is derived to estimate the dispersion coefficients, Dxand Dy, in a horizontal plane. The concentration profiles at different sampling heights with various gas velocities are plotted.Subsequently, to estimate the dispersion coefficients, surface fitting of the obtained analytical solution to the experimental data is performed. The dispersion coefficients obtained from this model are compared with those of a conventional model. Additionally, the effect of walls, bed height and gas injection rate on the dispersion coefficients in a horizontal plane is investigated, and the effect of distributor design on the dispersion coefficients in a horizontal plane is investigated with different tracer positions. It is found that Dxand Dyare nearly equivalent at a lower tracer gas ratio of the injected gas to the total gas flow rate. It is also demonstrated that the effect of bed height on Dxis minor. This model is also able to estimate the dispersion coefficients in the case of a multihorizontal nozzle distributor. 展开更多
关键词 Gas dispersion coefficient Horizontal mixing Wall effect Surface modeling
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Numerical simulation of single bubble rising in shear-thinning fluids by level set method 被引量:4
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作者 李少白 烟征 +2 位作者 李润东 王雷 栾敬德 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第4期1000-1006,共7页
The behavior of single bubble rising in quiescent shear-thinning tlmds was lnvestlgateO numerically by level set metnoa. number of bubbles in a large range of Reynolds number and Eotvos number were investigated includ... The behavior of single bubble rising in quiescent shear-thinning tlmds was lnvestlgateO numerically by level set metnoa. number of bubbles in a large range of Reynolds number and Eotvos number were investigated including spherical, oblate and spherical. The bubble shape and drag coefficient were compared with experimental results. It is observed that the simulated results show good conformity to experimental results over a wide range of Reynolds number. In addition, the detailed flow field based on the reference coordinate system moving with the bubble is obtained, and the relationship among flow field, bubble shape and velocity is discussed. 展开更多
关键词 single bubble shear thinning fluid numerical simulation level set method
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Determination of volatile components in cut tobacco with gas chromatography-mass spectrometry and chemometric resolution 被引量:2
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作者 黄兰芳 吴名剑 +5 位作者 孙贤军 钟科军 郭紫明 戴云辉 黄可龙 郭方遒 《Journal of Central South University of Technology》 EI 2007年第4期504-508,共5页
Chromatography-mass spectrometry(GC-MS)was used to analyze the volatile components of cut tobacco samples with the help of heuristic evolving latent projections(HELP).After extracting with simultaneous distillation an... Chromatography-mass spectrometry(GC-MS)was used to analyze the volatile components of cut tobacco samples with the help of heuristic evolving latent projections(HELP).After extracting with simultaneous distillation and extraction method,the volatile components in cut tobacco were detected by GC-MS.Then the obtained original two-dimensional data were resolved into pure mass spectra and chromatograms.The qualitative analysis was performed by similarity searches in the national institute of standards and technology(NIST)mass database with the obtained pure mass spectrum of each component and the quantitative results were obtained by calculating the volume of total two-way response.The accuracy of qualitative and quantitative results were greatly improved by using the two-dimensional comprehensive information of chromatograms and mass spectra.107 of 141 separated constituents in the total ion chromatogram of the volatile components were identified and quantified,accounting for about 88.01% of the total content.The result proves that the developed method is powerful for the analysis of complex cut tobacco samples. 展开更多
关键词 CHEMOMETRICS gas chromatograph-mass spectrometry heuristic evolving latent projection cut tobacco volatile component
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