Experiments were conducted to investigate the behavior of the sequential system of intensified zero-valent iron process(IZVI) and anaerobic filter and biological aerated filter(AF/BAF) reactors for advanced treatment ...Experiments were conducted to investigate the behavior of the sequential system of intensified zero-valent iron process(IZVI) and anaerobic filter and biological aerated filter(AF/BAF) reactors for advanced treatment of biologically pretreated coking wastewater. Particular attention was paid to the performance of the integrated system for the removal of chemical oxygen demand(COD), ammonia nitrogen(NH3-N) and total nitrogen(TN). The average removal efficiencies of COD, NH3-N and TN were 76.28%, 96.76% and 59.97%, with the average effluent mass concentrations of 56, 0.53 and 18.83 mg/L, respectively, reaching the first grade of the national discharge standard. Moreover, the results of gas chromatography/mass spectrum(GC/MS) and gel permeation chromatography(GPC) analysis demonstrated that the refractory organic compounds with high relative molecular mass were partly removed in IZVI process by the function of oxidation-reduction, flocculation and adsorption which could also enhance the biodegradability of the system effluent. The removal efficiencies of NH3-N and TN were achieved mainly in the subsequent AF/BAF reactors by nitrification and denitrification. Overall, the results obtained show that the application of IZVI in combination with AF/BAF is a promising technology for advanced treatment of biologically pretreated coking wastewater.展开更多
During the Asian summer monsoon(ASM)season,the process of stratosphere-troposphere exchange significantly affects the concentration and spatial distribution of chemical constituents in the upper troposphere and lower ...During the Asian summer monsoon(ASM)season,the process of stratosphere-troposphere exchange significantly affects the concentration and spatial distribution of chemical constituents in the upper troposphere and lower stratosphere(UTLS).However,the effect of the intensity of the Asian summer monsoon anticyclone(ASMA)on the horizontal distribution of chemical species within and around the ASMA,especially on the daily time scale,remains unclear.Here,the authors use the MERRA-2 reanalysis dataset and Aura Microwave Limb Sounder observations to study the impact of ASMA intensity on chemical distributions at 100 hPa during the ASM season.The intraseasonal variation of ASMA is classified into a strong period(SP)and weak period(WP),which refer to the periods when the intensity of ASMA remains strong and weak,respectively.The relatively low ozone(O_(3))region is found to be larger at 100 hPa during SPs,while its mixing ratio is lower than during WPs in summer.In June,analysis shows that the O_(3) horizontal distribution is mainly related to the intensity of AMSA,especially during SPs in June,while deep convections also impact the O_(3) horizontal distribution in July and August.These results indicate that the intraseasonal variation of the ASMA intensity coupled to deep convection can significantly affect the chemical distribution in the UTLS region during the ASM season.展开更多
基金Project(2006BAJ04A)suppprted by the National Sci-Tech Support Plan,China
文摘Experiments were conducted to investigate the behavior of the sequential system of intensified zero-valent iron process(IZVI) and anaerobic filter and biological aerated filter(AF/BAF) reactors for advanced treatment of biologically pretreated coking wastewater. Particular attention was paid to the performance of the integrated system for the removal of chemical oxygen demand(COD), ammonia nitrogen(NH3-N) and total nitrogen(TN). The average removal efficiencies of COD, NH3-N and TN were 76.28%, 96.76% and 59.97%, with the average effluent mass concentrations of 56, 0.53 and 18.83 mg/L, respectively, reaching the first grade of the national discharge standard. Moreover, the results of gas chromatography/mass spectrum(GC/MS) and gel permeation chromatography(GPC) analysis demonstrated that the refractory organic compounds with high relative molecular mass were partly removed in IZVI process by the function of oxidation-reduction, flocculation and adsorption which could also enhance the biodegradability of the system effluent. The removal efficiencies of NH3-N and TN were achieved mainly in the subsequent AF/BAF reactors by nitrification and denitrification. Overall, the results obtained show that the application of IZVI in combination with AF/BAF is a promising technology for advanced treatment of biologically pretreated coking wastewater.
基金sponsored by Strategic Priority Research Program of the Chinese Academy of Science[grant No.XDA17010106]the National Key Research and Development Program of China[grant Nos.2018YFC1505703 and 2018YFC1506704].
文摘During the Asian summer monsoon(ASM)season,the process of stratosphere-troposphere exchange significantly affects the concentration and spatial distribution of chemical constituents in the upper troposphere and lower stratosphere(UTLS).However,the effect of the intensity of the Asian summer monsoon anticyclone(ASMA)on the horizontal distribution of chemical species within and around the ASMA,especially on the daily time scale,remains unclear.Here,the authors use the MERRA-2 reanalysis dataset and Aura Microwave Limb Sounder observations to study the impact of ASMA intensity on chemical distributions at 100 hPa during the ASM season.The intraseasonal variation of ASMA is classified into a strong period(SP)and weak period(WP),which refer to the periods when the intensity of ASMA remains strong and weak,respectively.The relatively low ozone(O_(3))region is found to be larger at 100 hPa during SPs,while its mixing ratio is lower than during WPs in summer.In June,analysis shows that the O_(3) horizontal distribution is mainly related to the intensity of AMSA,especially during SPs in June,while deep convections also impact the O_(3) horizontal distribution in July and August.These results indicate that the intraseasonal variation of the ASMA intensity coupled to deep convection can significantly affect the chemical distribution in the UTLS region during the ASM season.
