气化法制备金属超细粉末的有关问题探讨

就电弧气化过程中金属超细粉末形成的机理作了进一步分析，研究了影响粉末粒度和产率的一些规律．提出了粉末粒度控制和提高产粉量的一些工艺要求，并通过系统压差实验和对反应液面吹气量实验进一步验证了理论分析的正确性．

波长连续可调激光及其在化学分析应用中的前景

在现代分析化学中 ,激光在分析测试仪器中的应用已起到了十分重要的作用。但激光在原子分析光谱仪中的应用才刚起步。与其他光分析测试仪相比 ,以光参量设备为基础的激光器具有更宽的波长范围和更容易的波长连续可调性 ,从而显示了巨大的应用潜力。简要介绍了应用于原子分析光谱中的激光技术的一些现状 ,并着重探讨了

Climate Changes in Northeastern China During Last Four Decades

The northeastern China is a sensitive region of climate change, whose detailed trend of climate changes is highly interesting. In this study, this kind of variation trend was analyzed. Potential evapotranspiration (PE) and moisture index (MI) were modeled by using Thornthwaite scheme based on the observation data of 1961-2004 from 94 meteorological stations. To describe the climate fluctuation in the northeastern China in 1961-2004, the linear regression method was used to analyze the variation trends of mean annual temperature, mean annual precipitation, PE and MI. Mann-Kendall method was used to test the significant difference. The results show a general increasing tendency in mean annual temperature, mean annual precipitation, PE and MI. However increasing tendency was more significant in mean annual temperature and PE than in mean annual precipitation and MI. Analysis of seasonal climate variation indicates that there showed positive trends in winter and in spring, while the positive trend was more significant in winter than in spring. Furthermore, the relations between climate changes and geographical factors were analyzed, the results show that both climate factors and their interannual variability were correlated to latitude, longitude and altitude, suggesting that latitude is the most climate factor affecting climate changes, followed by altitude and longitude.

Interannual and Interdecadal Variability of Atmospheric Water Vapor Transport in the Haihe River Basin

The seasonal mean atmospheric precipitable water and water vapor transport over the Haihe River Basin （HRB） in North China with a focus on their interannual to interdecadal variability, and then the relationships of the interannual and interdecadal variability of the water cycle over the HRB to the Pacific Decadal Oscillation （PDO） and E1 Nino-Southern Oscillation （ENSO） phenomena were investigated using the observational and National Centers for Environmental Prediction （NCEP） reanalysis data. There was a strong interdecadal variability for the water cycle （such as precipitation and water vapor transport） over the region, with an abrupt change occurring mostly in the mid 1970s. The intensity of the East Asian summer monsoon largely affected the atmospheric water vapor transport. Generally, the net meridional convergence of the water vapor flux over the region was relatively large before 1965, and it declined gradually from then on with a further notable decrease since mid 1970s. Zonal water vapor transport was similar to meridional, but with a much smaller magnitude and no noteworthy turning in the mid 1970s. Results also suggested that the wind field played an important role in the water vapor transport over the HRB before the mid 1960s, and the interdecadal variability of the water cycle （precipitation, water vapor transport, etc.） in the summer was related to the PDO; however, interannual variation of the water vapor transport could also be related to the ENSO phenomena.

Enhanced Property of Thin Cuprous Oxide Film Prepared through Green Synthetic Route

Thin cuprous oxide films have been prepared by chemical vapor deposition(pulsed spray evaporation-chemical vapor deposition)method without post-treatment.The synthesis of cuprous oxide was produced by applying a water strategy effect.Then,the effect of water on the morphology,topology,structure,optical properties and surface composition of the obtained films has been comprehensively investigated.The results reveal that a pure phase of Cu2O was obtained.The introduction of a small quantity of water in the liquid feedstock lowers the band gap energy from 2.16 eV to 2.04 eV.This finding was mainly related to the decrease of crystallite size due to the effect of water.The topology analyses,by using atomic force microscope,also revealed that surface roughness decreases with water addition,namely more uniform covered surface.Moreover,theoretical calculations based on density functional theory method were performed to understand the adsorption and reaction behaviors of water and ethanol on the Cu2O thin film surface.Formation mechanism of the Cu2O thin film was also suggested and discussed.

An Axial Dispersion Model for Evaporating Bubble Column Reactor

Evaporating bubble column reactor (EBCR) is a kind of aerated reactor in which the reaction heat is removed by the evaporation of volatile reaction mixture. In this paper, a mathematical model that accounts for the gas-liquid exothermic reaction and axial dispersions of both gas and liquid phase is employed to study the performance of EBCR for the process of p-xylene(PX) oxidation. The computational results show that there are remarkable concentration and temperature gradients in EBCR for high ratio of height to diameter (H/DT). The temperature is lower at the bottom of column and higher at the top, due to rapid evaporation induced by the feed gas near the bottom. The concentration profiles in the gas phase are more nonuniform than those (except PX) in the liquid phase, which causes more solvent burning consumption at high H/DT ratio. For p-xylene oxidation, theo ptimal H/DT is around 5.

CONVERSION RATES OF SURFACE HOX RADICALS IN BEIJING CITY

Surface OH radical concentration in Beijing City was measured by impregnated filter trapping technique-high performance liquid chromatography (IFT-HPLC). The observed concentration of OH radical showed obvious diurnal and seasonal variations, with maximum readings at noon or afternoon, similar to 80x10(6)OH/cm(3) in summer and similar to 20x10(6)-40x10(6)OH/cm(3) in fall. On the basis of measured data, the reaction rates related to the photochemical process of HO(x) (OH+HO(2)) were derived and characteristics of atmospheric chemical processes in the city were analyzed. The results showed that conversion rates of atmospheric OH and HO(2) in the summer of Beijing City were about 700x10(6) molecule/(cm(3) . s) and 600x10(6)molecule/(cm(3) . s), respectively. And the net production of OH in the air of the city mainly originated from the photolysis of the gaseous HNO(2), and the main sink of OH were the photochemical reactions with VOCs, NO(2), HCHO and CO. It was different from the clean area.

Comparison of the Influence of Interannual Vegetation Variability between Offline and Online Simulations

This study investigates the influence of interannual vegetation variability. Two sets of offline and online simulations were performed using the Community Earth System Model. The interannual Global LAnd Surface Satellite(GLASS) leaf area index(LAI) dataset from 1985 to 2000 and its associated climatological LAI were used to replace the default climatological LAI data in version 4 of the Community Land Model(CLM4). The results showed that on a global scale, canopy transpiration and evaporation, as well as total evapotranspiration in offline simulations were significantly positively correlated with LAI, whereas ground evaporation and ground temperature showed significant negative correlation with LAI. However, the correlations in online simulations were reduced markedly because of interactive feedbacks between albedo, changed climatic factors and atmospheric variability. In the offline simulations, the fluctuations of differences in interannual variability of evapotranspiration and ground temperature focused on vegetation growing regions and the magnitudes were smaller. Those in online simulations spread over more regions and the magnitudes were larger. These results highlight the influence of interannual vegetation variability, particularly in online simulations, an effect that deserves consideration and attention when investigating the uncertainty of climate change.

Flow characteristics by particle image velocimetry in liquefied natural gas vaporizer model with several baffles

Shell-and-tube vaporizers are the most commonly used and dominated types of vaporizers in liquefied natural gas （LNG） realm. Due to efficient performance, shell-side flow in this type of vaporizers has received considerable attention and has been investigated extensively. However, the detailed flow structure in the shell needs to be determined for reliable and effective design. Therefore, the objective of this study was to clarify the flow structure in shell by particle image velocimetry （PIV）. Experiments were conducted using two types of model; 15% baffle cut having inlet and outlet positions !n the direction of 90° to the cut and 30% baffle cut having inlet and outlet positions in the direction of 180° to the cut. Each test section is 169 mm in inner diameter and 344.6 mm in length. The flow features were characterized in different baffle cuts with regards to the velocity vector field and velocity distribution. The results show that the flow characteristics of 15% baffle cut type vaporizer are comparable to those of 30% baffle cut type vaporizer.

Analytical Model for Predicting the Heat Loss Effect on the Pyrolysis of Biomass Particles

This paper presents the combined influence of heat-loss and radiation on the pyrolysis of biomass particles by considering the structure of one-dimensional, laminar and steady state flame propagation in uniformly premixed wood particles. The assumed flame structure consists of a broad preheat-vaporization zone where the rate of gas-phase chemical reaction is small, a thin reaction zone composed of three regions: gas, tar and char combustion where convection and the vaporization rate of the fuel particles are small, and a broad convection zone. The analysis is performed in the asymptotic limit, where the value of the characteristic Zeldovich number is large and the equivalence ratio is larger than unity(i.e.u≥1). The principal attention is made on the determination of a non-linear burning velocity correlation. Consequently, the impacts of radiation, heat loss and particle size as the determining factors on the flame temperature and burning velocity of biomass particles are declared in this research.

The Microclimatic Influence of a Water Body on an Urban Environment

The paper aims to investigate the potential of a water body to influence in lowering the warmth in the city of Sao Jose do Rio Preto, Brazil, due to the evaporative cooling effects. In order to verify its potential, three collecting points of temperature and humidity were placed in an urban area close to the municipal dam. The first one was placed on the dam margin, the second one, 50 m distant of the margin and, the third one, 100 m distant. The data were taken during December 2010 and then compared to the climate data of the Climate Station of CIIAGRO-Integrated Center of Agro Meteorological. The results show that the closer the collection point is to the water body, and the lower is the temperature variation. The humidity taxes verified at the closest point to the water body indicate values higher than those ones collected at the most distant point. The insertion of moisture through the water bodies in an urban environment demonstrated to be a strategy that improved the thermal conditions and has to be considered for urban planners to establish strategies of urban occupation.

LNG储存容器非稳态泄漏模型研究

将LNG蒸发过程考虑在内,结合实际泄漏过程中容器内各参数的动态变化,建立能够准确表征容器非稳态泄漏过程的模型,结合实例进行分析。结果表明,该模型可模拟不同压力容器或常压容器的泄漏过程,并通过分析简化,得到泄漏率的两种简化计算方法。