Reactive mechanical alloying(RMA)was carried out in a planetary ball mill for the synthesis of ternary hydride Mg2FeH6 for hydrogen storage.The formation mechanism of Mg2FeH6 in RMA process and the sorption properties...Reactive mechanical alloying(RMA)was carried out in a planetary ball mill for the synthesis of ternary hydride Mg2FeH6 for hydrogen storage.The formation mechanism of Mg2FeH6 in RMA process and the sorption properties of the products were investigated.The results show that Mg2FeH6 has a yield ratio around 80%,and a grain size below 10 nm in the powder synthesized by milling 3Mg+Fe mixture for 150 h under the hydrogen pressure of 1 MPa.The synthesized powder possesses a high hydrogen capacity and good sorption kinetics,and absorbs 4.42%(mass fraction)of hydrogen within 200 s at 623 K under the hydrogen pressure of 4.0 MPa.In releasing hydrogen at 653 K under 0.1 MPa,it desorbs 4.43%(mass fraction)of hydrogen within 2 000 s.The addition of Ti increases the hydrogen desorption rate of the complex in the initial 120 s of the desorption process.展开更多
Above ground gas storage devices for compressed air energy storage(CAES) have three types:air storage tanks,gas cylinders,and gas storage pipelines.A cost model of these gas storage devices is established on the basis...Above ground gas storage devices for compressed air energy storage(CAES) have three types:air storage tanks,gas cylinders,and gas storage pipelines.A cost model of these gas storage devices is established on the basis of whole life cycle cost(LCC) analysis.The optimum parameters of the three types are determined by calculating the theoretical metallic raw material consumption of these three devices and considering the difficulties in manufacture and the influence of gas storage device number.The LCCs of the three types are comprehensively analyzed and compared.The result reveal that the cost of the gas storage pipeline type is lower than that of the other two types.This study may serve as a reference for designing large-scale CAES systems.展开更多
The integration and accommodation of the wind and solar energy pose great challenges on today’s power system operation due to the intermittent nature and volatility of the wind and solar resources.High efficient larg...The integration and accommodation of the wind and solar energy pose great challenges on today’s power system operation due to the intermittent nature and volatility of the wind and solar resources.High efficient large-scale electrical energy storage is one of the most effective and economical solutions to those problems.After the comprehensive review of the existing storage technologies,this paper proposes an overall design scheme for the Non-supplementary Fired Compressed Air Energy Storage(NFCAES)system,including system design,modeling and efficiency assessment,as well as protection and control.Especially,the design principles of the multistage regenerative,i.e.heat recovery system which is used to fully recycle and utilize the waste heat from compression are provided,so as the overall system efficiency evaluation method.This paper theoretically ascertains the storage decoupling rules in the potential and internal energy of molecular compressed air and reveals the conversion mechanism of gas,heat,power,electricity and other forms of energy.On this basis,a 500-k W physical simulation system of CAES system(TICC-500,Tsinghua-IPCCAS-CEPRI-CAES)is built,which passed a system-wide 420-k W load power generation test with less pollution and zero carbon emissions.Besides,the multi-form energy conversion of multi-stage regenerative CAES and storage efficiency is verified,especially its incomparable superiority in solving the uncertainty problem in wind and solar power generation.Finally,the propaganda and application scenario of the CAES system in China is introduced.展开更多
基金Project(50574105)supported by the National Natural Science Foundation of ChinaProject(10JJ2037)supported by Hunan Provincial Natural Science Foundation of ChinaProject(200902)supported by Innovation Foundation of State Key Laboratory for Powder Metallurgy,Central South University,China
文摘Reactive mechanical alloying(RMA)was carried out in a planetary ball mill for the synthesis of ternary hydride Mg2FeH6 for hydrogen storage.The formation mechanism of Mg2FeH6 in RMA process and the sorption properties of the products were investigated.The results show that Mg2FeH6 has a yield ratio around 80%,and a grain size below 10 nm in the powder synthesized by milling 3Mg+Fe mixture for 150 h under the hydrogen pressure of 1 MPa.The synthesized powder possesses a high hydrogen capacity and good sorption kinetics,and absorbs 4.42%(mass fraction)of hydrogen within 200 s at 623 K under the hydrogen pressure of 4.0 MPa.In releasing hydrogen at 653 K under 0.1 MPa,it desorbs 4.43%(mass fraction)of hydrogen within 2 000 s.The addition of Ti increases the hydrogen desorption rate of the complex in the initial 120 s of the desorption process.
基金supported by grants from the National High-Tech Research and Development Projects(863)of China(No.2013AA050801)the International S&T Cooperation Projects of China(No.2014DFA60600)
文摘Above ground gas storage devices for compressed air energy storage(CAES) have three types:air storage tanks,gas cylinders,and gas storage pipelines.A cost model of these gas storage devices is established on the basis of whole life cycle cost(LCC) analysis.The optimum parameters of the three types are determined by calculating the theoretical metallic raw material consumption of these three devices and considering the difficulties in manufacture and the influence of gas storage device number.The LCCs of the three types are comprehensively analyzed and compared.The result reveal that the cost of the gas storage pipeline type is lower than that of the other two types.This study may serve as a reference for designing large-scale CAES systems.
基金Science and Technology Fund of SGCC(Grant No.KJ-2012-627)The National Natural Science Foundation of China(Grant No.51321005)
文摘The integration and accommodation of the wind and solar energy pose great challenges on today’s power system operation due to the intermittent nature and volatility of the wind and solar resources.High efficient large-scale electrical energy storage is one of the most effective and economical solutions to those problems.After the comprehensive review of the existing storage technologies,this paper proposes an overall design scheme for the Non-supplementary Fired Compressed Air Energy Storage(NFCAES)system,including system design,modeling and efficiency assessment,as well as protection and control.Especially,the design principles of the multistage regenerative,i.e.heat recovery system which is used to fully recycle and utilize the waste heat from compression are provided,so as the overall system efficiency evaluation method.This paper theoretically ascertains the storage decoupling rules in the potential and internal energy of molecular compressed air and reveals the conversion mechanism of gas,heat,power,electricity and other forms of energy.On this basis,a 500-k W physical simulation system of CAES system(TICC-500,Tsinghua-IPCCAS-CEPRI-CAES)is built,which passed a system-wide 420-k W load power generation test with less pollution and zero carbon emissions.Besides,the multi-form energy conversion of multi-stage regenerative CAES and storage efficiency is verified,especially its incomparable superiority in solving the uncertainty problem in wind and solar power generation.Finally,the propaganda and application scenario of the CAES system in China is introduced.
