Based on the solid-gas eutectic unidirectional solidification technique and the principle of unidirectional solidification of single-phase alloy, a new method for evaluating the diffusion coefficient of hydrogen in li...Based on the solid-gas eutectic unidirectional solidification technique and the principle of unidirectional solidification of single-phase alloy, a new method for evaluating the diffusion coefficient of hydrogen in liquid metals was proposed. Taking Cu-H2 system for example, the influences of argon partial pressure and superheat degree of melt on the diffusion coefficient of hydrogen in liquid metal were studied and the predicted values were similar to each other. The obtained temperature-dependent equation for diffusion coefficient of hydrogen in liquid copper is comparable with experimental data in literature, which validates the effectiveness of this method. The temperature-dependent equations for diffusion coefficient of hydrogen in liquid Mg, Si and Cu-34.6%Mn alloy were also evaluated by this method, along with the values at the melting point of each metal and alloy.展开更多
The injection of a high pressure gas into a stagnant liquid pool is the characteristic phenomenon during the expansion phase of a hypothetical core disruptive accident in liquid metal cooled fast reactors. In order to...The injection of a high pressure gas into a stagnant liquid pool is the characteristic phenomenon during the expansion phase of a hypothetical core disruptive accident in liquid metal cooled fast reactors. In order to investigate lots of mechanisms involved in this phase of the accident＇s evolution, an experimental campaign called S GI was performed in 1994 in Forschungszentrum Karlsruhe, now KIT. This campaign consists of nine experiments which have been dedicated to assess the effects of different pressure injection, the nozzle＇s size and the presence of inner confinement in the formation of the rising bubble. Three of these experiments, which were focused on the pressure effects, have now been simulated with SIMMER III code and with FLUENT 6.3, a commercial CFD code. Both codes, despite their different features, have showed a good agreement with the experimental results. In particular, time trend evolutions of pressures and bubble volumes have been well reproduced by simulation. Furthermore, both codes agree on the shape of the bubble, even though they have evidenced same discrepancies with the experimental shape.展开更多
Previous reports about the growth of large graphene single crystals on polycrystalline metal substrates usually adopted the strategy of suppressing the nucleation by lowering the concentration of the feedstock, which ...Previous reports about the growth of large graphene single crystals on polycrystalline metal substrates usually adopted the strategy of suppressing the nucleation by lowering the concentration of the feedstock, which greatly limited the rate of the nucleation and the sequent growth. The emerging liquid metal catalyst possesses the characteristic of quasi-atomically smooth surface with high diffusion rate. In principle, it should be a naturally ideal platform for the lowdensity nucleation and the fast growth of graphene. However,the rapid growth of large graphene single crystals on liquid metals has not received the due attention. In this paper, we firstly purposed the insight into the rapid growth of large graphene single crystals on liquid metals. We obtained the millimeter-size graphene single crystals on liquid Cu. The rich free-electrons in liquid Cu accelerate the nucleation, and the isotropic smooth surface greatly suppresses the nucleation.Moreover, the fast mass-transfer of carbon atoms due to the excellent fluidity of liquid Cu promotes the fast growth with a rate up to 79 μm s^-1. We hope the research on the growth speed of graphene on liquid Cu can enrich the recognition of the growth behavior of two-dimensional(2 D) materials on the liquid metal. We also believe that the liquid metal strategy for the rapid growth of graphene can be extended to various 2 D materials and thus promote their future applications in the photonics and electronics.展开更多
基金Project(51271096)supported by the National Natural Science Foundation of ChinaProject(NCET-12-0310)supported by Program for New Century Excellent Talents in University,China
文摘Based on the solid-gas eutectic unidirectional solidification technique and the principle of unidirectional solidification of single-phase alloy, a new method for evaluating the diffusion coefficient of hydrogen in liquid metals was proposed. Taking Cu-H2 system for example, the influences of argon partial pressure and superheat degree of melt on the diffusion coefficient of hydrogen in liquid metal were studied and the predicted values were similar to each other. The obtained temperature-dependent equation for diffusion coefficient of hydrogen in liquid copper is comparable with experimental data in literature, which validates the effectiveness of this method. The temperature-dependent equations for diffusion coefficient of hydrogen in liquid Mg, Si and Cu-34.6%Mn alloy were also evaluated by this method, along with the values at the melting point of each metal and alloy.
文摘The injection of a high pressure gas into a stagnant liquid pool is the characteristic phenomenon during the expansion phase of a hypothetical core disruptive accident in liquid metal cooled fast reactors. In order to investigate lots of mechanisms involved in this phase of the accident＇s evolution, an experimental campaign called S GI was performed in 1994 in Forschungszentrum Karlsruhe, now KIT. This campaign consists of nine experiments which have been dedicated to assess the effects of different pressure injection, the nozzle＇s size and the presence of inner confinement in the formation of the rising bubble. Three of these experiments, which were focused on the pressure effects, have now been simulated with SIMMER III code and with FLUENT 6.3, a commercial CFD code. Both codes, despite their different features, have showed a good agreement with the experimental results. In particular, time trend evolutions of pressures and bubble volumes have been well reproduced by simulation. Furthermore, both codes agree on the shape of the bubble, even though they have evidenced same discrepancies with the experimental shape.
基金supported by the National Natural Science Foundation of China(21673161)the Sino-German Center for Research Promotion(1400)
文摘Previous reports about the growth of large graphene single crystals on polycrystalline metal substrates usually adopted the strategy of suppressing the nucleation by lowering the concentration of the feedstock, which greatly limited the rate of the nucleation and the sequent growth. The emerging liquid metal catalyst possesses the characteristic of quasi-atomically smooth surface with high diffusion rate. In principle, it should be a naturally ideal platform for the lowdensity nucleation and the fast growth of graphene. However,the rapid growth of large graphene single crystals on liquid metals has not received the due attention. In this paper, we firstly purposed the insight into the rapid growth of large graphene single crystals on liquid metals. We obtained the millimeter-size graphene single crystals on liquid Cu. The rich free-electrons in liquid Cu accelerate the nucleation, and the isotropic smooth surface greatly suppresses the nucleation.Moreover, the fast mass-transfer of carbon atoms due to the excellent fluidity of liquid Cu promotes the fast growth with a rate up to 79 μm s^-1. We hope the research on the growth speed of graphene on liquid Cu can enrich the recognition of the growth behavior of two-dimensional(2 D) materials on the liquid metal. We also believe that the liquid metal strategy for the rapid growth of graphene can be extended to various 2 D materials and thus promote their future applications in the photonics and electronics.
