In order to simplify the fabrication process,distribute the temperature uniformly and reduce the power consumption of the micro-hotplate(MHP) gas sensor,a planar-type gas sensor based on SnO2 thin film with suspende...In order to simplify the fabrication process,distribute the temperature uniformly and reduce the power consumption of the micro-hotplate(MHP) gas sensor,a planar-type gas sensor based on SnO2 thin film with suspended structure is designed through a MEMS process.Steady-state thermal analysis of the gas sensor and the closed membrane type sensor where the membrane overlaps the Si substrate is carried out with the finite element model,and it is shown that the suspended planar-type gas sensor has a more homogeneous temperature distribution and a lower power consumption.When the maximum temperature on the sensor reaches 383℃,the power consumption is only 7 mW,and the temperature gradient across the thin film is less than 14℃.To overcome the fragility of the suspended beams,a novel fabrication process in which the deposition of the gas sensing film occurs prior to the formation of suspended beams is proposed.The back side of the Si substrate is etched through deep reactive ion etching(DRIE) to avoid chemical pollution of the front side.The fabrication steps in which only four masks are used for the photolithography are described in detail.The Fe doped SnO2 thin film synthesized by sol-gel spin-coating is used as the gas sensing element.The device is tested on hydrogen and exhibits satisfactory sensing performance.The sensitivity increases with the rise of the concentration from 50×10-6 to 2000×10-6,and reaches about 30 at 2000×10-6.展开更多
The simulations of a heat wave occurring in southern Yangtze-Huaihe valley and southern China during late July,2003 were conducted to examine the sensitivity of simulated surface air temperature(SAT) to different land...The simulations of a heat wave occurring in southern Yangtze-Huaihe valley and southern China during late July,2003 were conducted to examine the sensitivity of simulated surface air temperature(SAT) to different land surface schemes(LSSs) using the Weather Research and Forecasting Model(WRF) Version 2.2 in the short-range mode for 24-h integrations.Initial and boundary conditions employed a National Centers for Environmental Prediction(NCEP) analysis.The results showed that,overall,simulated high-temperature weather is sensitive to different LSSs.Large differences in simulated SAT intensity,threat score,and simulated error under different schemes are identified clearly.In addition,some systematic differences are also in-duced by the LSSs.In terms of threat score from the three LSSs,SLAB is the best,and RUC is better than NOAH.SLAB gives the lowest absolute error for area-averaged SAT,and tends to depict the western Pacific subtropical high with the east-ernmost position at low levels.The LSSs modify the simulated SAT,primarily via the transfer of sensible heat from the land surface to the atmosphere.The physical mechanism of the positive feedback between atmospheric circulation and the SAT is unimportant,with"negative"feedback over most of the simulated areas.This study emphasizes the importance of improving LSSs in SAT forecasting by numerical models.展开更多
There are great needs for real-time detection of volatile organic amines(VOA)through low-cost detection methods in public health,food safety,and environmental monitoring area.Organic thin-film fluorescent probe(OTFFP)...There are great needs for real-time detection of volatile organic amines(VOA)through low-cost detection methods in public health,food safety,and environmental monitoring area.Organic thin-film fluorescent probe(OTFFP)is expected to become a new and efficient means of detecting VOA because of its fast response,high sensitivity,no contamination to the analyte and ease to prepare a portable instrument.Compared with the mature detection methods in solution,research on solid fluorescence sensing has been less studied.In this article,we review recent progress in OTFFP research for VOA vapour.We mainly focus on the new fluorescent sensing mechanisms applied in solid state in recent years and the design principle of probes for different types of organic amines(such as primary amine,secondary amine,tertiary amine and aromatic amine).We also review the material structures of these probes and the strategies to enhance their sensitivity or selectivity.展开更多
Richardson et al. (Sci Bull, 2015. doi:10.1007/ sl1434-015-0806-z) suggest that the irreducibly simple climate model described in Monckton of Brenchley et al. (Sci Bull 60:122-135, 2015. doi:10.1007/s11434-014- ...Richardson et al. (Sci Bull, 2015. doi:10.1007/ sl1434-015-0806-z) suggest that the irreducibly simple climate model described in Monckton of Brenchley et al. (Sci Bull 60:122-135, 2015. doi:10.1007/s11434-014- 0699-2) was not validated against observations, relying instead on synthetic test data based on underestimated global warming, illogical parameter choice and near-in- stantaneous response at odds with ocean warming and other observations. However, the simple model, informed by its authors' choice of parameters, usually hindcasts observed temperature change more closely than the general-circu- lation models, and finds high climate sensitivity implausi- ble. With IPCC's choice of parameters, the model is further validated in that it duly replicates IPCC's sensitivity interval. Also, fast climate system response is consistent with near-zero or net-negative temperature feedback. Given the large uncertainties in the initial conditions and evolutionary processes determinative of climate sensitivity, subject to obvious caveats a simple sensitivity-focused model need not, and the present model does not, exhibit significantly less predictive skill than the general-circula- tion models.展开更多
By using the global atmospheric general circulation model CAM4.0 including an urban canopy parameterization scheme,the possible impacts of large-scale urbanization in East China on East Asian winter monsoon was invest...By using the global atmospheric general circulation model CAM4.0 including an urban canopy parameterization scheme,the possible impacts of large-scale urbanization in East China on East Asian winter monsoon was investigated via idealized numerical experiments.Results suggest that large-scale urbanization can cause a significant warming effect in both surface temperature and air temperature near the surface over most areas of East China.Meanwhile,large-scale urbanization also alters the surface energy balance,causing evident increases in net surface long-wave radiation and sensible heat flux as well as intensified surface thermal heating to the atmosphere.Forced by the surface thermal heating anomalies induced by the large-scale urban expansion,East Asian winter monsoon circulation exhibits distinct changes.Overall,the extensive urbanization over East China will weaken East Asian winter monsoon,but intensify winter monsoon in northeast China.展开更多
基金The National Natural Science Foundation of China (No.58175122)the Natural Science Foundation of Jiangsu Province (No.BK2007185)+1 种基金the Natural Science Foundation of Higher Education Institutions of Jiangsu Province(No.07KJB460044)the Scientific Research Innovation Project for College Graduates in Jiangsu Province (No.CXZZ11_0340)
文摘In order to simplify the fabrication process,distribute the temperature uniformly and reduce the power consumption of the micro-hotplate(MHP) gas sensor,a planar-type gas sensor based on SnO2 thin film with suspended structure is designed through a MEMS process.Steady-state thermal analysis of the gas sensor and the closed membrane type sensor where the membrane overlaps the Si substrate is carried out with the finite element model,and it is shown that the suspended planar-type gas sensor has a more homogeneous temperature distribution and a lower power consumption.When the maximum temperature on the sensor reaches 383℃,the power consumption is only 7 mW,and the temperature gradient across the thin film is less than 14℃.To overcome the fragility of the suspended beams,a novel fabrication process in which the deposition of the gas sensing film occurs prior to the formation of suspended beams is proposed.The back side of the Si substrate is etched through deep reactive ion etching(DRIE) to avoid chemical pollution of the front side.The fabrication steps in which only four masks are used for the photolithography are described in detail.The Fe doped SnO2 thin film synthesized by sol-gel spin-coating is used as the gas sensing element.The device is tested on hydrogen and exhibits satisfactory sensing performance.The sensitivity increases with the rise of the concentration from 50×10-6 to 2000×10-6,and reaches about 30 at 2000×10-6.
基金supported by National Natural Science Foundation of China(Grant No.40875067)part by Knowledge Innovation Program of the Chinese Academy of Sciences(Grant No.IAP09306)
文摘The simulations of a heat wave occurring in southern Yangtze-Huaihe valley and southern China during late July,2003 were conducted to examine the sensitivity of simulated surface air temperature(SAT) to different land surface schemes(LSSs) using the Weather Research and Forecasting Model(WRF) Version 2.2 in the short-range mode for 24-h integrations.Initial and boundary conditions employed a National Centers for Environmental Prediction(NCEP) analysis.The results showed that,overall,simulated high-temperature weather is sensitive to different LSSs.Large differences in simulated SAT intensity,threat score,and simulated error under different schemes are identified clearly.In addition,some systematic differences are also in-duced by the LSSs.In terms of threat score from the three LSSs,SLAB is the best,and RUC is better than NOAH.SLAB gives the lowest absolute error for area-averaged SAT,and tends to depict the western Pacific subtropical high with the east-ernmost position at low levels.The LSSs modify the simulated SAT,primarily via the transfer of sensible heat from the land surface to the atmosphere.The physical mechanism of the positive feedback between atmospheric circulation and the SAT is unimportant,with"negative"feedback over most of the simulated areas.This study emphasizes the importance of improving LSSs in SAT forecasting by numerical models.
基金the National Natural Science Foundation of China(61325001,21273267,61321492,51473182)grant from Youth Innovation Promotion Association CAS(2015190)Shanghai Municipal Commission of Economy and Informatization
文摘There are great needs for real-time detection of volatile organic amines(VOA)through low-cost detection methods in public health,food safety,and environmental monitoring area.Organic thin-film fluorescent probe(OTFFP)is expected to become a new and efficient means of detecting VOA because of its fast response,high sensitivity,no contamination to the analyte and ease to prepare a portable instrument.Compared with the mature detection methods in solution,research on solid fluorescence sensing has been less studied.In this article,we review recent progress in OTFFP research for VOA vapour.We mainly focus on the new fluorescent sensing mechanisms applied in solid state in recent years and the design principle of probes for different types of organic amines(such as primary amine,secondary amine,tertiary amine and aromatic amine).We also review the material structures of these probes and the strategies to enhance their sensitivity or selectivity.
文摘Richardson et al. (Sci Bull, 2015. doi:10.1007/ sl1434-015-0806-z) suggest that the irreducibly simple climate model described in Monckton of Brenchley et al. (Sci Bull 60:122-135, 2015. doi:10.1007/s11434-014- 0699-2) was not validated against observations, relying instead on synthetic test data based on underestimated global warming, illogical parameter choice and near-in- stantaneous response at odds with ocean warming and other observations. However, the simple model, informed by its authors' choice of parameters, usually hindcasts observed temperature change more closely than the general-circu- lation models, and finds high climate sensitivity implausi- ble. With IPCC's choice of parameters, the model is further validated in that it duly replicates IPCC's sensitivity interval. Also, fast climate system response is consistent with near-zero or net-negative temperature feedback. Given the large uncertainties in the initial conditions and evolutionary processes determinative of climate sensitivity, subject to obvious caveats a simple sensitivity-focused model need not, and the present model does not, exhibit significantly less predictive skill than the general-circula- tion models.
基金supported by the National Basic Research Program of China(2010CB428505 and 2011CB952004)Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institu-tions(PAPD)
文摘By using the global atmospheric general circulation model CAM4.0 including an urban canopy parameterization scheme,the possible impacts of large-scale urbanization in East China on East Asian winter monsoon was investigated via idealized numerical experiments.Results suggest that large-scale urbanization can cause a significant warming effect in both surface temperature and air temperature near the surface over most areas of East China.Meanwhile,large-scale urbanization also alters the surface energy balance,causing evident increases in net surface long-wave radiation and sensible heat flux as well as intensified surface thermal heating to the atmosphere.Forced by the surface thermal heating anomalies induced by the large-scale urban expansion,East Asian winter monsoon circulation exhibits distinct changes.Overall,the extensive urbanization over East China will weaken East Asian winter monsoon,but intensify winter monsoon in northeast China.