钻井液定量气测分析系统设计与应用

钻井液所携天然气组分的定量采样检测是气测录井的难题,也是录井技术的发展方向之一。结合上海神开石油科技有限公司对定量气测分析系统的开发与应用,验证了全新的定量脱气器和色谱仪。定量脱气器通过PLC流量反馈控制技术实现了钻井液的定量采样脱气,其钻井液处理量可以与常规脱气器相当,脱气筒的加热设计进一步提高了对天然气高沸点组分的测量准确性,定量脱气器的模块化设计更便于现场安装和搬运;与之配套的色谱仪采用EPC流路控制技术和双色谱柱设计,可以实现对C_1-C_8组分的快速分离检测,C_(6+)组分的在线测量则进一步拓展了现场气测录井的应用范围。

浅谈合成基钻井液体系下落实油气显示的方法--以征10井为例

合成基钻井液在钻井中越来越多的被采用,针对合成基钻井液体系下落实油气显示的难题,通过改进传统录井手段,对气测曲线形态的分析、色谱全烃、组分的不同变化特点,定量荧光谱图特征、峰值变化规律及各种资料相关性进行综合性分析,结合区域地质资料对比分析,总结了一些在合成基钻井液条件下甄别真假油气显示的解释评价方法,实际应用取得较好效果。

QUALITY CONTROL OF SINGLE DOPPLER RADAR DATA AND RETRIEVAL OF HORIZONTAL WIND FOR A LANDING TYPHOON

The removal of noise and velocity ambiguity and retrieval and verification of horizontal wind field is a prerequisite to make the best and fullest use of Doppler radar measurements. This approach was applied to the Doppler radar data collected during August 2005 for a landing typhoon Matsa (0509) in Yantai, Shangdong Province, and the verified result shows that the quality control for this dataset was successful. The horizontal wind field was retrieved and then verified by studying the characteristics of the radar radial velocity and large-scale wind field and the vertical cross section of the radial velocity determined with the typhoon center as the circle center and comparing it with satellite imagery. The results show that the meso- and small-scale systems in Matsa and its horizontal and vertical structure could be clearly retrieved using the dataset collected by single Doppler radar, and a shear or a convergence was corresponding with a band of severe storm around Matsa. At the same time, the retrieved wind field from single Doppler radar is proved to be a reliable and high-resolution dataset in analyzing the inner meso-scale structure of Matsa. It is also proved that the method for removing the velocity ambiguity could be an effective approach for preliminary quality control of the Doppler radar data, and the VAP method could also be a reasonable solution for the analysis of mesoscale wind field.

The Curl of Q Vector: A New Diagnostic Parameter Associated with Heavy Rainfall

As a powerful tool to diagnose vertical motion, frontogenesis, and secondary circulation, the Q vector and its divergence are widely used. However, little attention has been given to the curl of Q vector. In this paper, a new set of analyses combining the divergence of the Q vector （DQ） with the vertical component of the curl of the Q vector （VQ） is applied to a Northeastern cold vortex rainfall case. From the derivation, it was found that the expressions of the Q vectors and their divergences in saturated moist flow （DQm） differ from those of dry and unsaturated moist atmosphere （DQ）, while the VQs of various background flows are exactly the same, which largely simplified the analyses. This case study showed that, compared with the DQ, not only can the DQm diagnose precipitation more effectively, but the VQ may also be indicative of precipitation （especially for heavy rainfall and strong convection） because of its direct, close relationship with ageostrophic motion. Thus, the VQ may be computed and analyzed with ease, and may serve as a useful tool for analyses of precipitation and strong convective svstems.

Numerical and Dimensional Analysis for Prediction of Line Heating Residual Deformations

Line heating process is a very complex phenomenon as a variety of factors affects the amount of residual deformations. Numerical thermal and mechanical analysis of line heating for prediction of residual deformation is time consuming. In the present work dimensional analysis has been presented to obtain a new relationship between input parameters and resulting residual deformations during line heating process. The temperature distribution and residual deformations for 6 mm, 8 mm, 10 mm and 12 mm thick steel plates were numerically estimated and compared with experimental and published results. Extensive data generated through a validated FE model were used to find co-relationship between the input parameters and the resulting residual deformation by multiple regression analysis. The results obtained from the deformation equations developed in this work compared well with those of the FE analysis with a drop in the computation time in the order of 100 (computational time required for FE analysis is around 7 200 second to 9 000 seconds and where the time required for getting the residual deformation by developed equations is only 60 to 90 seconds).

Determination of constituents of essential oil from Angelica sinensis by gas chromatographymass spectrometry

Gas chromatographymass spectrometry (GC-MS) coupled with chemometric resolution upon two- dimensional data was employed to analyze the constituents of essential oils of Angelica sinensis. Constituents in essential oils of Angelica sinensis root were identified by GC-MS with the help of subwindow factor analysis (SFA) method resolving two-dimensional original data into mass spectra and chromatograms. 76 of 97 separated constituents in essential oil of Angelica sinensis root were identified and quantified, and they account for about 91.36% of the total content. The results show that ligustilide, butylene phthalide, 2-methoxy-4-vinylphenol, carvacrol, allo-ocimene,2,6,6-trimethylbicyclo-[3,1,1]hept-2-ene are the main constituents in essential oil of Angelica sinensis root.

Characterization of Specific Spoilage Bacteria and Volatile Flavor Compounds of Flavored Crayfish

It is a common issue in the processing industry of crayfish that flavored crayfish stored at room temperature is perishable.In order to establish an effective putrid prediction mechanism,high-throughput sequencing and solid phase microextraction gas chromatography-mass spectrometry(SPME-GCMS)were used to analyse the microbial community structure and volatile flavor compounds of normal and putrid crayfish.The results showed that Aeromonas(57%),Macrococcus(7.7%),Vibrio sp.(6.6%),Acinetobacter(5%),Citrobacter(4.9%)and Enterobacter(1.49%)were the main bacterial genus in the refrigerated fresh crayfish(HNA).And Staphylococcus(17.04%),Aeromonas(4.46%),Xanthomonas(4.16%),Streptococcus(4.62%)and Enterococcus(2.77%)were the main bacterial genus in the marinated and refrigerated crayfish(HND).With the spoilage of samples(HNE and HNC),the diversity of bacteria decreased,and the specific spoilage bacteria grew rapidly,mainly Enterococcus,Bacillus,Lactobacillus,Leuconostoc,Weissella.Meanwhile,the volatile compounds in non-spoilage sample(HNA and HND)were mainly alkane compounds,aldehydes compound and esters compounds;and the volatile compounds in spoilage samples were mainly alcohols,acids,benzene compounds,terpenoids,N-containing compounds,S-containing compounds and ethers.This indicated that the contents and types of volatile compounds changed with the sample spoilage and deterioration.Correlation analysis results showed that Enterococcus,Lactobacillus and Bacillus were significantly positively correlated with alcohols,acids,benzene,terpenoids,N-containing compounds,S-containing compounds and ether compounds,while Aeromonas,Megasphaera,Acinetobacter,Citrobacter and Vibrio were significantly positively correlated with alkane compounds and esters compounds,and Leuconostoc were significantly positively correlated with alcohol compounds.These results can provide a theoretical guidance for the storage of cooked flavor crayfish at room temperature.

Climate Precipitation Prediction by Neural Network

In this work a neural network model for climate forecasting is presented. The model is built by training a neural network with available reanalysis data. In order to assess the model, the development methodology considers the use of data reduction strategies that eliminate data redundancy thus reducing the complexity of the models. The results presented in this paper considered the use of Rough Sets Theory principles in extracting relevant information from the available data to achieve the reduction of redundancy among the variables used for forecasting purposes. The paper presents results of climate prediction made with the use of the neural network based model. The results obtained in the conducted experiments show the effectiveness of the methodology, presenting estimates similar to observations.

A simple analytical method for deflation prediction of inflatable structures

The static performance of inflatable structures has been well studied and the dynamic deployment simulation has received much attention. However, very few studies focus on its deflation behavior. Although there are several dynamic finite element algorithms that can be applied to the deflation simulation, their computation costs are expensive, especially for large scale structures. In this work, a simple method based on classic thermodynamics and the analytical relationship between air and membrane was proposed to efficiently analyze the air state variables under the condition of ventilation. Combined with failure analysis of static bearing capacity, a fast incremental analytical method was presented to predict both elastic and post wrinkling deflation process of inflatable structures. Comparisons between simplified analysis, dynamic finite element simulation, and a full-scale experimental test are presented and the suitability of this simple method for solving the air state and predicting the deflation behavior of inflatable structures is proved.

Urbanization-related warming in local temperature records:a review

There have long been arguments about the impact of urbanization on local meteorological observations. This letter reviews up-to-date studies of the urbanization-related warming in the observed land surface air temperature series in China. Many previous studies have suggested that, over the past few decades, the local warming due to urbanization could have been about 0.1 °C/10 yr, or even larger. However, based on recently developed homogenized temperature records, the estimated urban bias is smaller. Major uncertainties arise from either the data quality or the techniques used to estimate the urbanization effect. A key example is the ‘observationminus-reanalysis＇ method, which tends to overestimate the urban signal in this region, partly due to systematic bias in the multi-decadal variability of surface air temperature in the reanalysis data. It is expected that improved numerical modeling with high-resolution information regarding the changing land surface in the region will help to further understand and quantify the effect of urbanization in local temperature records.

Multi-fractal Behaviors of Relative Humidity over China

The multi-fractal ity over China are studied behaviors of relative humid using the multi-fractal de trended fluctuation analysis （DFA） method. Three multi fractal parameters （the spectrum width Aa, the asymmetry Aaas, and the long-range correlation exponent a0） of the singularity spectrum are introduced to quantify the multi-fractal behaviors. The results show that multi-frac tality exists in daily humidity records over most stations in China and is mainly due to the broad distribution of the probability density of the sequence values. Strong multi fractal behaviors over some stations in the Yunnan, Guangdong, and Inner Mongolia provinces are obvious. These behaviors are mainly caused by different long range correlations between large and small fluctuations. The asymmetry of the singularity of relative humidity records is weak, except for a small number of stations in the far east and west of China, where the singularity spec trum is left-skewed. Finally, the long-range correlations in North China are stronger than those in South China, which indicates better predictability in North China. By studying the parameters of the multi-fractal spectrum, various data of long-range power law correlations of the relative humidity records are obtained, which may pro vide theoretical support for climate prediction.

The digital diagrams analysis and forecast of sandstorm weather

The strong sandstorm weather process analysis has been done with the information digital diagrams method and times extended observation information on 23rd May,2004 in Gansu Province. The research results reveal the unique mechanism structure of sandstorm disaster weather and the signification of irregular information,approve that the region digital diagrams has the capability to forecast the character and intension of transition disaster weather,and explain certainly that the meteorological problem is transformation problem of evolvement science.

Methane adsorption-induced coal swelling measured with an optical method

In order to quantify the effect of matrix shrinkage on reservoir permeability during coalbed methane production, coal samples from Huozhou, Changzhi and Jincheng areas in Shanxi province （classified as high-volatile bituminous coal, low-volatile bituminous coal and anthracite, respectively） were collected, and adsorption-induced coal swelling in methane were determined by an optical method at 40 ℃ and pressure up to 12 MPa. All three coals showed similar behavior-that swelling increased as a function of pressure up to about 10 MPa but thereafter no further increase in swelling was observed. Swelling in the direction perpendicular to the bedding plane is greater than that parallel to the bedding plane, and the differences are about 7.77-8.33%. The maximum volumetric swelling ranges from 2.73% to 3.21 %-increasing with increasing coal rank. The swelling data can be described by a modified DR model. In addition, swelling increases with the amount of adsorption. However, the increase shows a relatively slower stage followed by a relatively faster stage instead of a linear increase. Based on the assumption that sorption-induced swelling/shrinkage of coal in methane is reversible, the permeability increases induced by coal shrinkage during methane desorption was analyzed, and the results indicate that the permeability change is larger for higher rank coal in the same unit of pressure depletion.

超浅疏松地层气超浅疏松地层气、水层识别方法——以大庆某地区黑帝庙层为例

大庆某地区黑帝庙储层压实程度低、成岩作用差、物性好,导致气、水层的电性特征相近而难以区分。在储层岩性、物性、水性和电性关系分析的基础上,确立中子测井为气层敏感曲线。以中子测井曲线为核心,建立中子测井与深侧向电阻率、密度、声波时差的交会图,确定气层解释下限标准。利用电阻率与声波时差、自然电位以及中子测井与密度、声波时差在气、水层匹配关系的不同,提出多曲线重叠与气测资料综合定性判断气层方法。为进一步扩大气层响应特征,采用多曲线定量计算气层解释综合判断参数,并与自然电位曲线交会区分气、水层,取得较好效果。15口试气井解释结果与试气结论进行背对背验证,气层解释符合率达到了84.4%。

Biodiesel Production by Enzymatic Catalysis Process Using Two Analytical Ways： Gas Chromatography and Total Glycerol Determination

Currently, biodiesel is presented as one of the best alternatives for gradually replacing the use of fossil fuels, but it has some factors that make it economically impractical if it does not have a government support. For this reason, research efforts focused on this area have been responsible for optimizing the process of biodiesel production by different catalytic routes to achieve greater efficiency at a lower cost. In this case, the biggest problem has been the high cost generated by an investigation, which in many occasions is the main factor to decide if an investigation could be carried out. Trying to reduce these costs, in the current study, we are using a technique of glycerol quantification by volumetric methods and comparing obtained results with the chromatographic method, which is conventionally used and comparatively much more expensive. Biodiesel employee was obtained by an enzymatic catalysis process varying one of three process variables：oil：alcohol molar ratio, temperature and proportion of catalyst. The numerical differences obtained between the two quantification methods generated relative errors lower than 10%, resulting in some occasions lower than 1%. By gas chromatography analysis the best yield was obtained at the same conditions of the volumetric method, a temperature of 45 ℃, an oil：alcohol ratio 1：4 and 8 wt.% of catalyst, but a yield of 95.5% and 97.1%, respectively. Due to the high precision of gas chromatography, this method is used to carry out a surface response analysis obtaining as ideal operating conditions a temperature of 43.5 ℃, 8.9 wt.%. of catalyst and an oil：alcohol ratio 1：4.

Acoustic Resonance in Exhaust Gas Economizer Tube Bundles Prediction and Suppression of Resonance

The tendency for air column resonance generation in structures with a constant volume behind a tube array like that of an exhaust gas economizer has been reported, but many points remain unclear with respect to the mechanism and conditions that generate acoustical resonance. When acoustical resonance is generated, in reality, prevention and suppression measures are implemented by inserting a baffle plate into the ducts through a process of trial and error. The purpose of this study is to clarify the mechanism of generation of acoustical resonance, and to establish an appropriate measure to prevent such resonance. Noise generated in an exhaust gas economizer was correlated with the flow inside the tube array and experimentally analyzed, and the mechanism for resonance generation was considered. In addition, the effectiveness of a baffle plate positioned in order to prevent resonance was investigated. We have successfully employed a single baffle plate to suppress resonance.

A quantification of the treadmill 6-min walk test using the My Wellness Key^(TM) accelerometer

Background： Accelerometers have been suggested to provide additional information during the 6-min walk test which may be useful in evaluating changes in functional exercise capacity. The aim of the study was to identify whether the additional information measured by the My Wellness Key^TM（MWK） accelerometer during a treadmill 6-min walk test（t-6MWT） was related to currently used outcome measures.Methods： Fifteen participants（9 males, 6 females） performed a self-paced t-6MWT. Respiratory gas analysis and walking distance were measured whilst wearing the MWK.Results： A significant correlation was established between activity counts and 6-min walk distance（6MWD）（r=-0.847, p 〈 0.001） yet not 6-min walk work（6MWW）（r=-0.337, p=0.220）. Energy expenditure estimated by the MWK was strongly correlated to 6MWW（r=0.938, p 〈 0.001）but not 6MWD（r=0.477, p=0.072）. The MWK significantly underestimated energy expenditure（36.73, CI=33.9-39.7 kcal） compared to gas analysis（54.35, CI=46.2-61.4 kcal） demonstrating poor agreement between the two analyses（Bias=-17.61 kcal, Limits of agreement=-37.4,t2.2 kcal）. Measurement of time spent undertaking light, moderate, and vigorous physical activity was not significantly different（ p 〉 0.05）between the MWK and gas analysis.Conclusion： Estimated energy expenditure provided by the MWK was strongly correlated to 6MWW; however, MWK underestimated energy expenditure as measured by gas analysis. The MWK may provide outcome data that supplement those currently provided by the 6MWD for functional capacity assessment during the t-6MWT.

Full-Scale Measurement and Numerical Analysis of Liquefied Petroleum Gas Water Heaters with Ventilation Factors in Balcony

This study carried out full-scale gas water heater combustion experiments and adopted FDS （fire dynamics simulator） to simulate three scenarios--different balcony environments when using water heater, such as airtight balcony, indoor door with openings and force ventilation to compare with full-scale combustion experiments. According to FDS simulation results, 02, CO and CO2 simulation concentration value correspond with full-scale experimental results. When the indoor O2 concentration was lower than 15%, which causes incomplete combustion, the CO concentration would rise rapidly and even reached above 1,500 ppm, causing death in short time. In addition, when the force ventilation model supplied the water heater with enough air to bum, the indoor CO concentration will keep low and harmless to humans. The study also adopted diverse variables, such as the opening area of window, outdoor wind speed and water heater types, to analyze deeply user＇s safety regarding gas water heater. In a result, while balcony area is larger than 14 mE, the volume of water heater is below 16 L （33.1 kW）, and the indoor window, connecting balcony with room, is closed, if the opening on the outdoor window of the balcony is larger than 0.2 mE, this can ensure the personal security of the indoor space.

Simultaneous Determination of Halogen Compounds and Sulfur Oxides in Flue Gas by Ion Chromatography

Ion chromatography （IC） is a suitable analytical method for the determination of anions. As analytical methods for the halogen compounds in flue gas, those of bromine compound, fluorine compound, chlorine （Cl2） and hydrogen chloride （HCI） are listed in JIS. However, IC has not been adopted in JIS except for HCI and C12. Because the carbon dioxide in flue gas is absorbed in a 0.1 M sodium hydroxide solution as an absorber, it is interfered with the measurement of F^- and Cl^- ions. This paper describes the development of the pretreatment equipment for the flue gas analysis by IC, and its applications to real flue gas analysis. The F^-, Cl^-, Br^- and SO4^2- in the absorbing solution can be clearly separated by IC using the pretreatment equipment. The halogen compounds and sulfur oxides in flue gas can be simultaneously determined by IC.

Observed Climate Changes in Southwest China during 1961-2010

The present study focused on statistical analysis of interannual, interdecadal variations of climate variables and extreme climate events during the period of 1961-2010 using observational data from 376 meteorological stations uniformly distributed across Southwest China, which includes Yunnan, Guizhou, Chongqing, Sichuan and Tibet. It was found that temperatures in most of the region were warming and this was especially evident for areas at high elevation. The warming was mostly attributable to the increase in annual mean minimum temperature. The characteristics of high temperature/heat waves are increase in frequency, prolonged duration, and weakened intensity. Annual precipitation showed a weak decreasing trend and drier in the east and more rainfall in the west. The precipitation amount in flood season was declining markedly in the whole region; rainfall from extreme heavy precipitation did not change much, and the portion of annual precipitation contributed by extreme heavy precipitation had an increasing trend; annual non-rainy days and the longest consecutive non-rainy days were both increasing; the extreme drought had a decreasing trend since the 1990s; the autumn-rain days displayed a downward fluctuation with apparent periodicity and intermittency. The number of southwestern vortices was decreasing whereas the number of moving vortices increased.