季风强度与气温变化的统计特征

对贵阳季风强度与气温的变化关系进行了分析研究。结果表明：①贵阳的季风强度与温度的变化关系密切，其月际相关达-0．744；②季风强度与气温均具有2—11d的短期变化周期，其分布型状相似；③季风强度与气温日变化具有一定的对应关系，在冬、夏季风较稳定时，季风强度与气温的对应关系比冬、夏季风交替出现时好；④倒春寒过程与较强的偏北气流出现关系密切．气流对气温的影响具有滞后性。

重油燃烧雾化介质选择的经济性问题

重油的雾化效果直接关系到火焰质量、耗油量、窑炉状况及其他工艺参数。本文从雾化介质带走窑内热量的角度对两种方法进行了分析计算,同时根据两种方法在同一窑炉上运行期间获得的资料,参照近来重油与电力在价格上的差异,主要从经济角度对两种雾化方法进行了分析比较。分析表明,在同等条件下,压缩空气雾化比蒸汽雾化节油。雾化气/重油为0.534和0.857时,可分别节油1.74％和2.62％,雾化气/重油比值控制得越小节油效果越好。

Soil carbon dioxide fluxes of a typical broad-leaved/Korean pine mixed forest in Changbai Mountain, China

The forest ecosystem plays an important role in the global carbon cycling. A study was conducted to evaluate soil CO2 flux and its seasonal and diurnal variation with the air and soil temperatures by using static closed chamber technique in a typical broad-leaved/Korean pine mixed forest area on the northern slope of Changbai Mountain, Jilin Province, China. The experiment was carried out through the day and night in the growing season (from June to September) in situ and sample gas was analyzed by a gas chromatograph. Results showed that the forest floor was a large net source of carbon, and soil CO2 fluxes had an obvi-ous law of seasonal and diel variation. The soil CO2 flux of broad-leaved/Korean pine mixed forest was in the range of 0.302.42 mmol穖-2穝-1 with the mean value of 0.98 mmol穖-2穝-1. An examination on the seasonal pattern of soil CO2 emission suggested that the variability in soil CO2 flux could be correlated with variations in soil temperature, and the maximum of mean CO2 flux occurred in July ((1.27±23%) mmol穖-2穝-1) and the minimum was in September ((0.50±28%) mmol穖-2穝-1). The fluctuations in diel soil CO2 flux were also correlated with changes in soil temperature; however, there existed a factor for a time lag. Soil CO2 flux from the forest floor was strongly related to soil temperature and had the highest correlation with temperature at 6-cm depth of soil. Q10 values based on air temperature and soil temperature of different soil depths were at the ranges of 2.09–3.40.

Solvent-free selective oxidation of cyclohexane with molecular oxygen over manganese oxides:Effect of the calcination temperature

The effects of calcination temperature on the physicochemical properties of manganese oxide catalysts prepared by a precipitation method were assessed by X-ray diffraction,N2 adsorption-desorption,X-ray photoelectron spectroscopy,H2 temperature-programmed reduction,O2 temperature-programmed desorption,and thermogravimetry-differential analysis.The catalytic performance of each of these materials during the selective oxidation of cyclohexane with oxygen in a solvent-free system was subsequently examined.It was found that the MnOx-500 catalyst,calcined at 500 °C,consisted of a Mn2O3 phase in addition to Mn5O8 and Mn3O4 phases and possessed a low surface area.Unlike MnOx-500,the MnOx-400 catalyst prepared at 400 °C was composed solely of Mn3O4 and Mn5O8 and had a higher surface area.The pronounced catalytic activity of this latter material for the oxidation of cyclohexene was determined to result from numerous factors,including a higher concentration of surface adsorbed oxygen,greater quantities of the surface Mn4＋ ions that promote oxygen mobility and the extent of O2 adsorption and reducibility on the catalyst.The effects of various reaction conditions on the activity of the MnOx-400 during the oxidation of cyclohexane were also evaluated,such as the reaction temperature,reaction time,and initial oxygen pressure.Following a 4 h reaction at an initial O2 pressure of 0.5 MPa and 140 °C,an 8.0% cyclohexane conversion and 5.0% yield of cyclohexanol and cyclohexanone were achieved over the MnOx-400 catalyst.In contrast,employing MnOx-500 resulted in a 6.1% conversion of cyclohexane and 75% selectivity for cyclohexanol and cyclohexanone.After being recycled through 10 replicate uses,the catalytic activity of the MnOx-400 catalyst was unchanged,demonstrating its good stability.

Effect of Altitude and Latitude on Surface Air Temperature across the Qinghai-Tibet Plateau

The correlation between mean surface air temperature and altitude is analyzed in this paper based on the annual and monthly mean surface air temperature data from 106 weather stations over the period 1961-2003 across the Qinghai-Tibet Plateau. The results show that temperature variations not only depend on altitude but also latitude, and there is a gradual decrease in temperature with the increasing altitude and latitude. The overall trend for the vertical temperature lapse rate for the whole plateau is approximately linear. Three methods, namely multivariate composite analysis, simple correlation and traditional stepwise regression, were applied to analyze these three correlations. The results assessed with the first method are well matched to those with the latter two methods. The apparent mean annual near-surface lapse rate is -4.8 ℃ /km and the latitudinal effect is -0.87 ℃ /°latitude. In summer, the altitude influences the temperature variations more significantly with a July lapse rate of -4.3℃/km and the effect of latitude is only -0.28℃ /°latitude. In winter, the reverse happens. The temperature decrease is mainly due to the increase in latitude. The mean January lapse rate is -5.0℃/km, while the effect of latitude is -1.51℃ /°latitude. Comparative analysis for pairs of adjacent stations shows that at a small spatial scale the difference in altitude is the dominant factor affecting differences in mean annual near-surface air temperature, aided to some extent bydifferences of latitude. In contrast, the lapse rate in a small area is greater than the overall mean value for the Qinghai-Tibet Plateau （5 to 13℃ /km）. An increasing trend has been detected for the surface lapse rate with increases in altitude. The temperature difference has obvious seasonal variations, and the trends for the southern group of stations （south of 33 o latitude） and for the more northerly group are opposite, mainly because of the differences in seasonal variation at low altitudes. For yearly changes, the temperature for high-altitude stations occurs earlier clearly. Temperature datasets at high altitude stations are well-correlated, and those in Nanjing were lagged for 1 year but less for contemporaneous correlations. The slope of linear trendline of temperature change for available years is clearly related to altitude, and the amplitude of temperature variation is enlarged by high altitude. The change effect in near-surface lapse rate at the varying altitude is approximately 1.0℃ /km on the rate of warming over a hundred-year period.

Ash melting behavior by Fourier transform infrared spectroscopy

A Fourier Transform Infrared Spectroscopic(FTIR)method involving a Fe2O3 flux was used to learn how China's coal ash melts.The relationship between ash fusion temperature and chemical composition,as well as the effects of Fe2O3 flux on the ash fusion temperature were studied.The relationship between ash fusion temperature and chemical composition,mineralogical phases and functional groups was analyzed with the FTIR method.The results show that the ash fusion temperature is related to the location and transmittance of certain absorption peaks,which is of great significance for the study of ash behavior.

Drought Response to Air Temperature Change over China on the Centennial Scale

Climate data from the Climatic Research Unit （CRU） for the period 1901-2013 are used to investigate the drought response to air temperature change over China on the centennial scale. Drought is observed to have increased evidently across China, except for some regions in eastern China. This increase is much stronger in northern China compared to southern China, especially in Northwest and North China. These change characteris- tics of drought are closely associated with air temperature change, with the severe droughts in the major drought episodes of the last century generally coinciding with higher temperatures. The significantly increasing trend of drought in China based on observations only appears when considering the effects of air temperature change, which can explain -49% of droughts in observations and 30%-65% of droughts in Coupled Model Intereomparison Project Phase 5 （CMIP5） model simulations. Furthermore, the response of drought to air temperature change generally increases as the drought time scale increases. Furthermore, drought shows relatively high sensitivity in spring and early summer in China on the centennial scale.

Difference in the Interdecadal Variability of Spring and Summer Sensible Heat Fluxes over Northwest China

The present study investigates the difference in interdecadal variability of the spring and summer sensible heat fluxes over Northwest China by using station observations from 1960 to 2000. It was found that the spring sensible heat flux over Northwest China was greater during the period from the late 1970s to the 1990s than during the period from the 1960s to the mid-1970s. The summer sensible heat flux was smaller in the late 1980s through the 1990s than it was in the 1970s through the early 1980s. Both the spring and summer land-air temperature differences over Northwest China displayed an obvious interdecadal increase in the late 1970s. Both the spring and summer surface wind speeds experienced an obvious interdecadal weakening in the late 1970s. The change in the surface wind speed played a more important role in the interdecadal variations in sensible heat flux during the summer, whereas the change in the land-air temperature difference was more important for the interdecadal variations in sensible heat flux in the spring. This difference was related to seasonal changes in the mean land-air temperature difference and the surface wind speed. Further analysis indicated that the increase in the spring land surface temperature in Northwest China was related to an increase in surface net radiation.

Investigation of non-isothermal and isothermal gasification process of coal char using different kinetic model

Isothermal and non-isothermal gasification kinetics of coal char were investigated by using thermogravimetric analysis(TGA) in CO2 atmosphere, and the experimental data were interpreted with the aids of random pore model(RPM), unreacted shrinking core model(URCM) and volume model(VM). With the increase of heating rate, gasification curve moves into high temperature zone and peak rate of gasification increases; with the increase of gasification temperature, gasification rate increases and the total time of gasification is shortened. The increase of both heating rate and gasification temperature could improve gasification process of coal char. Kinetics analysis indicates that experimental data agree better with the RPM than with the other two models. The apparent activation energy of non-isothermal and isothermal gasification of coal char using RPM is 193.9 k J/mol and 212.6 k J/mol respectively, which are in accordance with reported data. Gasification process of coal char under different heating rates and different temperatures are predicted by the RPM derived in this study, and it is found that the RPM predicts the reaction process satisfactorily.

CLIMATIC FEATURES OF SUMMER TEMPERATURE IN NORTHEAST CHINA UNDER WARMING BACKGROUND

By using,summer temperature data in 26 stations from 1951 to 2003, the variation characteristics of summer temperature in Northeast China （NET） were analyzed based on the background of climate wanning. The results showed that the warming in summer was 0.15~C/10a in Northeast China, which was higher than that on the global, Northern Hemisphere or Northeast Asia scale in the recent 50 years. The responses of NET to global warming were shown in 3 aspects mainly. Firstly, it became warm and the average temperature increased in summer; secondly, the temperature variability increased, which displayed the increase of climatic instability; thirdly, the disaster of low temperature decreased and high temperature damage increased obviously, but the disaster of low temperature still existed in some areas under global warming background, which would be worthy of notice further.

Long-term variability of the sharp thermocline in the Yellow and East China Seas

Based on observed temperature data since the 1950s, long-term variability of the summer sharp thermocline in the Yellow Sea Cold Water Mass （YSCWM） and East China Sea Cold Eddy （ECSCE） areas is examined. Relationships between the thermocline and atmospheric and oceanic forcing were investigated using multiyear wind, Kuroshio discharge and air temperature data. Results show that： 1） In the YSCWM area, thermocline strength shows about 4-year and 16-year period oscillations. There is high correlation between summer thermocline strength and local atmospheric temperature in summer and the previous winter; 2） In the ECSCE area, interannual oscillation of thermocline strength with about a 4-year period （stronger in El Nifio years） is strongly correlated with that of local wind stress. A transition from weak to strong thermocline during the mid 1970s is consistent with a 1976/1977 climate shift and Kuroshio volume transport; 3） Long-term changes of the thermocline in both regions are mainly determined by deep layer water, especially on the decadal timescale. However, surface water can modify the thermocline on an interannual timescale in the YSCWM area.

Variation in the temperature field of rocks overlying a high-temperature cavity during underground coal gasification

High temperature affects rocks in a way that changes the physical and mechanical properties of them. The temperature field in rock overlying a high temperature zone has been estimated using experimental research on thermal conductivity of the overlying strata. Numerical analysis software was used to esti- mate rock thermal conductivity at different temperatures. These estimates were then used with COMSOL Multiphysics to perform a numerical analysis with the heat conduction model. The results show that rock thermal conductivity decreases as the temperature increases and that various lithologies show similar behavior. The thermal conductivity of each rock type differs from the others at a given temperature. Exact values for the temperature distribution in the overlying strata during the process of underground coal gasification are obtained from the numerical simulation. The temperature in the rock changes with the height and direction from the gasifier. Temperature gradients vary for different types of rock. This result provides an important reference for further study of the strength of overlying strata subject to the process of underground coal gasification.

Spatial and temporal variation of daytime and nighttime MODIS land surface temperature across Nepal

Land surface temperature(LST)is an important variable for assessing climate change and related environmental impacts observed in recent decades.Regular monitoring of LST using satellite sensors such as MODIS has the advantage of global coverage,including topographically complex regions such as Nepal.In order to assess the climatic and environmental changes,daytime and nighttime LST trend analysis from 2000 to 2017 using Terra-MODIS monthly daytime and nighttime LST datasets at seasonal and annual scales over the territory of Nepal was performed.The magnitude of the trend was quantified using ordinary linear regression,while the statistical significance of the trend was identified by the Modified Mann—Kendall test.Our findings suggest that the nighttime LST in Nepal increased more prominently compared to the daytime LST,with more pronounced warming in the pre-monsoon and monsoon seasons.The annual nighttime LST increased at a rate of 0.05 K yr-1(p<0.01),while the daytime LST change was statistically insignificant.Spatial heterogeneity of the LST and LST change was observed both during the day and the night.The daytime LST remained fairly unchanged in large parts of Nepal,while a nighttime LST rise was dominant all across Nepal in the pre-monsoon and monsoon seasons.Our results on LST trends and their spatial distribution can facilitate a better understanding of regional climate changes.

Implications of Climate Change on Streamflow of a Snow-Fed River System of the Northwest Himalaya

Air temperature and snow cover variability are sensitive indicators of climate change. This study was undertaken to forecast and quantify the potential streamflow response to climate change in the Jhelum River basin. The implications of air temperature trends （＋0.11℃decade） reported for the entire north-west Himalaya for past century and the regional warming （＋0.7℃/decade） trends of three observatories analyzed between last two decades were used for future projection of snow cover depletion and stream flow. The streamflow was simulated and validated for the year 2007-2008 using snowmelt runoff model （SRM） based on in-situ temperature and precipitation with remotely sensed snow cover area. The simulation was repeated using higher values of temperature and modified snow cover depletion curves according to the assumed future climate. Early snow cover depletion was observed in the basin in response to warmer climate. The results show that with the increase in air temperature, streamfiow pattern of Jhelum will be severely affected. Significant redistribution of streamflow was observed in both the scenarios. Higher discharge was observed during spring-summer months due to early snowmelt contribution with water deficit during monsoon months. Discharge increased by 5%-40% during the months of March to May in 2030 and 2050. The magnitude of impact of air temperature is higher in the scenario-2 based on regional warming. The inferences pertaining to change in future streamflow pattern can facilitate long term decisions and planning concerning hydro-power potential, waterresource management and flood hazard mapping in the region.

Effect of Landform on Seasonal Temperature Structures across China in the Past 52 Years

The data of 16o national meteorological observatory stations including the long-term monthly temperature data in China were analyzed to study the seasonal variation of the spatial temperature structures across China in the past half century. It is found that temperature structures differ between seasons： a latitude temperature pattern in winter and a landform temperature pattern in summer, which indicate that the effect of landform on temperature structure is much stronger in summer than that in winter and the effect of latitudinal temperature is much stronger in winter than that in summer. The mechanisms of the seasonal difference in temperature structures are also discussed in this paper.

Effect of Aspect on Climate Variation in Mountain Ranges of Shennongjia Massif, Central China

The aim of this study was to better understand the mechanisms of regional climate variation in mountain ranges with contrasting aspects as mediated by changes in global climate. It may help predict trends of vegetation variations in native ecosystems in natural reserves. As measures of climate response, temperature and precipitation data from the north, east, and south-facing mountain ranges of Shennongjia Massif in the coldest and hottest months(January and July), different seasons(spring, summer, autumn, and winter) and each year were analyzed from a long-term dataset(1960 to 2003) to tested variations characteristics, temporal and spatial quantitative relationships of climates. The results showed that the average seasonal temperatures and precipitation in the north, east, and south aspects of the mountain ranges changed at different rates. The average seasonal temperatures change rate ranges in the north, east, and south-facing mountain ranges were from –0.0210℃/yr to 0.0143℃/yr, –0.0166℃/yr to 0.0311℃/yr, and –0.0290 ℃/yr to 0.0084℃/yr, respectively, and seasonal precipitation variation magnitude were from –1.4940 mm/yr to 0.6217 mm/yr, –1.6833 mm/yr to 2.6182 mm/yr, and –0.8567 mm/yr to 1.4077 mm/yr, respectively. The climates variation trend among the three mountain ranges were different in magnitude and direction, showing a complicated change of the climates in mountain ranges and some inconsistency with general trends in global climate change. The climate variations were significantly different and positively correlated cross mountain ranges, revealing that aspects significantly affected on climate variations and these variations resulted from a larger air circulation system, which were sensitive to global climate change. We conclude that location and terrain of aspect are the main factors affecting differences in climate variation among the mountain ranges with contrasting aspects.

CHARACTERISTICS OF CLIMATE WARMING AND IMPACT ON CLIMATE ZONES CHANGE IN GUANGDONG

Based on temperature data in Guangdong in the past 50years, statistical methods are used to analyze the characteristics of temperature in spatial and temporal variation. The results show that land surface temperature warms by 0.16℃/1 0a in Guangdong. The range of warming was lower than the average of nationwide and global land surface. Furthermore, the temperature has a larger increase tendency in winter and spring and coastal areas than in summer and autumn and inland areas. Climate zones move towards the north obviously. North tropical zone is expanding, south subtropical zone is reducing and central subtropical zone is relatively stable. Under the global climate warming, characteristics of climate warming in Guangdong were influenced by atmosphere general circulation, sea surface temperature and human activities etc.

Experiment and mechanism investigation on advanced reburning for NO_x reduction:influence of CO and temperature

Pulverized coal reburning, ammonia injection and advanced reburning in a pilot scale drop tube furnace were inves- tigated. Premix of petroleum gas, air and NH3 were burned in a porous gas burner to generate the needed flue gas. Four kinds of pulverized coal were fed as reburning fuel at constant rate of 1g/min. The coal reburning process parameters including 15%~25% reburn heat input, temperature range from 1100 °C to 1400 °C and also the carbon in fly ash, coal fineness, reburn zone stoichiometric ratio, etc. were investigated. On the condition of 25% reburn heat input, maximum of 47% NO reduction with Yanzhou coal was obtained by pure coal reburning. Optimal temperature for reburning is about 1300 °C and fuel-rich stoichiometric ratio is essential; coal fineness can slightly enhance the reburning ability. The temperature window for ammonia injection is about 700 °C^1100 °C. CO can improve the NH3 ability at lower temperature. During advanced reburning, 72.9% NO reduction was measured. To achieve more than 70% NO reduction, Selective Non-catalytic NOx Reduction (SNCR) should need NH3/NO stoichiometric ratio larger than 5, while advanced reburning only uses common dose of ammonia as in conventional SNCR technology. Mechanism study shows the oxidization of CO can improve the decomposition of H2O, which will rich the radical pools igniting the whole reactions at lower temperatures.

Changes in surface air temperature over China under the 1.5 and 2.0 ℃ global warming targets

This study investigated the projected changes in the annual mean surface air temperature （SAT） over China under the 1.5 and 2.0 ℃ targets, by analyzing the outputs from 22 models of the Coupled Model Intercomparison Project Phase 5. Under the 1.5 ℃ target, the scope of changes in the average SAT over China is quite narrow and has the largest probability to increase by 1.7-2.0 ℃ under the various RCP pathways, although the time of occurrence of the 1.5 ℃ target has a large spread of 40-60 years. Similarly, the models consistently show that the average SAT over China would most likely increase by 2.4-2.7 ℃ under the 2.0 ℃ target. Furthermore, the warming shows a clear spatial distinction over China： being stronger in the northwest part and weaker in the southeast part. Under all RCP pathways, the SAT over the northwest part would increase by 1.9-2.1 ℃ for the 1.5℃ target, which is much stronger than the SAT increase over the southeast part （1.3-1.5 ℃）. A similar spatial pattern appears for the 2.0 ℃ target.

Interdecadal Variations of Winter Temperatures in East China During the Past 100 Years and Related Atmospheric Circulation

The winter temperature changes in East China during the past 100 years are investigated by using the Twentieth Century Version 2(20th-v2)Reanalysis.Four typical warm(P1,1911–30;P4,1991–2010)and cold(P2,1938–57;P3,1961–80)periods are identified for the East China winter temperature index.Comparison of160-station observational data,NCAR sea level pressure(SLP)data,and NCEP/NCAR Reanalysis shows that the20th-v2 Reanalysis can successfully depict the major features of the warming from P3 to P4,which is part of the global warming phenomenon.The cooling from P1 to P2is a regional phenomenon under global warming.However,both changes are consistent with the phase change of the Arctic Oscillation(AO),while the second change is also accompanied by the phase change of Antarctic Oscillation(AAO)from negative to positive.Original sources of the interdecadal shifts of the AO and winter temperature in East China require further research.