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功能化MIL-101(Cr)修饰QCM气相传感器的组装与甲酸识别
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作者 陈雅婷 王鹏 +8 位作者 郭宝盈 付思芸 刘琬宁 陈舒仪 施羽 蔡松亮 郑盛润 范军 章伟光 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2024年第6期30-43,共14页
挥发性有机化合物(VOCs)是一类主要的大气污染物,对人体健康和环境均可造成危害,因此发展可快速、灵敏检测VOCs的技术具有重要意义.本文分别以乙二胺(ED)和乙醇胺(EA)修饰MIL-101(Cr),制得了MIL-101(Cr)-ED和MIL-101(Cr)-EA,采用滴涂法... 挥发性有机化合物(VOCs)是一类主要的大气污染物,对人体健康和环境均可造成危害,因此发展可快速、灵敏检测VOCs的技术具有重要意义.本文分别以乙二胺(ED)和乙醇胺(EA)修饰MIL-101(Cr),制得了MIL-101(Cr)-ED和MIL-101(Cr)-EA,采用滴涂法制备了3种负载MIL-101(Cr)材料的石英晶体微天平(QCM)气相传感器,研究了其对甲醇、乙醇、异丙醇、丙酮、环己烷、二乙胺、甲酸、甲醛、氨气和乙酸的传感性能.实验结果表明,与负载MIL-101(Cr)的传感器相比,负载MIL-101(Cr)-ED和MIL-101(Cr)-EA的QCM传感器对甲酸的吸附性能显著提高,在甲酸浓度为350 mg/L时,传感器的振荡频率分别下降至-375.6和-232.1 Hz.在甲酸浓度为5~350 mg/L时,负载MIL-101(Cr)-ED的QCM传感器对甲酸响应的灵敏度为0.95 Hz·L·mg^(-1),检测限为0.95mg/L,表现出线性良好、灵敏度高、检测限低和重复性好的特点.这表明此类QCM气相传感器在VOCs实时检测方面具有良好的应用前景. 展开更多
关键词 石英晶体微天平(QCM) MIL-101(Cr) 功能化 气相传感器 甲酸识别
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羟基化碳纳米管检测油中溶解气体的理论分析 被引量:4
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作者 张晓星 孟凡生 +1 位作者 常涛 刘王挺 《高电压技术》 EI CAS CSCD 北大核心 2010年第8期1957-1961,共5页
为检测油中溶解气体,应用密度泛函理论,通过计算机量子力学模拟研究了羟基侧壁修饰的(8,0)单壁碳纳米管(SWNT-OH)对变压器油中溶解气体分子C2H2、CH4、C2H4、CO、H2的吸附特性。计算得到的吸附能、净电荷转移量、作用距离及电子态密度表... 为检测油中溶解气体,应用密度泛函理论,通过计算机量子力学模拟研究了羟基侧壁修饰的(8,0)单壁碳纳米管(SWNT-OH)对变压器油中溶解气体分子C2H2、CH4、C2H4、CO、H2的吸附特性。计算得到的吸附能、净电荷转移量、作用距离及电子态密度表明,SWNT-OH对油中溶解气体分子的吸附属于物理吸附,且吸附气体分子之后,SWNT-OH的几何结构和电子结构都发生了变化。SWNT-OH对有机分子(C2H2、CH4、C2H4)的吸附能力大于对无机分子(CO、H2)的吸附能力,在有机分子中对C2H2的吸附能力最大。因此,预测SWNT-OH可以作为检测变压器油中溶解的C2H2气体的新型气体传感器。 展开更多
关键词 羟基化碳纳米管 油中溶解 乙炔 体检测 密度泛函理论 气相传感器
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硼氮掺杂的碳纳米管对硫化氢气敏性能的理论研究 被引量:4
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作者 王若曦 张冬菊 +1 位作者 武剑 刘成卜 《化学学报》 SCIE CAS CSCD 北大核心 2007年第2期107-110,共4页
应用密度泛函理论研究了纯(8,0)单壁碳纳米管(SWCNT)和B原子、N原子以及BN原子对掺杂的(8,0)SWCNTs对硫化氢气体分子的传感性质.计算结果表明,与纯碳纳米管相比,B原子掺杂的SWCNT显示了对H2S分子的敏感性,其几何结构和电子性质在吸附H2... 应用密度泛函理论研究了纯(8,0)单壁碳纳米管(SWCNT)和B原子、N原子以及BN原子对掺杂的(8,0)SWCNTs对硫化氢气体分子的传感性质.计算结果表明,与纯碳纳米管相比,B原子掺杂的SWCNT显示了对H2S分子的敏感性,其几何结构和电子性质在吸附H2S分子后发生了显著变化;而N原子和BN原子对的掺杂没有改善SWCNT对H2S分子的吸附性能,因此我们建议B原子掺杂的SWCNT作为检测H2S分子的新型气相传感器. 展开更多
关键词 单壁碳纳米管 硫化氢 掺杂 气相传感器 密度泛函理论
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基于酶催化银沉积质量放大的血吸虫压电免疫传感器的研究 被引量:2
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作者 申田田 周瑾艳 +3 位作者 徐金玲 吴朝阳 沈国励 俞汝勤 《化学学报》 SCIE CAS CSCD 北大核心 2010年第23期2477-2481,共5页
发展了一种基于酶催化金属银沉积信号放大的新型高灵敏气相压电免疫传感检测技术.先将血吸虫抗原(SjAg)共价固定在石英晶体表面,制备得到血吸虫压电免疫传感器.检测时,在晶振上滴加不同浓度的待测血吸虫抗体,再将碱性磷酸酶标记的二抗... 发展了一种基于酶催化金属银沉积信号放大的新型高灵敏气相压电免疫传感检测技术.先将血吸虫抗原(SjAg)共价固定在石英晶体表面,制备得到血吸虫压电免疫传感器.检测时,在晶振上滴加不同浓度的待测血吸虫抗体,再将碱性磷酸酶标记的二抗通过夹心方式结合到传感器表面.然后利用碱性磷酸酶催化磷酸化的抗坏血酸酯水解从而还原硝酸银,使金属银沉积在晶振表面上,放大传感器的质量响应信号.实验结果表明该传感检测方法可显著提高气相压电免疫传感器的检测灵敏度,传感器对血吸虫抗体的响应线性范围在1~225 ng/mL,检测下限为1 ng/mL. 展开更多
关键词 银沉积 酶催化 压电传感器 日本血吸虫
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Model improvement and verification of ring electrostatic sensors
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作者 DENG Fang-fang ZHANG Jian-yong +3 位作者 CHENG Rui-xue ZHOU Han-chang WANG Gao YAN Bing 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2018年第1期68-72,共5页
Accurate measurement of flow parameters is important in gas-solid two-phase flow,and such flow has to be dealt with in many processes involving bulk solids handling and transportation.The circular electrostatic sensor... Accurate measurement of flow parameters is important in gas-solid two-phase flow,and such flow has to be dealt with in many processes involving bulk solids handling and transportation.The circular electrostatic sensor is one of those used for gas-solid flow measurement.In this paper,the finite element method(FEM)is used to establish the mathematical model of the sensor,the spatial sensitivity characteristics of the sensors is analyzed,and the analytic model is improved by the nonlinear least square method and the iterative method.Finally,the correlation coefficients between the experimental results and the improved processing are compared and analyzed,and the mathematical expression of the model is improved.The feasibility and practicability of the improved model are verified. 展开更多
关键词 electrostatic sensor gas-solid flow measurement of flow parameters
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Voidage Measurement of Air-Water Two-phase Flow Based on ERT Sensor and Data Mining Technology
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作者 王保良 孟振振 +2 位作者 黄志尧 冀海峰 李海青 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2012年第2期400-405,共6页
Based on an electrical resistance tomography(ERT) sensor and the data mining technology,a new voidage measurement method is proposed for air-water two-phase flow.The data mining technology used in this work is a least... Based on an electrical resistance tomography(ERT) sensor and the data mining technology,a new voidage measurement method is proposed for air-water two-phase flow.The data mining technology used in this work is a least squares support vector machine(LS-SVM) algorithm together with the feature extraction method,and three feature extraction methods are tested:principal component analysis(PCA),partial least squares(PLS) and independent component analysis(ICA).In the practical voidage measurement process,the flow pattern is firstly identified directly from the conductance values obtained by the ERT sensor.Then,the appropriate voidage measurement model is selected according to the flow pattern identification result.Finally,the voidage is calculated.Experimental results show that the proposed method can measure the voidage effectively,and the measurement accuracy and speed are satisfactory.Compared with the conventional voidage measurement methods based on ERT,the proposed method doesn't need any image reconstruction process,so it has the advantage of good real-time performance.Due to the introduction of flow pattern identification,the influence of flow pattern on the voidage measurement is overcome.Besides,it is demonstrated that the LS-SVM method with PLS feature extraction presents the best measurement performance among the tested methods. 展开更多
关键词 two-phase flow voidage measurement electrical resistance tomography sensor data mining feature extraction
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Superhydrophobic conductive rubber band with synergistic dual conductive layer for wide-range sensitive strain sensor 被引量:3
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作者 Hongling Sun Yibing Bu +6 位作者 Hu Liu Jingwen Wang Wenke Yang Qianming Li Zhanhu Guo Chuntai Liu Changyu Shen 《Science Bulletin》 SCIE EI CAS CSCD 2022年第16期1669-1678,M0004,共11页
Wearable electronic devices have received increasing interests because of their excellent flexibility,stretchability,and human friendliness.As the core components,flexible strain sensors integrated with wide working r... Wearable electronic devices have received increasing interests because of their excellent flexibility,stretchability,and human friendliness.As the core components,flexible strain sensors integrated with wide working range,high sensitivity,and environment stability,especially in moisture or corrosive environments,remain a huge challenge.Herein,synergistic carbon nanotubes(CNTs)/reduced graphene oxide(rGO)dual conductive layer decorated elastic rubber band(RB)was successfully developed and treated with hydrophobic fumed silica(Hf-SiO_(2))for preparing superhydrophobic strain sensor.As expected,stable entangled CNTs layer and ultrasensitive microcracked rGO layer endow the sensor with extremely low detection limit(0.1%),high sensitivity(gauge factor is 685.3 at 482%strain),wide workable strain range(0–482%),fast response/recovery(200 ms/200 ms)and favorable reliability and reproducibility over 1000 cycles.Besides,the constructed Hf-SiO_(2) coating also makes the sensor exhibit excellent superhydrophobicity,self-cleaning property,and corrosion-resistance.As a proof of concept,our prepared high-performance strain sensor can realize the full-range monitoring of human motions and physiological signals even in the water environment,including pulse,vocalization,joint bending,running,and gesture recognition.Interestingly,it can also be knitted into a tactile electronic textile for spatial pressure distribution measurement.Thus,this study provides a universal technique for the preparation of high-performance strain sensors with great potential applications in the field of next-generation intelligent wearable electronics. 展开更多
关键词 Rubber band SUPERHYDROPHOBIC Strain sensor Synergistic dual conductive layer Wearable electronics
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Design and Optimization of Index-Guiding Photonic Crystal Fiber Gas Sensor 被引量:3
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作者 Saeed OLYAEE Alieh NARAGHI 《Photonic Sensors》 SCIE EI CAS 2013年第2期131-136,共6页
An index guiding photonic crystal fiber used in gas sensing applications is presented. The dependency of the confinement loss and relative sensitivity on the fiber parameters and wavelength is numerically investigated... An index guiding photonic crystal fiber used in gas sensing applications is presented. The dependency of the confinement loss and relative sensitivity on the fiber parameters and wavelength is numerically investigated by using the full-vectorial finite element method (FEM). The simulations showed that the gas sensing sensitivity increased with an increase in the core diameter and a decrease in the distance between centers of two adjacent holes. Increasing the hole size of two outer cladding rings, this structure simultaneously showed up to 10% improved sensitivity, and the confinement loss reached 6x 10-4 times less than that of the prior sensor at the wavelength of 1.5 μm. This proved the ability of this fiber used in gas and chemicals sensing applications. 展开更多
关键词 Confinement loss evanescent field gas sensor relative sensitivity photonic crystal fiber
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Nanoscopic Tip Sensors Fabricated by Gas Phase Etching of Optical Glass Fibers
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作者 Jorg BIERLICH Jens KOBELKE +3 位作者 David BRAND Konstantin KIRSCH Jan DELLITH Hartmut BARTELT 《Photonic Sensors》 SCIE EI CAS 2012年第4期331-339,共9页
Silica-based fiber tips are used in a variety of spectroscopic, micro- or nano-scopic optical sensor applications and photonic micro-devices. The miniaturization of optical sensor systems and the technical implementat... Silica-based fiber tips are used in a variety of spectroscopic, micro- or nano-scopic optical sensor applications and photonic micro-devices. The miniaturization of optical sensor systems and the technical implementation using optical fibers can provide new sensor designs with improved properties and functionality for new applications. The selective-etching of specifically doped silica fibers is a promising method in order to form complex photonic micro structures at the end or within fibers such as tips and cavities in various shapes useful for the all-fiber sensor and imaging applications. In the present study, we investigated the preparation of geometrically predefined, nanoscaled fiber tips by taking advantage of the dopant concentration profiles of highly doped step-index fibers. For this purpose, a gas phase etching process using hydrofluoric acid (HF) vapor was applied. The shaping of the fiber tips was based on very different etching rates as a result of the doping characteristics of specific optical fibers. Technological studies on the influence of the etching gas atmosphere on the temporal tip shaping and the final geometry were performed using undoped and doped silica fibers. The influence of the doping characteristics was investigated in phosphorus-, germanium-, fluorine- and boron-doped glass fibers. Narrow exposed as well as protected internal fiber tips in various shapes and tip radiuses down to less than 15 nm were achieved and characterized geometrically and topologically. For investigations into surface plasmon resonance effects, the fiber tips were coated with nanometer-sized silver layers by means of vapour deposition and finally subjected to an annealing treatment. 展开更多
关键词 Optical fiber tips NANOPROBES gas phase etching doping tip shaping metal coating
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