The hydrogen adsorption （storage） studies upon Ni/A1203 nano-composite prepared by metal organic chemical vapor deposition technique （MOCVD） exploiting single source molec ular precursor （SSP） approach were carr...The hydrogen adsorption （storage） studies upon Ni/A1203 nano-composite prepared by metal organic chemical vapor deposition technique （MOCVD） exploiting single source molec ular precursor （SSP） approach were carried out. The Ni/A1203 nano-composite is prepared in cold walled MOCVD reactor by the decomposition of SSP, [H2AI（OtBu）]2, on a substrate holding Ni（acac）2 powder. The SSP is a reducing agent which reduces Ni＋2 to Ni0 and works as source for Al203 matrix in which the Ni0 is dispersed. The resulting Ni/A1203 nano-composite is characterized by XRD, SEM, TEM, and EDX. The hydrogen adsorption （storage） studies are performed using home-made Sievert＇s type apparatus. The hydrogen storage studies reveal that approximately 2.9% （mass ratio） hydrogen can be stored in the Ni/A1203 nano-composite. The results show that Ni/A1203 nano-composite can be a po- tential candidate for hydrogen storage which can be used for onboard fuel purposes.展开更多
文摘The hydrogen adsorption （storage） studies upon Ni/A1203 nano-composite prepared by metal organic chemical vapor deposition technique （MOCVD） exploiting single source molec ular precursor （SSP） approach were carried out. The Ni/A1203 nano-composite is prepared in cold walled MOCVD reactor by the decomposition of SSP, [H2AI（OtBu）]2, on a substrate holding Ni（acac）2 powder. The SSP is a reducing agent which reduces Ni＋2 to Ni0 and works as source for Al203 matrix in which the Ni0 is dispersed. The resulting Ni/A1203 nano-composite is characterized by XRD, SEM, TEM, and EDX. The hydrogen adsorption （storage） studies are performed using home-made Sievert＇s type apparatus. The hydrogen storage studies reveal that approximately 2.9% （mass ratio） hydrogen can be stored in the Ni/A1203 nano-composite. The results show that Ni/A1203 nano-composite can be a po- tential candidate for hydrogen storage which can be used for onboard fuel purposes.
