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茂金属催化剂及其乙烯气相聚合控制
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作者 裴小静 《齐鲁石油化工》 2015年第3期247-250,共4页
简述茂金属催化剂的构成及其反应动力学特征,详介茂金属催化剂乙烯气相聚合体系防结块措施,以及该聚合体系常见异常情况及相应的控制对策。
关键词 茂金属催化剂 聚乙烯 气相聚合控制
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Dynamics and Predictive Control of Gas Phase Propylene Polymerization in Fluidized Bed Reactors 被引量:4
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作者 Ahmad Shamiri Mohamed azlan Hussain +2 位作者 Farouq sabri Mjalli Navid Mostoufi Seyedahmad Hajimolana~ 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第9期1015-1029,共15页
A two-phase dynamic model, describing gas phase propylene polymerization in a fluidized bed reactor, was used to explore the dynamic behavior and process control of the polypropylene production rate and reactor temper... A two-phase dynamic model, describing gas phase propylene polymerization in a fluidized bed reactor, was used to explore the dynamic behavior and process control of the polypropylene production rate and reactor temperature. The open loop analysis revealed the nonlinear behavior of the polypropylene fluidized bed reactor, jus- tifying the use of an advanced control algorithm for efficient control of the process variables. In this case, a central- ized model predictive control (MPC) technique was implemented to control the polypropylene production rate and reactor temperature by manipulating the catalyst feed rate and cooling water flow rate respectively. The corre- sponding MPC controller was able to track changes in the setpoint smoothly for the reactor temperature and pro- duction rate while the setpoint tracking of the conventional proportional-integral (PI) controller was oscillatory with overshoots and obvious interaction between the reactor temperature and production rate loops. The MPC was able to produce controller moves which not only were well within the specified input constraints for both control vari- ables, but also non-aggressive and sufficiently smooth for practical implementations. Furthermore, the closed loop dynamic simulations indicated that the speed of rejecting the process disturbances for the MPC controller were also acceotable for both controlled variables. 展开更多
关键词 model predictive control fluidized bed reactor propylene polymerization Ziegler-Natta catalyst
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