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北京春季大气中氨的气粒相转化及颗粒态铵采样偏差研究 被引量:18
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作者 韦莲芳 段菁春 +5 位作者 谭吉华 马永亮 贺克斌 王书肖 黄晓锋 张元勋 《中国科学:地球科学》 CSCD 北大核心 2015年第2期216-226,共11页
利用Partisol 2300型化学物种采样器,通过溶蚀器-膜-后置膜采集了北京2013年春季大气颗粒物及酸碱性气体样品,利用离子色谱分析获得PM2.5中主要无机组分和气体SO2,HNO2,HNO3和HCl浓度.结果表明,NH3,NH4+和PM2.5的昼夜变化特征相似,晚间... 利用Partisol 2300型化学物种采样器,通过溶蚀器-膜-后置膜采集了北京2013年春季大气颗粒物及酸碱性气体样品,利用离子色谱分析获得PM2.5中主要无机组分和气体SO2,HNO2,HNO3和HCl浓度.结果表明,NH3,NH4+和PM2.5的昼夜变化特征相似,晚间浓度均高于日间.非雾霾天[NH3]:[NH4+]均大于1,而雾霾期间NH3,NH4+和PM2.5浓度大幅度增加,NH3转化率加快,导致该比值小于1,表明NH3在灰霾的形成过程中起着重要作用.采样偏差研究表明,采样过程中普遍存在颗粒态NH4+的正、负偏差,半挥发无机组分在低污染水平下损失明显,但整体上单一滤膜采样高估NH4+浓度.NH4+的挥发损失受气象条件影响,而由于溶蚀器对酸碱性气体的吸收,[NH3]:[N(-Ⅲ)]和[HNO3][NH3]对NH4+的损失影响显著.因此对颗粒物中半挥发性组分进行采样偏差补偿,有利于提高大气颗粒物化学质量重构、污染物形成机制及其来源解析等研究结果的准确性. 展开更多
关键词 气粒相转化 PM2.5 铵盐 采样偏差 日内变化
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Experimental study on the spatial distribution of particle rotation in the upper dilute zone of a cold CFB riser 被引量:1
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作者 Xue-cheng WU Qin-hui WANG +3 位作者 Chen TIAN Zhong-yang LUO Meng-xiang FANG Ke-fa CEN 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2008年第7期922-931,共10页
Particle rotation plays an important role in gas-solid flows. This paper presents an experimental investigation on the spatial distribution of average rotation speed for glass beads in the upper dilute zone of a cold ... Particle rotation plays an important role in gas-solid flows. This paper presents an experimental investigation on the spatial distribution of average rotation speed for glass beads in the upper dilute zone of a cold circulating fluidized bed(CFB) riser. It is shown that in the horizontal direction,the average rotation speed in the near-wall area is larger than that in the center area,while in the vertical direction,it decreases as the height increases. The reason resulting in this distribution is analyzed by considering several factors including particle size,particle shape,particle number density,particle collision behavior,and the surrounding flow field,etc. The effects of CFB operation conditions on the spatial distribution of average rotation speed are also studied. The results show that the increasing superficial gas velocity increases the average rotation speed of particles in the near wall area but takes nearly no effect on that in the center area. The external solids mass flux,however,takes the opposite effect. It is found that the average rotation speeds of particles in both areas are increased as the total amount of bed material increases. 展开更多
关键词 Particle rotation Gas-solid two-phase flow Circulating fluidized bed (CFB)
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